TY - JOUR A1 - Petitgirard, Sylvain A1 - Spiekermann, Georg A1 - Glazyrin, Konstantin A1 - Garrevoet, Jan A1 - Murakami, Motohiko T1 - Density of amorphous GeO2 to 133 GPa with possible pyritelike structure and stiffness at high pressure JF - Physical review : B, Condensed matter and materials physics N2 - Germanium oxide is a prototype network-forming oxide with pressure-induced structural changes similar to those found in crystals and amorphous silicate oxides at high pressure. Studying density and coordination changes in amorphous GeO2 allows for insight into structural changes in silicate oxides at very high pressure, with implications for the properties of planetary magmas. Here, we report the density of germanium oxide glass up to 133 GPa using the x-ray absorption technique, with very good agreement with previous experimental data at pressure below 40 GPa and recent calculation up to 140 GPa. Our data highlight four distinct compressibility domains, corresponding to changes of the local structure of GeO2. Above 80 GPa, our density data show a compressibility and bulk modulus similar to the counterpart crystal phase, and we propose that a compact distorted sixfold coordination, similar to the structural motif of the pyritelike crystalline GeO2 polymorph, is likely to be stable in that pressure range. Our density data point to a smooth continuous evolution of the average coordination for pressure above 20 GPa with persistent sixfold coordination, without sharp density or density slope discontinuities. These observations are in very good agreement with theoretical calculations and spectroscopic measurements, and our results indicate that glasses and melts may behave similarly to their high-pressure solid counterparts with comparable densities, compressibility, and possibly average coordination. Y1 - 2019 U6 - https://doi.org/10.1103/PhysRevB.100.214104 SN - 2469-9950 SN - 2469-9969 VL - 100 IS - 21 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Krapf, Diego A1 - Metzler, Ralf T1 - Strange interfacial molecular dynamics JF - Physics today Y1 - 2019 U6 - https://doi.org/10.1063/PT.3.4294 SN - 0031-9228 SN - 1945-0699 VL - 72 IS - 9 SP - 48 EP - 54 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Teichmann, Erik A1 - Rosenblum, Michael T1 - Solitary states and partial synchrony in oscillatory ensembles with attractive and repulsive interactions JF - Chaos : an interdisciplinary journal of nonlinear science N2 - We numerically and analytically analyze transitions between different synchronous states in a network of globally coupled phase oscillators with attractive and repulsive interactions. The elements within the attractive or repulsive group are identical, but natural frequencies of the groups differ. In addition to a synchronous two-cluster state, the system exhibits a solitary state, when a single oscillator leaves the cluster of repulsive elements, as well as partially synchronous quasiperiodic dynamics. We demonstrate how the transitions between these states occur when the repulsion starts to prevail over attraction. Y1 - 2019 U6 - https://doi.org/10.1063/1.5118843 SN - 1054-1500 SN - 1089-7682 VL - 29 IS - 9 PB - American Institute of Physics CY - Melville ER - TY - GEN A1 - Cestnik, Rok A1 - Abel, Markus T1 - Erratum: Inferring the dynamics of oscillatory systems using recurrent neural networks (Chaos : an interdisciplinary journal of nonlinear science. - 29 (2019) 063128) T2 - Chaos : an interdisciplinary journal of nonlinear science Y1 - 2019 U6 - https://doi.org/10.1063/1.5122803 SN - 1054-1500 SN - 1089-7682 VL - 29 IS - 8 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Meyer, Dominique M.-A. A1 - Kreplin, Alexander A1 - Kraus, S. A1 - Vorobyov, E. I. A1 - Haemmerlé, Lionel A1 - Eislöffel, Jochen T1 - On the ALMA observability of nascent massive multiple systems formed by gravitational instability JF - Monthly notices of the Royal Astronomical Society N2 - Massive young stellar objects (MYSOs) form during the collapse of high-mass pre-stellar cores, where infalling molecular material is accreted through a centrifugally balanced accretion disc that is subject to efficient gravitational instabilities. In the resulting fragmented accretion disc of the MYSO, gaseous clumps and low-mass stellar companions can form, which will influence the future evolution of massive protostars in the Hertzsprung-Russell diagram. We perform dust continuum radiative transfer calculations and compute synthetic images of disc structures modelled by the gravito-radiation-hydrodynamics simulation of a forming MYSO, in order to investigate the Atacama Large Millimeter/submillimeter Array (alma) observability of circumstellar gaseous clumps and forming multiple systems. Both spiral arms and gaseous clumps located at similar or equal to a few from the protostar can be resolved by interferometric alma Cycle 7 C43-8 and C43-10 observations at band 6 (), using a maximal 0.015 aracsec beam angular resolution and at least exposure time for sources at distances of . Our study shows that substructures are observable regardless of their viewing geometry or can be inferred in the case of an edge-viewed disc. The observation probability of the clumps increases with the gradually increasing efficiency of gravitational instability at work as the disc evolves. As a consequence, large discs around MYSOs close to the zero-age-main-sequence