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Synthesis of Magnaldehydes B and E and Dictyobiphenyl B by Microwave-Promoted Cross-Coupling of Boronophenols

  • Magnaldehydes B and E along with their 4'-methylated derivatives are naturally occurring 2,4'-biphenols that have been isolated from the Magnoliaceae. Herein, these natural products have been synthesized from a common intermediate, which was obtained by a microwave-promoted, hetero-geneously catalyzed, and protecting-group-free Suzuki-Miyaura coupling reaction in an aqueous medium. These reaction conditions were also successfully applied to a one-step synthesis of the slime mold metabolite dictyobiphenyl B.

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Metadaten
Author:Bernd SchmidtORCiDGND, Martin Riemer
DOI:https://doi.org/10.1002/ejoc.201500350
ISSN:1434-193X (print)
ISSN:1099-0690 (online)
Parent Title (English):European journal of organic chemistry
Publisher:Wiley-VCH
Place of publication:Weinheim
Document Type:Article
Language:English
Year of first Publication:2015
Year of Completion:2015
Release Date:2017/03/27
Tag:Biaryls; Cross-coupling; Natural products; Palladium; Phenols; Total synthesis
Issue:17
Pagenumber:7
First Page:3760
Last Page:3766
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert