Metathesis polymerization of cystine-based macrocycles
- Macrocycles based on L-cystine were synthesized by ring-closing metathesis (RCM) and subsequently polymerized by entropy-driven ring-opening metathesis polymerization (ED-ROMP). Monomer conversion reached ∼80% in equilibrium and the produced poly(ester-amine-disulfide-alkene)s exhibited apparent molar masses (Mappw) of up to 80 kDa and dispersities (Đ) of ∼2. The polymers can be further functionalized with acid anhydrides and degraded by reductive cleavage of the main-chain disulfide.
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| Author details: | Felix Nicolas BehrendtORCiDGND, Helmut SchlaadORCiDGND |
|---|---|
| URN: | urn:nbn:de:kobv:517-opus4-395080 |
| Publication series (Volume number): | Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (329) |
| Publication type: | Postprint |
| Language: | English |
| Date of first publication: | 2016/11/22 |
| Publication year: | 2016 |
| Publishing institution: | Universität Potsdam |
| Release date: | 2017/04/27 |
| Number of pages: | 4 |
| Source: | Polym. Chem. (2017) Nr. 8, S. 366-369. - DOI: 10.1039/C6PY01864E |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| DDC classification: | 5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften |
| Peer review: | Referiert |
| Publishing method: | Open Access |
| Grantor: | RSC |
| License (English): |  Creative Commons - Namensnennung 3.0 Unported |
| External remark: | Bibliographieeintrag der Originalveröffentlichung/Quelle |
