TY - THES A1 - Stoyanov, Hristiyan T1 - Soft nanocomposites with enhanced electromechanical response for dielectric elastomer actuators T1 - Elastomer-Nanokomposite mit erhöhter elektro-mechanischer Sensitivität für dielektrische Elastomer Aktoren N2 - Electromechanical transducers based on elastomer capacitors are presently considered for many soft actuation applications, due to their large reversible deformation in response to electric field induced electrostatic pressure. The high operating voltage of such devices is currently a large drawback, hindering their use in applications such as biomedical devices and biomimetic robots, however, they could be improved with a careful design of their material properties. The main targets for improving their properties are increasing the relative permittivity of the active material, while maintaining high electric breakdown strength and low stiffness, which would lead to enhanced electrostatic storage ability and hence, reduced operating voltage. Improvement of the functional properties is possible through the use of nanocomposites. These exploit the high surface-to-volume ratio of the nanoscale filler, resulting in large effects on macroscale properties. This thesis explores several strategies for nanomaterials design. The resulting nanocomposites are fully characterized with respect to their electrical and mechanical properties, by use of dielectric spectroscopy, tensile mechanical analysis, and electric breakdown tests. First, nanocomposites consisting of high permittivity rutile TiO2 nanoparticles dispersed in thermoplastic block copolymer SEBS (poly-styrene-coethylene-co-butylene-co-styrene) are shown to exhibit permittivity increases of up to 3.7 times, leading to 5.6 times improvement in electrostatic energy density, but with a trade-off in mechanical properties (an 8-fold increase in stiffness). The variation in both electrical and mechanical properties still allows for electromechanical improvement, such that a 27 % reduction of the electric field is found compared to the pure elastomer. Second, it is shown that the use of nanofiller conductive particles (carbon black (CB)) can lead to a strong increase of relative permittivity through percolation, however, with detrimental side effects. These are due to localized enhancement of the electric field within the composite, which leads to sharp reductions in electric field strength. Hence, the increase in permittivity does not make up for the reduction in breakdown strength in relation to stored electrical energy, which may prohibit their practical use. Third, a completely new approach for increasing the relative permittivity and electrostatic energy density of a polymer based on 'molecular composites' is presented, relying on chemically grafting soft π-conjugated macromolecules to a flexible elastomer backbone. Polarization caused by charge displacement along the conjugated backbone is found to induce a large and controlled permittivity enhancement (470 % over the elastomer matrix), while chemical bonding, encapsulates the PANI chains manifesting in hardly any reduction in electric breakdown strength, and hence resulting in a large increase in stored electrostatic energy. This is shown to lead to an improvement in the sensitivity of the measured electromechanical response (83 % reduction of the driving electric field) as well as in the maximum actuation strain (250 %). These results represent a large step forward in the understanding of the strategies which can be employed to obtain high permittivity polymer materials with practical use for electro-elastomer actuation. N2 - Die Palette von elektro-mechanischen Aktuatoren, basierend auf dem Prinzip weicher dehnbarer Kondensatoren, scheint besonders für Anwendungen in der Medizin und für biomimetische Applikationen unbegrenzt. Diese Wandler zeichnen sich sowohl durch hohe Reversibilität bei großer mechanischer Deformation als auch durch ihre Flexibilität aus, wobei die mechanischen Deformationen durch elektrische Felder