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Smart polymer surfaces : mapping chemical landscapes on the nanometre scale

  • We show that Scattering Infrared Near-field Microscopy (SNIM) allows chemical mapping of polymer monolayers that can serve as designed nanostructured surfaces with specific surface chemistry properties on a nm scale. Using s- SNIM a minimum volume of 100 nm x 100 nm x 15 nm is sufficient for a recording of a "chemical'' IR signature which corresponds to an enhancement of at least four orders of magnitudes compared to conventional FT-IR microscopy. We could prove that even in cases where it is essentially difficult to distinguish between distinct polymer compositions based solely on topography, nanophase separated polymers can be clearly distinguished according to their characteristic near-field IR response.

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Author:Marlena Filimon, Ilona Kopf, Fuad Ballout, Dietrich A. Schmidt, Erik Bruendermann, Jürgen Rühe, Svetlana SanterORCiDGND, Martina Havenith
URL:http://www.rsc.org/Publishing/Journals/sm/index.asp
DOI:https://doi.org/10.1039/C0sm00098a
ISSN:1744-683X
Document Type:Article
Language:English
Year of first Publication:2010
Year of Completion:2010
Release Date:2017/03/25
Source:Soft matter. - ISSN 1744-683X. - 6 (2010), 16, S. 3764 - 3768
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie
Peer Review:Referiert