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Synthesis of a Co(II)-imidazolate framework from an anionic linker precursor: gas-sorption and magnetic properties

  • A Co(II)-imidazolate-4-amide-5-imidate based MOF, IFP-5, is synthesized by using an imidazolate anion-based novel ionic liquid as a linker precursor under solvothermal conditions. IFP-5 shows significant amounts of gas (N-2, CO2, CH4 and H-2) uptake capacities. IFP-5 exhibits an independent high spin Co(II) centre and antiferromagnetic coupling.

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Metadaten
Author details:Suvendu Sekhar MondalORCiDGND, Asamanjoy Bhunia, Serhiy Demeshko, Alexandra Kelling, Uwe SchildeORCiDGND, Christoph Janiak, Hans-Jürgen HoldtORCiD
DOI:https://doi.org/10.1039/c3ce42040j
ISSN:1466-8033
Title of parent work (English):CrystEngComm
Publisher:Royal Society of Chemistry
Place of publishing:Cambridge
Publication type:Article
Language:English
Year of first publication:2014
Publication year:2014
Release date:2017/03/27
Volume:16
Issue:1
Number of pages:4
First page:39
Last Page:42
Funding institution:German Research Foundation on "Metal-Organic Frameworks" [1362]
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer review:Referiert
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