Novel porous materials based on oligospiroketals (OSK)

  • New porous materials based on covalently connected monomers are presented. The key step of the synthesis is an acetalisation reaction. In previous years we used acetalisation reactions extensively to build up various molecular rods. Based on this approach, investigations towards porous polymeric materials were conducted by us. Here we wish to present the results of these studies in the synthesis of 1D polyacetals and porous 3D polyacetals. By scrambling experiments with 1D acetals we could prove that exchange reactions occur between different building blocks (evidenced by MALDI-TOF mass spectrometry). Based on these results we synthesized porous 3D polyacetals under the same mild conditions.

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Metadaten
Author:Pablo WessigORCiDGND, Maik Gerngross, Simon Pape, Philipp Bruhns, Jens Weber
DOI:https://doi.org/10.1039/c4ra04437a
ISSN:2046-2069 (print)
Parent Title (English):RSC Advances
Publisher:Royal Society of Chemistry
Place of publication:Cambridge
Document Type:Article
Language:English
Year of first Publication:2014
Year of Completion:2014
Release Date:2017/03/27
Volume:4
Issue:59
Pagenumber:7
First Page:31123
Last Page:31129
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert