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Copolymers derived from rapeseed derivatives via ADMET and thiol-ene addition
- Novel (co)polymers were synthesized from substances obtained from rapeseed via ADMET and thiol-ene additions. alpha,omega-Dienes derived from oleic and erucic acid were copolymerized with a ferulic acid derivative, a representative phenolic acid (p-hydroxycinnamic acid) present, for instance, in rapeseed cake. Copolymers with different ratios of these monomers were prepared via two different routes (ADMET and thiol-ene) and studied in detail. Both monomer and polymer synthesis were optimized in order to achieve high yielding synthetic procedures that meet the requirements of green chemistry. Some thermal properties of the resulting copolymer series were then studied and correlated to the co-monomer composition.
| Author details: | Oliver Kreye, Tommy Toth, Michael A. R. Meier |
|---|---|
| DOI: | https://doi.org/10.1016/j.eurpolymj.2011.06.012 |
| ISSN: | 0014-3057 |
| Title of parent work (English): | European polymer journal |
| Publisher: | Elsevier |
| Place of publishing: | Oxford |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2011 |
| Publication year: | 2011 |
| Release date: | 2017/03/26 |
| Tag: | ADMET polymerization; Rapeseed cake; Rapeseed oil; Thiol-ene addition; alpha,omega-Dienes; p-Hydroxycinnamic acids |
| Volume: | 47 |
| Issue: | 9 |
| Number of pages: | 13 |
| First page: | 1804 |
| Last Page: | 1816 |
| Funding institution: | German Federal Ministry of Food, Agriculture and Consumer Protection [FKZ 22023008] |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| Peer review: | Referiert |