induziert werden. Die Notwendigkeit von hoher elektrischer Spannung zur Erzeugung dieser mechanischen Deformationen verzögert jedoch die technisch einfache und breite Markteinführung dieser Technologie. Diesem Problem kann durch eine gezielte Materialmodifikation begegnet werden. Eine Modifikation hat das Ziel, die relative Permittivität zu erhöhen, wobei die Flexibilität und die hohe elektrische Durchbruchsfeldstärke beibehalten werden sollten. Durch eine Materialmodifikation kann die Energiedichte des Materials bedeutend erhöht und somit die notwendige Betriebsspannung des Aktuators herabgesetzt werden. Eine Verbesserung der funktionalen Materialeigenschaften kann durch die Verwendung von Nanokompositen erzielt werden, welche die fundamentalen Eigenschaften der Nanopartikel, d.h. ein gutes Verhältnis von Oberfläche zu Volumen nutzen, um eine gezielte makroskopische Materialmodifikation zu bewirken. Diese Arbeit behandelt die Anwendung innovativer Strategien für die Erzeugung von Nanomaterialien mit hoher Permittivität. Die so erzeugten Materialien und deren relevante Aktuatorkenngrößen werden durch elektrische und mechanische Experimente vollständig erfasst. Mittels der klassischen Mischansätze zur Erzeugung von Kompositmaterialen mit hoher Permittivität konnte durch nichtleitendes Titaniumdioxid TiO2 (Rutile) in einem Thermoplastischen-Block-Co-Polymer SEBS (poly-styrene-co-ethylene-cobutylene-co-styrene) die Permittivität bereits um 370 % erhöht und die elektrische Energiedichte um 570 % gesteigert werden. Diese Veränderungen führten jedoch zu einem signifikanten Anstieg der Steifigkeit des Materials. Aufgrund der positiven Rückkopplung von elektrischen und mechanischen Eigenschaften des Kompositmaterials ermöglicht bereits dieser einfache Ansatz eine Verbesserung der Aktuation, bei einer 27 %-igen Reduktion der Aktuatorbetriebsspannung. Eine direkte Verwendung von leitfähigen Nanopartikeln kann ebenso zu einem Anstieg der relativen Permittivität beitragen, wobei jedoch die Leitfähigkeit dieser Nanopartikel bedeutende Wechselwirkungen verursacht, welche somit die Energiedichte des Materials negativ beeinflusst und die praktische Verwendung dieses Kompositsystems ausschließt. Als ein völlig neuer Ansatz zur Steigerung der relativen Permittivität und Energiedichte und abweichend vom klassischen Mischverfahren, wird die Herstellung eines "Molekularen Komposits", basierend auf einem chemischen Propfverfahren, präsentiert. In diesem Ansatz wird ein π-konjugiertes leitfähiges Polymer (PANI) an die Hauptkette des Elastomers der Polymermatrix gebunden. Die daraus resultierende Ladungsverteilung entlang der Elastomerhauptkette bewirkt eine 470 %-ige Steigerung der Permittivität des "Molekularen Komposits" im Vergleich zur Permittivität des unbehandelten Elastomermaterials. Aufgrund der Verkapselung der chemischen Bindungen der PANI-Kette entstehen kaum negative Rückwirkungen auf die elektrischen und mechanischen Eigenschaften des so erzeugten Komposits. Diese Materialeigenschaften resultieren in einem signifikanten Anstieg der Energiedichte des Materials. Das mittels dieses Verfahrens erzeugte Komposit zeigt sowohl eine Steigerung der Sensitivität der elektromechanischen Antwort (Reduktion des elektrischen Felds um 83 %) als auch eine bedeutende Steigerung der maximalen Aktuation (250 %). Die Ergebnisse und Ideen dieser Arbeit stellen einen wesentlichen Sprung im Verständnis zur Permittivitätssteigerung in Polymermaterialien dar und werden deshalb in der Erforschung und Entwicklung von Elastomeraktuatoren Beachtung finden. KW - dielektrische Elastomere KW - Nanokomposite KW - hohe Permittivität KW - elektrostatische Energiedichte KW - elektromechanische Reaktion KW - dielectric elastomers KW - nanocomposites KW - high permittivity KW - electrostatic energy density KW - electromechanical response Y1 - 2011 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-51194 ER - TY - JOUR A1 - Stete, Felix A1 - Schossau, Phillip A1 - Bargheer, Matias A1 - Koopman, Wouter-Willem