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Oligo(omega-pentadecalactone) decorated magnetic nanoparticles

  • Hybrid magnetic nanoparticles (mgNP) with a magnetite core diameter of 10 +/- 1 nm surface functionalized with oligo(omega-pentadecalactone) (OPDL) oligomers with M-n between 1300 and 3300 g mol(-1) could be successfully prepared having OPDL grafted from 200 mg g(-1) to 2170 mg g(-1). The particles are dispersible in chloroform resulting in stable suspensions. Magnetic response against an external magnetic field proved the superparamagnetic nature of the particles with a low coercivity (B-c) value of 297 mu T. The combination of the advantageous superparamagnetism of the mgNP with the exceptional stability of OPDL makes these novel hybrid mgNP promising candidates as multifunctional building blocks for magnetic nanocomposites with tunable physical properties.

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Author details:Muhammad Yasar RazzaqORCiDGND, Marc BehlORCiDGND, Ute Frank, Joachim KoetzORCiDGND, Wojciech Szczerba, Andreas LendleinORCiDGND
DOI:https://doi.org/10.1039/c2jm16146j
ISSN:0959-9428
Title of parent work (English):Journal of materials chemistry
Publisher:Royal Society of Chemistry
Place of publishing:Cambridge
Publication type:Article
Language:English
Year of first publication:2012
Publication year:2012
Release date:2017/03/26
Volume:22
Issue:18
Number of pages:7
First page:9237
Last Page:9243
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer review:Referiert
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