Sebastian Oliver Eckert, Jesper Norell, Piter S. Miedema, Martin Beye, Mattis Fondell, Wilson Quevedo, Brian Kennedy, Markus Hantschmann, Annette Pietzsch, Benjamin E. Van Kuiken, Matthew Ross, Michael P. Minitti, Stefan P. Moeller, William F. Schlotter, Munira Khalil, Michael Odelius, Alexander Föhlisch
- The femtosecond excited-state dynamics following resonant photoexcitation enable the selective deformation of N-H and N-C chemical bonds in 2-thiopyridone in aqueous solution with optical or X-ray pulses. In combination with multiconfigurational quantum-chemical calculations, the orbital-specific electronic structure and its ultrafast dynamics accessed with resonant inelastic X-ray scattering at the N 1s level using synchrotron radiation and the soft X-ray free-electron laser LCLS provide direct evidence for this controlled photoinduced molecular deformation and its ultrashort time-scale.
Metadaten| Author details: | Sebastian Oliver EckertORCiDGND, Jesper NorellORCiD, Piter S. Miedema, Martin BeyeORCiDGND, Mattis FondellORCiD, Wilson Quevedo, Brian Kennedy, Markus HantschmannORCiDGND, Annette PietzschORCiD, Benjamin E. Van Kuiken, Matthew RossORCiD, Michael P. Minitti, Stefan P. Moeller, William F. Schlotter, Munira Khalil, Michael OdeliusORCiD, Alexander FöhlischORCiDGND |
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| DOI: | https://doi.org/10.1002/anie.201700239 |
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| ISSN: | 1433-7851 |
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| ISSN: | 1521-3773 |
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| Pubmed ID: | https://pubmed.ncbi.nlm.nih.gov/28374523 |
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| Title of parent work (English): | Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker ; International edition |
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| Publisher: | Wiley-VCH |
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| Place of publishing: | Weinheim |
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| Publication type: | Article |
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| Language: | English |
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| Year of first publication: | 2017 |
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| Publication year: | 2017 |
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| Release date: | 2020/04/20 |
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| Tag: | RIXS (resonant inelastic X-ray scattering); nitrogen; photochemistry; protonation; selective bond cleavage |
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| Volume: | 56 |
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| Number of pages: | 5 |
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| First page: | 6088 |
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| Last Page: | 6092 |
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| Funding institution: | ERC-ADG under the Horizon 2020 EU Framework Programme for Research and Innovation [669531/EDAX]; Helmholtz Virtual Institute [VI 419]; Swedish Research Council (VR); Carl Trygger Foundation; Volkswagen-Stiftung; Office of Basic Energy Sciences of the US Department of Energy [DE-SC0002190]; US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-76SF00515]; LCLS; Stanford University through the Stanford Institute for Materials and Energy Sciences (SIMES); Lawrence Berkeley National Laboratory (LBNL); University of Hamburg through the BMBF priority program [FSP 301]; Center for Free Electron Laser Science (CFEL); DOE Office of Basic Energy Sciences |
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| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie |
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| Peer review: | Referiert |
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| External remark: | Zweitveröffentlichung in der Schriftenreihe Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe ; 1115 |
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