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A short and efficient route from myo- to neo-inositol

  • An efficient route from myo- to neo-inositol is described. The key steps of the sequence are oxidation of the hydroxy group at C-5 to the corresponding ketone, followed by a highly (dr = 7.8:1) stereoselective reduction. The route includes nine steps with an overall yield of 51% and is therefore superior to all hitherto reported methods for the preparation of neo-inositol.

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Metadaten
Author:Pablo WessigORCiDGND, Kristian Möllnitz, Sebastian Hübner
URL:http://www.thieme-connect.com/ejournals/toc/synlett
DOI:https://doi.org/10.1055/s-0029-1220071
ISSN:0936-5214
Document Type:Article
Language:English
Year of first Publication:2010
Year of Completion:2010
Release Date:2017/03/25
Source:Synlett. - ISSN 0936-5214. - (2010), 10, S. 1497 - 1500
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert