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1H,1H,2H,2H-Perfluorodecyl-Acrylate-Containing block copolymers from ARGET ATRP

  • Block copolymers of 1H,1H,2H,2H-perfluorodecyl acrylate (AC8) were obtained from ARGET ATRP. To obtain block copolymers of low dispersity the PAC8 block was synthesized in anisole with a CuBr(2)/PMDETA catalyst in the presence of tin(II) 2-ethylhexanoate as a reducing agent. The PAC8 block was subsequently used as macroinitiator for copolymerization with butyl and tert-butyl acrylate carried out in scCO(2). To achieve catalyst solubility in CO(2) two fluorinated ligands were employed. The formation of block copolymers was confirmed by size exclusion chromatography and DSC.

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Metadaten
Author:Ulrike Schreiber, Benjamin Hosemann, Sabine Beuermann
DOI:https://doi.org/10.1002/macp.201000307
ISSN:1022-1352 (print)
Parent Title (English):Macromolecular chemistry and physics
Publisher:Wiley-VCH
Place of publication:Weinheim
Document Type:Article
Language:English
Year of first Publication:2011
Year of Completion:2011
Release Date:2017/03/26
Tag:atom transfer radical polymerization (ATRP); block copolymers; fluoropolymers; supercritical carbon dioxide
Volume:212
Issue:2
Pagenumber:12
First Page:168
Last Page:179
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert