Diversified applications of chemically modified 1,2-Polybutadiene
- Commercially available 1,2-PB was transformed into a well-defined reactive intermediate by quantitative bromination. The brominated polymer was used as a polyfunctional macroinitiator for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline to yield a water-soluble brush polymer. Nucleophilic substitution of bromide by 1-methyl imidazole resulted in the formation of polyelectrolyte copolymers consisting of mixed units of imidazolium, bromo, and double bond. These copolymers, which were soluble in water without forming aggregates, were used as stabilizers in the heterophase polymerization of styrene and were also studied for their ionic conducting properties.
| Author details: | Jiayin YuanORCiDGND, Niels ten Brummelhuis, Mathias Junginger, Zailai Xie, Yan LuORCiDGND, Andreas TaubertORCiDGND, Helmut SchlaadORCiDGND |
|---|---|
| DOI: | https://doi.org/10.1002/marc.201100254 |
| ISSN: | 1022-1336 |
| Title of parent work (English): | Macromolecular rapid communications |
| Publisher: | Wiley-Blackwell |
| Place of publishing: | Malden |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2011 |
| Publication year: | 2011 |
| Release date: | 2017/03/26 |
| Tag: | emulsion polymerization; polybutadiene; polyelectrolytes; polymer modification; ring-opening polymerization |
| Volume: | 32 |
| Issue: | 15 |
| Number of pages: | 6 |
| First page: | 1157 |
| Last Page: | 1162 |
| Funding institution: | Max Planck Society; MPI Colloids Interfaces |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| Peer review: | Referiert |