Adriaan T1 - Size-Dependent coupling of Hybrid Core-Shell Nanorods BT - Toward Single-Emitter Strong-Coupling JF - The journal of physical chemistry : C, Nanomaterials and interfaces N2 - Owing to their ability of concentrating electromagnetic fields to subwavelength mode volumes, plasmonic nanoparticles foster extremely high light-matter coupling strengths reaching far into the strong-coupling regime of light matter interaction. In this article, we present an experimental investigation on the dependence of coupling strength on the geometrical size of the nanoparticle. The coupling strength for differently sized hybrid plasmon-core exciton-shell nanorods was extracted from the typical resonance anticrossing of these systems, obtained by controlled modification of the environment permittivity using layer-by-layer deposition of polyelectrolytes. The observed size dependence of the coupling strength can be explained by a simple model approximating the electromagnetic mode volume by the geometrical volume of the particle. On the basis of this model, the coupling strength for particles of arbitrary size can be predicted, including the particle size necessary to support single-emitter strong coupling. Y1 - 2018 U6 - https://doi.org/10.1021/acs.jpcc.8b04204 SN - 1932-7447 VL - 122 IS - 31 SP - 17976 EP - 17982 PB - American Chemical Society CY - Washington ER - TY - GEN A1 - Stete, Felix A1 - Schossau, Phillip Gerald A1 - Koopman, Wouter-Willem Adriaan A1 - Bargheer, Matias T1 - Size Dependence of the Coupling Strength in Plasmon-Exciton Nanoparticles T2 - Quantum Nano-Photonics N2 - The coupling between molecular excitations and nanoparticles leads to promising applications. It is for example used to enhance the optical cross-section of molecules in surface enhanced Raman scattering, Purcell enhancement or plasmon enhanced dye lasers. In a coupled system new resonances emerge resulting from the original plasmon (ωpl) and exciton (ωex) resonances as ω±=12(ωpl+ωex)±14(ωpl−ωex)2+g2−−−−−−−−−−−−−−−√, (1) where g is the coupling parameter. Hence, the new resonances show a separation of Δ = ω+ − ω− from which the coupling strength can be deduced from the minimum distance between the two resonances, Ω = Δ(ω+ = ω−). Y1 - 2018 SN - 978-94-024-1546-9 SN - 978-94-024-1544-5 SN - 978-94-024-1543-8 U6 - https://doi.org/10.1007/978-94-024-1544-5_26 SN - 1871-465X SP - 381 EP - 383 PB - Springer CY - Dordrecht ER - TY - INPR A1 - Pikovskij, Arkadij A1 - Zaks, Michael A. A1 - Feudel, Ulrike A1 - Kurths, Jürgen T1 - Singular continuous spectra in dissipative dynamics N2 - We demonstrate the occurrence of regimes with singular continuous (fractal) Fourier spectra in autonomous dissipative dynamical systems. The particular example in an ODE system at the accumulation points of bifurcation sequences associated to the creation of complicated homoclinic orbits. Two different machanisms responsible for the appearance of such spectra are proposed. In the first case when the geometry of the attractor is symbolically represented by the Thue-Morse sequence, both the continuous-time process and its descrete Poincaré map have singular power spectra. The other mechanism owes to the logarithmic divergence of the first return times near the saddle point; here the Poincaré map possesses the discrete spectrum, while the continuous-time process displays the singular one. A method is presented for computing the multifractal characteristics of the singular continuous spectra with the help of the usual Fourier analysis technique. T3 - NLD Preprints - 15 Y1 - 1995 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13787 ER - TY - GEN A1 - Sposini, Vittoria A1 - Metzler, Ralf A1 - Oshanin, Gleb T1 - Single-trajectory spectral analysis of scaled Brownian motion T2 - Postprints der Universität Potsdam Mathematisch-Naturwissenschaftliche Reihe N2 - Astandard approach to study time-dependent stochastic processes is the power spectral density (PSD), an ensemble-averaged property defined as the Fourier transform of the autocorrelation function of the process in the asymptotic limit of long observation times, T → ∞. In many experimental situations one is able to garner only relatively few stochastic time series of finite T, such that practically neither an ensemble average nor the asymptotic limit T → ∞ can be achieved. To accommodate for a meaningful analysis of such finite-length data we here develop the framework of single-trajectory spectral analysis for one of the standard models of anomalous diffusion, scaled Brownian motion.Wedemonstrate that the frequency dependence of the single-trajectory PSD is exactly the same as for standard Brownian motion, which may lead one to the erroneous conclusion that the observed motion is normal-diffusive. However, a distinctive feature is shown to be provided by the explicit dependence on the measurement time T, and this ageing phenomenon can be used to deduce the anomalous diffusion exponent.Wealso compare our results to the single-trajectory PSD behaviour of another standard anomalous diffusion process, fractional Brownian motion, and work out the commonalities and differences. Our results represent an important step in establishing singletrajectory PSDs as an alternative (or complement) to analyses based on the time-averaged mean squared displacement. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 753 KW - diffusion KW - anomalous diffusion KW - power spectral analysis KW - single trajectory analysis Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-436522 SN - 1866-8372 IS - 753 ER - TY - JOUR A1 - Sposini, Vittoria A1 - Metzler, Ralf A1 - Oshanin, Gleb T1 - Single-trajectory spectral analysis of scaled Brownian motion JF - New Journal of Physics N2 - Astandard approach to study time-dependent stochastic processes is the power spectral density (PSD), an ensemble-averaged property defined as the Fourier transform of the autocorrelation function of the process in the asymptotic limit of long observation times, T → ∞. In many experimental situations one is able to garner only relatively few stochastic time series of finite T, such that practically neither an ensemble average nor the asymptotic limit T → ∞ can be achieved. To accommodate for a meaningful analysis of such finite-length data we here develop the framework of single-trajectory spectral analysis for one of the standard models of anomalous diffusion, scaled Brownian motion.Wedemonstrate that the frequency dependence of the single-trajectory PSD is exactly the same as for standard Brownian motion, which may lead one to the erroneous conclusion that the observed motion is normal-diffusive. However, a distinctive feature is shown to be provided by the explicit dependence on the measurement time T, and this ageing phenomenon can be used to deduce the anomalous diffusion exponent.Wealso compare our results to the single-trajectory PSD behaviour of another standard anomalous diffusion process, fractional Brownian motion, and work out the commonalities and differences. Our results represent an important step in establishing singletrajectory PSDs as an alternative (or complement) to analyses based on the time-averaged mean squared displacement. KW - diffusion KW - anomalous diffusion KW - power spectral analysis KW - single trajectory analysis Y1 - 2019 U6 - https://doi.org/10.1088/1367-2630/ab2f52 SN - 1367-2630 VL - 21 PB - Deutsche Physikalische Gesellschaft ; IOP, Institute of Physics CY - Bad Honnef und London ER - TY - JOUR A1 - Raoufi, Meysam A1 - Hörmann, Ulrich A1 - Ligorio, Giovanni A1 - Hildebrandt, Jana A1 - Pätzel, Michael A1 - Schultz, Thorsten A1 - Perdigón-Toro, Lorena A1 - Koch, Norbert A1 - List-Kratochvil, Emil A1 - Hecht, Stefan A1 - Neher, Dieter T1 - Simultaneous effect of ultraviolet radiation and surface modification on the work function and hole injection properties of ZnO thin films JF - Physica Status Solidi. A , Applications and materials science N2 - The combined effect of ultraviolet (UV) light soaking and self-assembled monolayer deposition