Synthesis of a Co(II)-imidazolate framework from an anionic linker precursor: gas-sorption and magnetic properties

  • A Co(II)-imidazolate-4-amide-5-imidate based MOF, IFP-5, is synthesized by using an imidazolate anion-based novel ionic liquid as a linker precursor under solvothermal conditions. IFP-5 shows significant amounts of gas (N-2, CO2, CH4 and H-2) uptake capacities. IFP-5 exhibits an independent high spin Co(II) centre and antiferromagnetic coupling.

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Author:Suvendu Sekhar Mondal, Asamanjoy Bhunia, Serhiy Demeshko, Alexandra Kelling, Uwe SchildeORCiDGND, Christoph Janiak, Hans-Jürgen Holdt
ISSN:1466-8033 (print)
Parent Title (English):CrystEngComm
Publisher:Royal Society of Chemistry
Place of publication:Cambridge
Document Type:Article
Year of first Publication:2014
Year of Completion:2014
Release Date:2017/03/27
First Page:39
Last Page:42
Funder:German Research Foundation on "Metal-Organic Frameworks" [1362]
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert