• search hit 3 of 212
Back to Result List

Discrete Polymetallic Arrangements of Ag-I and Cu-I Ions Based on Multiple Bridging Phosphane Ligands and pi-pi Interactions

  • A simple and straightforward approach to new polymetallic Ag-I and Cu-I supramolecules is presented. The reaction of N,P,N,P,N ligand 2 with Ag-I ions affords a trimetallic complex bearing a triangular Ag-3 core; metallophilic interactions are stabilized by ligands that display a multiple bridging coordination mode as 10-electron donors. Heteroleptic polymetallic Ag-I and Cu-I complexes based on ligand 2 and the 1,12-diazaperylene (dape) ligand are obtained by an alternative molecular organization of the polymetallic arrays compared to that in homoleptic complexes of ligand 2.

Export metadata

Additional Services

Share in Twitter Search Google Scholar Statistics
Metadaten
Author:Bianca Attenberger, Mehdi El Sayed Moussa, Thomas Brietzke, Volodimir Vreshch, Hans-Jürgen Holdt, Christophe Lescop, Manfred Scheer
DOI:https://doi.org/10.1002/ejic.201500445
ISSN:1434-1948 (print)
ISSN:1099-0682 (online)
Parent Title (English):European journal of inorganic chemistry : a journal of ChemPubSoc Europe
Publisher:Wiley-VCH
Place of publication:Weinheim
Document Type:Article
Language:English
Year of first Publication:2015
Year of Completion:2015
Release Date:2017/03/27
Tag:Heterocycles; N; P ligands; Pi interactions; Polyaromatic fragments; Supramolecular chemistry
Issue:18
Pagenumber:5
First Page:2934
Last Page:2938
Funder:National de la Recherche Scientifique (CNRS); Ministere des Affaires Etrangeres et Europeennes; Agence Nationale de la Recherche (ANR) [ANR-12-BS07-0004-METALHEL-01]; Campus France; Deutsche Forschungsgemeinschaft (DFG); COST action PhoSciNet for short-term scientific mission (STSM) grants; Alexander von Humboldt Foundation
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert