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Photochemical synthesis and properties of axially chiral naphthylpyridines

  • Five alkynyl pyridines were prepared and cyclized to naphthylpyridines as the main products in the course of a Photo-Dehydro-Diels-Alder reaction. Four of the final products are axially chiral and the determination of the rotational barrier by DFT calculations, dynamic NMR and H PLC experiments is demonstrated. (C) 2011 Elsevier B.V. All rights reserved.

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Author details:Pablo WessigORCiDGND, Charlotte Pick
DOI:https://doi.org/10.1016/j.jphotochem.2011.06.006
ISSN:1010-6030
Title of parent work (English):Journal of photochemistry and photobiology : A, Chemistry
Publisher:Elsevier
Place of publishing:Lausanne
Publication type:Article
Language:English
Year of first publication:2011
Publication year:2011
Release date:2017/03/26
Tag:Axial chirality; Dynamic HPLC; Dynamic NMR; Molecular modeling; Photo-Dehydro-Diels-Alder reaction; Photochemistry
Volume:222
Issue:1
Number of pages:3
First page:263
Last Page:265
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer review:Referiert
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