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Snapshots of the Fluctuating Hydrogen Bond Network in Liquid Water on the Sub-Femtosecond Timescale with Vibrational Resonant Inelastic x-ray Scattering

  • Liquid water molecules interact strongly with each other, forming a fluctuating hydrogen bond network and thereby giving rise to the anomalous phase diagram of liquid water. Consequently, symmetric and asymmetric water molecules have been found in the picosecond time average with IR and optical Raman spectroscopy. With subnatural linewidth resonant inelastic x-ray scattering (RIXS) at vibrational resolution, we take sub-femtosecond snapshots of the electronic and structural properties of water molecules in the hydrogen bond network. We derive a strong dominance of nonsymmetric molecules in liquid water in contrast to the gas phase on the sub-femtosecond timescale of RIXS and determine the fraction of highly asymmetrically distorted molecules.

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Metadaten
Author:Annette Pietzsch, Franz Hennies, Piter S. Miedema, Brian Kennedy, Justine Schlappa, Thorsten Schmitt, Vladimir N. Strocov, Alexander FöhlischORCiDGND
DOI:https://doi.org/10.1103/PhysRevLett.114.088302
ISSN:0031-9007 (print)
ISSN:1079-7114 (online)
Pubmed Id:http://www.ncbi.nlm.nih.gov/pubmed?term=25768783
Parent Title (English):Physical review letters
Publisher:American Physical Society
Place of publication:College Park
Document Type:Article
Language:English
Year of first Publication:2015
Year of Completion:2015
Release Date:2017/03/27
Volume:114
Issue:8
Pagenumber:5
Funder:Swedish Research Council (VR); Carl Tryggers Stiftelse (CTS); European
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie
Peer Review:Referiert