on the work function (WF) of thin ZnO layers and on the efficiency of hole injection into the prototypical conjugated polymer poly(3-hexylthiophen-2,5-diyl) (P3HT) is systematically investigated. It is shown that the WF and injection efficiency depend strongly on the history of UV light exposure. Proper treatment of the ZnO layer enables ohmic hole injection into P3HT, demonstrating ZnO as a potential anode material for organic optoelectronic devices. The results also suggest that valid conclusions on the energy-level alignment at the ZnO/organic interfaces may only be drawn if the illumination history is precisely known and controlled. This is inherently problematic when comparing electronic data from ultraviolet photoelectron spectroscopy (UPS) measurements carried out under different or ill-defined illumination conditions. KW - charge injection across hybrid interfaces KW - energy-level alignments KW - hybrid metal oxides KW - organic interfaces Y1 - 2020 U6 - https://doi.org/10.1002/pssa.201900876 SN - 1862-6300 SN - 1862-6319 VL - 217 IS - 5 SP - 1 EP - 6 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Castillo, Angelica M. A1 - Shprits, Yuri A1 - Ganushkina, Natalia A1 - Drozdov, Alexander A1 - Aseev, Nikita A1 - Wang, Dedong A1 - Dubyagin, Stepan T1 - Simulations of the inner magnetospheric energetic electrons using the IMPTAM-VERB coupled model JF - Journal of Atmospheric and Solar-Terrestrial Physics N2 - In this study, we present initial results of the coupling between the Inner Magnetospheric Particle Transport and Acceleration Model (IMPTAM) and the Versatile Electron Radiation Belt (VERB-3D) code. IMPTAM traces electrons of 10-100 keV energies from the plasma sheet (L = 9 Re) to inner L-shell regions. The flux evolution modeled by IMPTAM is used at the low energy and outer L* computational boundaries of the VERB code (assuming a dipole approximation) to perform radiation belt simulations of energetic electrons. The model was tested on the March 17th, 2013 storm, for a six-day period. Four different simulations were performed and their results compared to satellites observations from Van Allen probes and GOES. The coupled IMPTAM-VERB model reproduces evolution and storm-time features of electron fluxes throughout the studied storm in agreement with the satellite data (within similar to 0.5 orders of magnitude). Including dynamics of the low energy population at L* = 6.6 increases fluxes closer to the heart of the belt and has a strong impact in the VERB simulations at all energies. However, inclusion of magnetopause losses leads to drastic flux decreases even below L* = 3. The dynamics of low energy electrons (max. 10s of keV) do not affect electron fluxes at energies >= 900 keV. Since the IMPTAM-VERB coupled model is only driven by solar wind parameters and the Dst and Kp indexes, it is suitable as a forecasting tool. In this study, we demonstrate that the estimation of electron dynamics with satellite-data-independent models is possible and very accurate. KW - Electron populations KW - Radiation belts KW - IMPTAM KW - VERB Y1 - 2019 U6 - https://doi.org/10.1016/j.jastp.2019.05.014 SN - 1364-6826 SN - 1879-1824 VL - 191 PB - Elsevier CY - Oxford ER - TY - THES A1 - Uyaver, Sahin T1 - Simulation of annealed polyelectrolytes in poor solvents N2 - Polymere sind lange kettenartige Moleküle. Sie bestehen aus vielen elementaren chemischen Einheiten, den Monomeren, die durch kovalente Bindungen aneinander gekettet sind. Polyelektrolyte sind Polymere, die ionisierbare Monomeren enthalten. Aufgrund ihrer speziellen Eigenschaften sind Polyelektrolyte sowohl in der Molekular- und Zellbiologie von großen Bedeutung als auch in der Chemie großtechnisch relevant. Verglichen mit ungeladenen Polymeren sind Polyelektrolyte theoretisch noch wenig verstanden. Insbesondere gilt dies für Polyelektrolyte in sogenanntem schlechten Lösungsmittel. Ein schlechtes Lösungsmittel bewirkt eine effektive Anziehung zwischen den Monomeren. Für Polyelektrolyte in schlechtem