Syntheses of two imidazolate-4-amide-5-imidate linker-based hexagonal metal–organic frameworks with flexible ethoxy substituent

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A rare example of in situ linker generation with the formation of soft porous Zn- and Co-MOFs (IFP-9 and -10, respectively) is reported. The flexible ethoxy groups of IFP-9 and -10 protrude into the 1D hexagonal channels. The gas-sorption behavior of both materials for H2, CO2 and CH4 showed wide hysteretic isotherms, typical for MOFs having a flexible substituent which can give rise to a gate effect.

Metadaten
Author details:	Suvendu Sekhar Mondal ORCiD GND, Subarna Dey, Igor A. Baburin, Alexandra Kelling, Uwe Schilde ORCiD GND, Gotthard Seifert, Christoph Janiak, Hans-Jürgen Holdt ORCiD
URN:	urn:nbn:de:kobv:517-opus4-94360
Publication series (Volume number):	Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (234)
Publication type:	Postprint
Language:	English
Date of first publication:	2013/10/08
Publication year:	2013
Publishing institution:	Universität Potsdam
Release date:	2016/08/11
Tag:	adsorption; behavior; carbon-dioxide; crystals; gases; ligand; pressure; selectivity; temperature; zinc
First page:	9394
Last Page:	9399
Source:	CrystEngComm (2013) Nr. 15, S. 9394-9399. - DOI: 10.1039/C3CE41632A
Organizational units:	Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
DDC classification:	5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer review:	Referiert
Publishing method:	Open Access
License (German):	Keine öffentliche Lizenz: Unter Urheberrechtsschutz