Synthesis and conformational properties of 1,3-dimethyl-3-phenyl-1,3-azasilinane low temperature dynamic NMR and computational study
- 1,3-Dimethyl-3-phenyl-1,3-azasilinane was synthesized and its conformational behavior was studied by the low temperature NMR spectroscopy and quantum chemical calculations. The compound was shown to exist as an equilibrium mixture of the PhaxMeeq and PheqMeax chair conformers with the N-methyl substituent in equatorial position. The barrier to ring inversion was also determined.
Metadaten| Author details: | Bagrat A. Shainyan, Svetlana V. Kirpichenko, Erich KleinpeterORCiDGND |
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| ISSN: | 1551-7004 |
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| Title of parent work (English): | Arkivoc : free online journal of organic chemistry |
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| Publisher: | ARKAT |
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| Place of publishing: | Gainesville |
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| Publication type: | Article |
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| Language: | English |
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| Year of first publication: | 2012 |
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| Publication year: | 2012 |
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| Release date: | 2017/03/26 |
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| Tag: | 1,3-Dimethyl-3-phenyl-1,3-azasilinane; conformational analysis; low temperature NMR spectroscopy; quantum chemical calculations |
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| Issue: | 24 |
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| Number of pages: | 11 |
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| First page: | 175 |
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| Last Page: | 185 |
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| Funding institution: | Russian Foundation for Basic Research; Deutsche Forschungsgemeinschaft
(Grant RFBR-DFG) [11-03-91334] |
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| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
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| Peer review: | Referiert |
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