Lösungsmittel kommt es daher zu einer Konkurrenz zwischen dieser Anziehung und der elektrostatischen Abstoßung. Geladene Polymere werden im Rahmen der chemischen Klassifikation in starke und schwache Polyelektrolyte unterschieden. Erstere zeigen vollständige Dissoziation unabhängig vom pH-Wert der Lösung. Die Position der Ladungen auf der Kette wird ausschließlich während der Polymersynthese festgelegt. In der Physik spricht man deshalb von Polyelektrolyten mit eingefrorener Ladungsverteilung (quenched polyelectrolytes). Im Falle von schwachen Polyelektrolyten ist die Ladungsdichte auf der Kette nicht konstant, sondern wird durch der pH-Wert der Lösung kontrolliert. Durch Rekombinations- und Dissoziationsprozesse sind die Ladungen auf der Kette beweglich. Im allgemeinen stellt sich eine inhomogene Gleichgewichtsverteilung ein, die mit der Struktur der Kette gekoppelt ist. Diese Polymere werden deshalb auch Polyelektrolyte mit Gleichgewichtsladungsverteilung (annealed polyelectrolytes) genannt. Wegen des zusätzlichen Freiheitsgrades in der Ladungsverteilung werden eine Reihe ungewöhnlicher Eigenschaften theoretisch vorhergesagt. Mit Hilfe von Simulationen ist es zum ersten Mal gelungen, zu zeigen daß 'annealed' Polyelektrolyte in relativ schlechtem Lösungsmittel einen diskontinuierlichen Phasenübergang durchlaufen, wenn ein kritischer pH-Werts der Lösung überschritten wird. Bei diesem Phasenübergang, gehen die Polyelektolyte von einer schwach geladenen kompakten globulären Struktur zu einer stark geladenen gestreckten Konfiguration über. Aufgrund theoretischer Vorhersagen wird erwartet, daß die globuläre Struktur in weniger schlechtem Lösungsmittel instabil wird und sich eine Perlenkettenkonfiguration ausbildet. Diese Vorhersage konnte für 'annealed' Polyelektrolyte mit den durchgeführten Simulationen zum ersten Mal bestätigt werden - inzwischen auch durch erste experimentelle Ergebnisse. Schließlich zeigen die Simulationen auch, daß annealed Polyelektrolyte bei einer kritischen Salzkonzentration in der Lösung einen scharfen Übergang zwischen einem stark geladenen gestreckten Zustand und einem schwach geladenen globulären Zustand aufweisen, wiederum in Übereinstimmung mit theoretischen Erwartungen. N2 - A polymer is a large molecule made up of many elementary chemical units, joined together by covalent bonds (for example, polyethylene). Polyelectrolytes (PELs) are polymer chains containing a certain amount of ionizable monomers. With their specific properties PELs acquire big importance in molecular and cell biology as well as in technology. Compared to neutral polymers the theory of PELs is less understood. In particular, this is valid for PELs in poor solvents. A poor solvent environment causes an effective attraction between monomers. Hence, for PELs in a poor solvent, there occurs a competition between attraction and repulsion. Strong or quenched PELs are completely dissociated at any accessible pH. The position of charges along the chain is fixed by chemical synthesis. On the other hand, in weak or annealed PELs dissociation of charges depends on solution pH. For the first time the simulation results have given direct evidence that at rather poor solvents an annealed PEL indeed undergoes a first-order phase transition when the chemical potential (solution pH) reaches at a certain value. The discontinuous transition occurs between a weakly charged compact globular structure and a strongly charged stretched configuration. At not too poor solvents theory predicts that globule would become unstable with respect to the formation of pearl-necklaces. The results show that pearl-necklaces exist in annealed PELs indeed. Furthermore, as predicted by theory, the simulation results have shown that annealed PELs display a sharp transition from a highly charged stretched state to a weakly charged globule at a critical salt concentration. KW - Polymer-Plastik KW - Polyelektrolyte KW - Simulation KW - polymer KW - polyelectrolytes KW - simulation Y1 - 2004 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-0001488 ER - TY - JOUR A1 - Eberhard, Julius A1 - Schaik, N. Loes M. B. A1 - Schibalski, Anett A1 - Gräff, Thomas T1 - Simulating future salinity dynamics in a coastal marshland under different climate scenarios JF - Vadose zone journal N2 - Salinization is a well-known problem in agricultural areas worldwide. In the last 20-30 yr, rising salinity in the upper, unconfined aquifer has been observed in the Freepsumer Meer, a grassland near the German North Sea coast. For investigating long-term development of salinity and water balance during 1961-2099, the one-dimensional Soil-Water-Atmosphere-Plant (SWAP) model was set up and calibrated for a soil column in the area. The model setup involves a deep aquifer as the source of salt through upward seepage. In the vertical salt transport equation, dispersion and advection are included. Six different regional outputs of statistical downscaling methods were used as climate scenarios. These comprise different rates of increasing surface temperature and different trends in seasonal rainfall. The simulation results exhibit opposing salinity trends for topsoil and deeper layers. Although projections of some scenarios entail decreasing salinities near the surface, most of them project a rise in subsoil salinity, with the strongest trends of up to +0.9 mg cm(-3) 100 yr(-1) at -65 cm. The results suggest that topsoil salinity trends in the study area are affected by the magnitude of winter rainfall trends, whereas high subsoil salinities correspond to low winter rainfall and high summer temperature. How these projected trends affect the vegetation and thereby future land use will depend on the future management of groundwater levels in the area. Y1 - 2020 U6 - https://doi.org/10.1002/vzj2.20008 SN - 1539-1663 VL - 19 IS - 1 PB - Wiley CY - Hoboken ER - TY - JOUR A1 - Bolotov, Maxim I. A1 - Smirnov, Lev A. A1 - Osipov, Grigory V. A1 - Pikovskij, Arkadij T1 - Simple and complex chimera states in a nonlinearly coupled oscillatory medium JF - Chaos : an interdisciplinary journal of nonlinear science N2 - We consider chimera states in a one-dimensional medium of nonlinear nonlocally coupled phase oscillators. In terms of a local coarse-grained complex order parameter, the problem of finding stationary rotating nonhomogeneous solutions reduces to a third-order ordinary differential equation. This allows finding chimera-type and other inhomogeneous states as periodic orbits of this equation. Stability calculations reveal that only some of these states are stable. We demonstrate that an oscillatory instability leads to a breathing chimera, for which the synchronous domain splits into subdomains with different mean frequencies. Further development of instability leads to turbulent chimeras. Published by AIP Publishing. Y1 - 2018 U6 - https://doi.org/10.1063/1.5011678 SN - 1054-1500 SN - 1089-7682 VL - 28 IS - 4 PB - American Institute of Physics CY - Melville ER - TY - GEN A1 - Stete, Felix A1 - Koopman, Wouter-Willem Adriaan A1 - Bargheer, Matias T1 - Signatures of strong coupling on nanoparticles BT - revealing absorption anticrossing by tuning the dielectric environment T2 - Quantum Nano-Photonics N2 - The electromagnetic coupling of molecular excitations to plasmonic nanoparticles offers a promising method to manipulate the light-matter interaction at the nanoscale. Plasmonic nanoparticles foster exceptionally high coupling strengths, due to their capacity to strongly concentrate the light-field to sub-wavelength mode volumes. A particularly interesting coupling regime occurs, if the coupling increases to a level such that the coupling strength surpasses all damping rates in the system. In this so-called strong-coupling regime hybrid light-matter states emerge, which can no more be divided into separate light and matter components. These hybrids unite the features of the original components and possess new resonances whose positions are separated by the Rabi splitting energy h Omega. Detuning the