line exhibit more substructures than at the end of the gravitational collapse. Our results motivate further observational campaigns devoted to the close surroundings of the massive protostars S255IR-NIRS3 and NGC 6334I-MM1, whose recent outbursts are a probable signature of disc fragmentation and accretion variability. KW - radiative transfer KW - methods: numerical KW - stars: circumstellar matter Y1 - 2019 U6 - https://doi.org/10.1093/mnras/stz1585 SN - 0035-8711 SN - 1365-2966 VL - 487 IS - 4 SP - 4473 EP - 4491 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Niven, Robert K. A1 - Abel, Markus A1 - Schlegel, Michael A1 - Waldrip, Steven H. T1 - Maximum Entropy Analysis of Flow Networks: Theoretical Foundation and Applications JF - Entropy N2 - The concept of a "flow network"-a set of nodes and links which carries one or more flows-unites many different disciplines, including pipe flow, fluid flow, electrical, chemical reaction, ecological, epidemiological, neurological, communications, transportation, financial, economic and human social networks. This Feature Paper presents a generalized maximum entropy framework to infer the state of a flow network, including its flow rates and other properties, in probabilistic form. In this method, the network uncertainty is represented by a joint probability function over its unknowns, subject to all that is known. This gives a relative entropy function which is maximized, subject to the constraints, to determine the most probable or most representative state of the network. The constraints can include "observable" constraints on various parameters, "physical" constraints such as conservation laws and frictional properties, and "graphical" constraints arising from uncertainty in the network structure itself. Since the method is probabilistic, it enables the prediction of network properties when there is insufficient information to obtain a deterministic solution. The derived framework can incorporate nonlinear constraints or nonlinear interdependencies between variables, at the cost of requiring numerical solution. The theoretical foundations of the method are first presented, followed by its application to a variety of flow networks. KW - maximum entropy analysis KW - flow network KW - probabilistic inference Y1 - 2019 U6 - https://doi.org/10.3390/e21080776 SN - 1099-4300 VL - 21 IS - 8 SP - 776 PB - MDPI CY - Basel ER - TY - JOUR A1 - Seiler, Michael A1 - Seiß, Martin A1 - Hoffmann, Holger A1 - Spahn, Frank T1 - Hydrodynamic Simulations of Asymmetric Propeller Structures in Saturn's Rings JF - The astrophysical journal : an international review of spectroscopy and astronomical physics ; Supplement series N2 - The observation of the non-Keplerian behavior of propeller structures in Saturn's outer A ring raises the question: how does the propeller respond to the wandering of the central embedded moonlet? Here, we study numerically how the structural imprint of the propeller changes for a libration of the moonlet. It turns out that the libration induces an asymmetry in the propeller, which depends on the libration period and amplitude of the moonlet. Further, we study the dependence of the asymmetry on the libration period and amplitude for a moonlet with a 400 m Hill radius, which is located in the outer A ring. This allows us to apply our findings to the largest known propeller Blériot, which is expected to be of a similar size. For Blériot, we can conclude that, supposing the moonlet is librating with the largest observed period of 11.1 yr and an azimuthal amplitude of about 1845 km, a small asymmetry should be measurable but depends on the moonlet's libration phase at the observation time. The longitude residuals of other trans-Encke propellers (e.g., Earhart) show amplitudes similar to Blériot, which might allow us to observe larger asymmetries due to their smaller azimuthal extent, allowing us to scan the whole gap structure for asymmetries in one observation. Although the librational model of the moonlet is a simplification, our results are a first step toward the development of a consistent model for the description of the formation of asymmetric propellers caused by a freely moving moonlet. KW - Hydrodynamics KW - methods: data analysis KW - methods: numerical KW - planets and satellites: dynamical evolution and stability KW - planets and satellites: individual (Saturn) KW - planets and satellites: rings Y1 - 2019 U6 - https://doi.org/10.3847/1538-4365/ab26b0 SN - 0067-0049 SN - 1538-4365 VL - 243 IS - 2 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Richter, Lothar A1 - Vollhardt, Dieter T1 - Force measuring methods for determination of surface tension of liquids: A comparison JF - Tenside, surfactants, detergents N2 - Three methods for the determination of the surface tension of liquids based on force measurements namely, the vertical plate method of Wilhelmy, the frame method of Lenard and the ring method of du Nouy are compared and studied in respect of a common principle of correction. It is shown that these three most important force-based methods allow the determination of the surface tension under static conditions. The force components of the corresponding liquid column below the measuring wire obtained for the straight part of the withdrawal curve up to the transition in its curved part provides exact surface tension values. The experimentally accessible value of the force component describes the physical background of the measured value correction contrary to the approximate equations obtained by mathematical way. Usually the determination of surface tension of liquids is based merely at the vertical plate method on exact equations thermodynamically derived whereas in the case of the frame and ring methods correction factors in approximate equations are used. At usual application of the force-based methods under the non-static condition of the withdrawal of a liquid column, the force maximum measured at withdrawal of the measuring object (plate, frame, or ring) is the basis for the determination of surface tension. In these cases, the measured surface tension values are compensated by correction equations for the frame and ring methods which are based on an correction factor and correction tables empirically obtained. The surface tension values obtained in this usual way agree with those obtained by using the force component of the corresponding liquid column below the measuring wire for the straight part of the withdrawal curve up to the transition in its curved part. Problems arising at the force measurements with increasing thickness of the measuring wires inside and outside the rings are discussed. N2 - Drei auf Kraftmessungen basierende Methoden zur Bestimmung der Oberflächenspannung von Flüssigkeiten, nämlich die Vertikalplattenmethode von Wilhelmy, die Bügelmethode von Lenard und die Ringmethode von du Noüy werden miteinander verglichen und auf ein experimentell zugängliches gemeinsames Korrekturprinzip hin untersucht. Auf Basis der Messresultate wird demonstriert, dass diese drei wichtigsten auf Kraftmessungen basierenden Methoden eine exakte Bestimmung der Oberflächenspannung ermöglichen. Dies basiert auf Berücksichtigung der Kraftkomponente der entsprechenden Flüssigkeitssäule unterhalb des Messdrahtes, der für die Austauchgerade bis zum Übergang in den gekrümmten Teil der Austauchkurve erhalten wird. Der experimentell zugängliche Wert der Kraftkomponente beschreibt den physikalischen Hintergrund der Messwertkorrektur im Gegensatz zu den auf mathematischen Weg erhaltenen Näherungsgleichungen. Gebräuchlicher Weise basiert die Bestimmung der Oberflächenspannung von Flüssigkeiten lediglich bei der Vertikalplattenmethode auf thermodynamisch-exakt ableitbaren Gleichungen, während bei Bügel- und Ringmethode Korrekturfaktoren für Näherungsgleichungen bzw. Korrekturtabellen üblich sind. Die so erhaltenen Oberflächenspannungswerte stimmen mit denen überein, die unter Berücksichtigung der Kraftkomponente der entsprechenden Flüssigkeitssäule unterhalb des Messdrahtes erhalten werden. Probleme, die mit zunehmender Dicke des Messdrahtes innerhalb und außerhalb des Rings entstehen, werden diskutiert. T2 - Kraftmessungsmethoden zur Bestimmung der Oberflächenspannung von Flüssigkeiten: Ein Vergleich KW - surface tension KW - force methods Y1 - 2006 U6 - https://doi.org/10.3139/113.100314 SN - 0932-3414 VL - 43 IS - 5 SP - 256 EP - 261 PB - Hanser CY - München ER - TY - JOUR A1 - Assmann, Birte A1 - Thiel, Marco A1 - Romano, Maria Carmen A1 - Niemitz, Carsten T1 - Recurrence plot analyses suggest a novel reference system involved in newborn spontaneous movements JF - Behavior research methods : a journal of the Psychonomic Society N2 - The movements of newborns have been thoroughly studied in terms of reflexes, muscle synergies, leg coordination, and target-directed arm/hand movements. Since these approaches have concentrated mainly on separate accomplishments, there has remained a clear need for more integrated investigations. Here, we report an inquiry in which we explicitly concentrated on taking such a perspective and, additionally, were guided by the methodological concept of home base behavior, which Ilan Golard developed for studies of exploratory behavior in animals. Methods from nonlinear dynamics, such as symbolic dynamics and recurrence plot analyses of kinematic data received from audiovisual newborn recordings, yielded new insights into the spatial and temporal organization of limb movements. In the framework of home base behavior, our approach uncovered a novel reference system of spontaneous newborn movements. Y1 - 2006 U6 - https://doi.org/10.3758/BF03192793 SN - 1554-351X SN - 1554-3528 VL - 38 IS - 3 SP - 400 EP - 406 PB - Springer CY - New York ER - TY - JOUR A1 - Diez, Isabel A1 - Tauer, Klaus A1 - Schulz, Burkhard T1 - Unusual polymer dispersions-polypyrrole suspensions made of rings, frames, and platelets JF - Colloid and polymer science : official journal of the Kolloid-Gesellschaft N2 - Experimental results show that the polymerization of pyrrole in the presence of beta-naphthalenesulfonic acid and different fluorosurfactants like perfluorooctanesulfonic acid, perfluorooctyldiethanolamide, and ammonium perfluorooctanoate leads to polypyrrole with special morphologies, such as rings or disks and rectangular frames or plates. The formation of these unusually shaped particles of polymer dispersions is explained by the chemical and colloidal peculiarities of the oxidative pyrrole polymerization with ammonium peroxodisulfate in aqueous medium. KW - polypyrrole KW - chemical oxidative polymerization KW - particle morphology Y1 - 2006 U6 - https://doi.org/10.1007/s00396-006-1521-8 SN - 0303-402X VL - 284 SP - 1431 EP - 1442 PB - Springer CY - New York ER -