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Renewable pyridinium ionic liquids from the continuous hydrothermal decarboxylation of furfural-amino acid derived pyridinium zwitterions

  • Fully renewable pyridinium ionic liquids were synthesised via the hydrothermal decarboxylation of pyridinium zwitterions derived from furfural and amino acids in flow. The functionality of the resulting ionic liquid (IL) can be tuned by choice of different amino acids as well as different natural carboxylic acids as the counter-ions. A representative member of this new class of ionic liquids was successfully used for the synthesis of ionogels and as a solvent for the Heck coupling.

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Metadaten
Author:Sarah Kirchhecker, Steffen Tröger-MüllerORCiD, Sebastian Bake, Markus AntoniettiORCiDGND, Andreas TaubertORCiDGND, Davide Esposito
DOI:https://doi.org/10.1039/c5gc00913h
ISSN:1463-9262 (print)
ISSN:1463-9270 (online)
Parent Title (English):Green chemistry : an international journal and green chemistry resource
Publisher:Royal Society of Chemistry
Place of publication:Cambridge
Document Type:Article
Language:English
Year of first Publication:2015
Year of Completion:2015
Release Date:2017/03/27
Volume:17
Issue:8
Pagenumber:6
First Page:4151
Last Page:4156
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert