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Reversing the triazole topology in a cyclam-triazole-dye ligand gives a 10-fold brighter signal response to Zn2+ in aqueous solution

  • The fluorescence response of a set of cyclam-triazole-dye ligands is controlled by the appended dye, but simple reversal of the triazole topology affords a novel probe for Zn2+ with a longer fluorescence lifetime and higher fluorescence quantum yield upon Zn2+ binding (<tau t > = 2.0 ns, Phi(f) = 0.76).

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Author details:Sandra Ast, Peter J. Rutledge, Matthew H. Todd
DOI:https://doi.org/10.1002/ejic.201201072
ISSN:1434-1948
Title of parent work (English):European journal of inorganic chemistry : a journal of ChemPubSoc Europe
Publisher:Wiley-VCH
Place of publishing:Weinheim
Publication type:Article
Language:English
Year of first publication:2012
Publication year:2012
Release date:2017/03/26
Tag:Click chemistry; Electrochemistry; Fluorescence; Sensors; Zinc
Issue:34
Number of pages:5
First page:5611
Last Page:5615
Funding institution:National Breast Cancer Foundation [NC-10-69]; Australian Research Council [DP120104035]
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer review:Referiert
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