The search result changed since you submitted your search request. Documents might be displayed in a different sort order.
  • search hit 8 of 95
Back to Result List

NMR spectroscopic conformational analysis of 4-methylene-cyclohexyl pivalateThe effect of sp(2) hybridization

  • The conformational equilibrium of the axial/equatorial conformers of 4-methylene-cyclohexyl pivalate is studied by dynamic NMR spectroscopy in a methylene chloride/freon mixture. At 153K, the ring interconversion gets slow on the nuclear magnetic resonance timescale, the conformational equilibrium (-G degrees) can be examined, and the barrier to ring interconversion (G(#)) can be determined. The structural influence of sp(2) hybridization on both G degrees and G(#) of the cyclohexyl moiety can be quantified.

Export metadata

Additional Services

Search Google Scholar Statistics
Metadaten
Author details:Erich KleinpeterORCiDGND, Matthias HeydenreichORCiD, Andreas KochORCiDGND, Angela Krtitschka, Tobias KrügerORCiDGND, Torsten LinkerORCiDGND
DOI:https://doi.org/10.1002/mrc.4630
ISSN:0749-1581
ISSN:1097-458X
Pubmed ID:https://pubmed.ncbi.nlm.nih.gov/28665001
Title of parent work (English):Magnetic resonance in chemistry
Publisher:Wiley
Place of publishing:Hoboken
Publication type:Article
Language:English
Year of first publication:2017
Publication year:2017
Release date:2020/04/20
Tag:4-methylene-cyclohexyl pivalate; conformational analysis; dynamic NMR spectroscopy; exo-methylene conformational effect at cyclohexane; quantum chemical calculations
Volume:55
Number of pages:6
First page:1073
Last Page:1078
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer review:Referiert
Accept ✔
This website uses technically necessary session cookies. By continuing to use the website, you agree to this. You can find our privacy policy here.