Imino glycals via Ruthenium-catalyzed RCM and isomerization
- N-Allyl-N-homoallylamines were converted in one step into cyclic enamides via a ruthenium-catalyzed assisted tandem catalytic ring-closing metathesis-isomerization sequence. The sequence relies on the in situ transformation of a metathesis active Ru-carbene into an isomerization active Ru-hydride by addition of hydroxide as a chemical trigger.
Author details: | Bernd SchmidtORCiDGND, Sylvia Hauke, Nino Muehlenberg |
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DOI: | https://doi.org/10.1055/s-0033-1338615 |
ISSN: | 0039-7881 |
ISSN: | 1437-210X |
Title of parent work (English): | Synthesis |
Publisher: | Thieme |
Place of publishing: | Stuttgart |
Publication type: | Article |
Language: | English |
Year of first publication: | 2014 |
Publication year: | 2014 |
Release date: | 2017/03/27 |
Tag: | heterocycles; isomerization; metathesis; ruthenium; tandem reaction |
Volume: | 46 |
Issue: | 12 |
Number of pages: | 11 |
First page: | 1648 |
Last Page: | 1658 |
Funding institution: | Deutsche Forschungsgemeinschaft (DFG) [Schm1095/6-2] |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
Peer review: | Referiert |