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Gold-Catalyzed reactions of 2-C-Branched carbohydrates mild glycosidations and selective anomerizations

  • 2-C-branched methyl glycosides react with various alcohols under gold catalysis to transglycosylated products. The method is applicable for the convenient synthesis of disaccharides. Without nucleophile a selective anomerization occurs, giving first access to alpha-configured 2-C-nitromethyl glycosides. The results are interesting for the mechanism of gold-catalyzed glycosidations.

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Author details:Srinivasa Rao Vidadala, Tukaram M. Pimpalpalle, Torsten LinkerORCiDGND, Srinivas Hotha
DOI:https://doi.org/10.1002/ejoc.201100134
ISSN:1434-193X
Title of parent work (English):European journal of organic chemistry
Publisher:Wiley-Blackwell
Place of publishing:Malden
Publication type:Article
Language:English
Year of first publication:2011
Publication year:2011
Release date:2017/03/26
Tag:Anomerization; Carbohydrates; Glycosidation; Gold; Synthetic methods
Issue:13
Number of pages:5
First page:2426
Last Page:2430
Funding institution:Department of Science & Technology, New Delhi; Council of Scientific & Industrial Research, New Delhi
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer review:Referiert
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