Imino glycals via Ruthenium-catalyzed RCM and isomerization
- N-Allyl-N-homoallylamines were converted in one step into cyclic enamides via a ruthenium-catalyzed assisted tandem catalytic ring-closing metathesis-isomerization sequence. The sequence relies on the in situ transformation of a metathesis active Ru-carbene into an isomerization active Ru-hydride by addition of hydroxide as a chemical trigger.
| Author details: | Bernd SchmidtORCiDGND, Sylvia Hauke, Nino Muehlenberg |
|---|---|
| DOI: | https://doi.org/10.1055/s-0033-1338615 |
| ISSN: | 0039-7881 |
| ISSN: | 1437-210X |
| Title of parent work (English): | Synthesis |
| Publisher: | Thieme |
| Place of publishing: | Stuttgart |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2014 |
| Publication year: | 2014 |
| Release date: | 2017/03/27 |
| Tag: | heterocycles; isomerization; metathesis; ruthenium; tandem reaction |
| Volume: | 46 |
| Issue: | 12 |
| Number of pages: | 11 |
| First page: | 1648 |
| Last Page: | 1658 |
| Funding institution: | Deutsche Forschungsgemeinschaft (DFG) [Schm1095/6-2] |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| Peer review: | Referiert |
