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Crystal structure of erioflorin isolated from Podanthus mitiqui (L.)

  • The title compound, erioflorin, C19H24O6 [systematic name: (1aR,3S,4Z,5aR,8aR,9R,10aR)-1a, 2,3,5a, 7,8,8a, 9,10,10a-decahydro-3-hydroxy-4,10a-dimethyl-8-methylidene-7-oxooxireno[5,6] cyclodeca[1,2-b]furan-9-yl methacrylate], is a tricyclic germacrane sesquiterpene lactone, which was isolated from Podanthus mitiqui (L.). The compound crystallizes in the space group P2(1)2(1)2(1), and its molecular structure consists of a methacrylic ester of a ten-membered ring sesquiterpenoid annelated with an epoxide and a butyrolactone. The structure is stabilized by one intramolecular C-H center dot center dot center dot O hydrogen bond. An O-H center dot center dot center dot O hydrogen bond and further C-H center dot center dot center dot O interactions can be observed in the packing.

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Metadaten
Author:Uwe SchildeORCiDGND, Christian Paz, Leandro Ortiz
URN:urn:nbn:de:kobv:517-opus4-401832
Series (Serial Number):Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe (379)
Document Type:Postprint
Language:English
Year of first Publication:2017
Year of Completion:2017
Publishing Institution:Universität Potsdam
Release Date:2017/10/12
Tag:Podanthus mitiqui; crystal structure; germacrane sesquiterpene lactone
Pagenumber:4
Source:Acta Crystallographica Section E : Crystallographic Communications 73 (2017), S. 334-337. - DOI: 10.1107/S2056989017001700
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Dewey Decimal Classification:5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften
Peer Review:Referiert
Publication Way:Open Access
Licence (German):License LogoCreative Commons - Namensnennung, 2.0 UK
Notes extern:Bibliographieeintrag der Originalveröffentlichung/Quelle