Y. -P. Sun, Franz Hennies, Annette Pietzsch, B. Kennedy, Thorsten Schmitt, Vladimir N. Strocov, Joakim Andersson, Martin Berglund, Jan-Erik Rubensson, K. Aidas, F. Gel'mukhanov, Michael Odelius, Alexander Föhlisch
- Resonant inelastic x-ray scattering spectra excited at the O1s(-1)pi* resonance of liquid acetone are presented. Scattering to the electronic ground state shows a resolved vibrational progression where the dominant contribution is due to the C-O stretching mode, thus demonstrating a unique sensitivity of the method to the local potential energy surface in complex molecular systems. For scattering to electronically excited states, soft vibrational modes and, to a smaller extent, intermolecular interactions give a broadening, which blurs the vibrational fine structure. It is predicted that environmental broadening is dominant in aqueous acetone.
MetadatenAuthor details: | Y. -P. Sun, Franz Hennies, Annette PietzschORCiD, B. Kennedy, Thorsten Schmitt, Vladimir N. Strocov, Joakim Andersson, Martin Berglund, Jan-Erik Rubensson, K. Aidas, F. Gel'mukhanov, Michael OdeliusORCiD, Alexander FöhlischORCiDGND |
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DOI: | https://doi.org/10.1103/PhysRevB.84.132202 |
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ISSN: | 1098-0121 |
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Title of parent work (English): | Physical review : B, Condensed matter and materials physics |
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Publisher: | American Physical Society |
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Place of publishing: | College Park |
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Publication type: | Article |
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Language: | English |
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Year of first publication: | 2011 |
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Publication year: | 2011 |
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Release date: | 2017/03/26 |
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Volume: | 84 |
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Issue: | 13 |
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Number of pages: | 4 |
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Funding institution: | Swedish Research Council (V.R.); Carl Tryggers Foundation; Magnus
Bergvall Foundation; Natural Science Foundation of China [10974121];
National Basic Research Program of China [2006CB806000]; European
Community [226716] |
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Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Physik und Astronomie |
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Peer review: | Referiert |
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