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"Schizomorphic" Emulsion Copolymerization Particles

  • Cryo-electron microscopy, atomic force microscopy, and light microscopy investigations provide experimental evidence that amphiphilic emulsion copolymerization particles change their morphology in dependence on concentration. The shape of the particles is spherical at solids content above 1%, but it changes to rod-like, ring-like, and web-like structures at lower concentrations. In addition, the shape and morphology of these particles at low concentrations are not fixed but very flexible and vary with time between spheres, flexible pearlnecklace structures, and stretched rods.

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Author details:Nancy Weber, Brigitte TierschORCiD, Miriam M. Unterlass, Anneliese Heilig, Klaus TauerORCiD
DOI:https://doi.org/10.1002/marc.201100491
ISSN:1022-1336
Title of parent work (English):Macromolecular rapid communications
Publisher:Wiley-Blackwell
Place of publishing:Malden
Publication type:Article
Language:English
Year of first publication:2011
Publication year:2011
Release date:2017/03/26
Tag:amphiphilic particles; emulsion polymerization; morphology
Volume:32
Issue:23
Number of pages:5
First page:1925
Last Page:1929
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer review:Referiert
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