A supramolecular Co(II)₁₄-metal–organic cube in a hydrogen-bonded network and a Co(II)–organic framework with a flexible methoxy substituent

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The reaction of 4,5-dicyano-2-methoxyimidazole (L1) with Co(NO3)2·6H2O under solvothermal conditions in DMF, a MOF, IFP-8 and a hydrogen-bonded network consisting of tetradecanuclear Co(II)14-metal organic cube (1) are achieved. 1 shows the bcu net with 14 cobalt atoms.

Metadaten
Author details:	Suvendu Sekhar Mondal ORCiD GND, Asamanjoy Bhunia, Alexandra Kelling, Uwe Schilde ORCiD GND, Christoph Janiak, Hans-Jürgen Holdt ORCiD
URN:	urn:nbn:de:kobv:517-opus4-74098
Publication series (Volume number):	Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (paper 169)
Publication type:	Postprint
Language:	English
Date of first publication:	2014/03/26
Publication year:	2014
Publishing institution:	Universität Potsdam
Release date:	2015/03/23
Tag:	zinc
Issue:	169
Number of pages:	3
First page:	5441
Last Page:	5443
Source:	Chemical communications, 2014, 50, S. 5441-5443 - DOI: 10.1039/c3cc49698h
Organizational units:	Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
DDC classification:	5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer review:	Referiert
Publishing method:	Open Access
License (English):	Creative Commons - Namensnennung 3.0 Unported
External remark:	Bibliographieeintrag der Originalveröffentlichung/Quelle