Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity

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A new imidazolate-4-amide-5-imidate based MOF, IFP-7, is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO2 sorption over N2 and CH4 gases.

Metadaten
Author details:	Suvendu Sekhar Mondal ORCiD GND, Asamanjoy Bhunia, Igor A. Baburin, Christian Jäger, Alexandra Kelling, Uwe Schilde ORCiD GND, Gotthard Seifert, Christoph Janiak, Hans-Jürgen Holdt ORCiD
URN:	urn:nbn:de:kobv:517-opus4-94341
Publication series (Volume number):	Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (233)
Publication type:	Postprint
Language:	English
Date of first publication:	2013/06/28
Publication year:	2013
Publishing institution:	Universität Potsdam
Release date:	2016/08/09
Tag:	adsorption; capacity; carbon-dioxide capture; coordination polymer; flexibility; hydrogen storage; ligand; metal-organic frameworks; mixed-matrix membranes; separation
First page:	7599
Last Page:	7601
Source:	Chem. Commun. (2013) 49, S. 7599-7601. - DOI: 10.1039/C3CC42156B
Organizational units:	Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
DDC classification:	5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer review:	Referiert
Publishing method:	Open Access
License (German):	Keine öffentliche Lizenz: Unter Urheberrechtsschutz