In situ synthesis of an imidazolate-4-amide-5-imidate ligand and formation of a microporous zinc-organic framework with H2-and CO2-storage ability

  • Narrow channels with polar walls are the structural and functional features responsible for the high capacity of a zinc-organic framework based on an imidazolate-amide-imidate ligand for the uptake of H2 and CO2 (see structure: orange Zn, blue N, red O, dark gray C, light gray H). The rigid and stable chelating ligand was synthesized in situ by partial hydrolysis of a dicyanoimidazole compound.

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Author:Franziska Debatin, Arne Thomas, Alexandra Kelling, Niklas Hedin, Zoltan Bacsik, Irena Senkovska, Stefan Kaskel, Matthias Junginger, Holger Müller, Uwe SchildeORCiDGND, Christian Jäger, Alwin Friedrich, Hans-Jürgen Holdt
Document Type:Article
Year of first Publication:2010
Year of Completion:2010
Release Date:2017/03/25
Source:Angewandte Chemie. - ISSN 1433-7851. - 49 (2010), 7, S. 1258 - 1262
Organizational units:Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie
Peer Review:Referiert