alpha,beta-Unsaturated delta-Valerolactones through RCM-Isomerization Sequence
- alpha,beta-Unsaturated d-lactones are accessible via a sequential ring-closing metathesis (RCM) double-bond migration reaction starting from butenoates of allyl alcohols. This approach proceeds efficiently with lower catalyst loadings and higher initial substrate concentrations compared to the alternative RCM of acrylates derived from homoallylic alcohols.
| Author details: | Bernd SchmidtORCiDGND, Oliver Kunz |
|---|---|
| DOI: | https://doi.org/10.1055/s-0031-1290488 |
| ISSN: | 0936-5214 |
| Title of parent work (English): | Synlett : accounts and rapid communications in synthetic organic chemistry |
| Publisher: | Thieme |
| Place of publishing: | Stuttgart |
| Publication type: | Article |
| Language: | English |
| Year of first publication: | 2012 |
| Publication year: | 2012 |
| Release date: | 2017/03/26 |
| Tag: | esters; lactones; metathesis; ruthenium; tandem reactions |
| Issue: | 6 |
| Number of pages: | 4 |
| First page: | 851 |
| Last Page: | 854 |
| Funding institution: | Deutsche Forschungsgemeinschaft (DFG) [Schm 1095/6-1] |
| Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
| Peer review: | Referiert |
