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Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity

  • A new imidazolate-4-amide-5-imidate based MOF, IFP-7, is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO2 sorption over N2 and CH4 gases.

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Metadaten
Author:Suvendu Sekhar Mondal, Asamanjoy Bhunia, Igor A. Baburin, Christian Jäger, Alexandra Kelling, Uwe SchildeORCiDGND, Gotthard Seifert, Christoph Janiak, Hans-Jürgen Holdt
URN:urn:nbn:de:kobv:517-opus4-94341
Series (Serial Number):Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (233)
Document Type:Postprint
Language:English
Date of first Publication:2013/06/28
Year of Completion:2013
Publishing Institution:Universität Potsdam
Release Date:2016/08/09
Tag:adsorption; capacity; carbon-dioxide capture; coordination polymer; flexibility; hydrogen storage; ligand; metal-organic frameworks; mixed-matrix membranes; separation
First Page:7599
Last Page:7601
Source:Chem. Commun. (2013) 49, S. 7599-7601. - DOI: 10.1039/C3CC42156B
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer Review:Referiert
Publication Way:Open Access
Licence (German):License LogoKeine Nutzungslizenz vergeben - es gilt das deutsche Urheberrecht