resonance of one of the components leads to an anticrossing of the two arising branches of the new resonances omega(+) and omega(-) with a minimal separation of Omega = omega(+) - omega(-). Y1 - 2018 SN - 978-94-024-1546-9 SN - 978-94-024-1544-5 SN - 978-94-024-1543-8 U6 - https://doi.org/10.1007/978-94-024-1544-5_53 SN - 1871-465X SP - 445 EP - 447 PB - Springer CY - Dordrecht ER - TY - THES A1 - Mari, Andrea T1 - Signatures of non-classicality in optomechanical systems T1 - Nicht klassische Merkmale in optomechanischen Systemen N2 - This thesis contains several theoretical studies on optomechanical systems, i.e. physical devices where mechanical degrees of freedom are coupled with optical cavity modes. This optomechanical interaction, mediated by radiation pressure, can be exploited for cooling and controlling mechanical resonators in a quantum regime. The goal of this thesis is to propose several new ideas for preparing meso- scopic mechanical systems (of the order of 10^15 atoms) into highly non-classical states. In particular we have shown new methods for preparing optomechani-cal pure states, squeezed states and entangled states. At the same time, proce-dures for experimentally detecting these quantum effects have been proposed. In particular, a quantitative measure of non classicality has been defined in terms of the negativity of phase space quasi-distributions. An operational al- gorithm for experimentally estimating the non-classicality of quantum states has been proposed and successfully applied in a quantum optics experiment. The research has been performed with relatively advanced mathematical tools related to differential equations with periodic coefficients, classical and quantum Bochner’s theorems and semidefinite programming. Nevertheless the physics of the problems and the experimental feasibility of the results have been the main priorities. N2 - Die vorliegende Arbeit besteht aus verschiedenen theoretischen Untersuchungen von optomechanischen Systemen, das heißt physikalische Bauteile bei denen mechanische Freiheitsgrade mit Lichtmoden in optischen Kavitäten gekoppelt sind. Diese optimechanischen Wechselwirkungen, die über den Strahlungsdruck vermittelt werden, lassen sich zur Kühlung und Kontrolle von mechanischen Resonatoren im Quantenregime verwenden. Das Ziel dieser Arbeit ist es, verschiedene neue Ideen für Methoden vorzuschlagen, mit denen sich mesoskopische mechanische Systeme (bestehend aus etwa 10^15 Atomen) in sehr nicht-klassischen Zuständen präparieren lassen. Außerdem werden Techniken beschrieben, mit denen sich diese Quateneffekte experimentell beobachten lassen. Insbesondere wird ein quantitatives Maß für Nichtklassizität auf der Basis von Quasiwahrscheinlichkeitsverteilungen im Phasenraum definiert und ein operationeller Algorithmus zu dessen experimenteller Beschrieben, der bereits erfolgreich in einem quantenoptischen Experiment eingesetzt wurde. KW - Quanten Optomechanik KW - gequetschte Zustände KW - nicht klassische Zustände KW - Verschränkung KW - Wigner Funktion KW - Quantum Optomechanics KW - squeezing entanglement KW - Wigner negativity KW - non-classicality Y1 - 2012 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-59814 ER - TY - JOUR A1 - Zou, Yong A1 - Thiel, M. A1 - Romano, Maria Carmen A1 - Kurths, Jürgen A1 - Bi, Q. T1 - Shrimp structure and associated dynamics in parametrically excited oscillators JF - International journal of bifurcation and chaos : in applied sciences and engineering N2 - We investigate the bifurcation structures in a two-dimensional parameter space (PS) of a parametrically excited system with two degrees of freedom both analytically and numerically. By means of the Renyi entropy of second order K-2, which is estimated from recurrence plots, we uncover that regions of chaotic behavior are intermingled with many complex periodic windows, such as shrimp structures in the PS. A detailed numerical analysis shows that, the stable solutions lose stability either via period doubling, or via intermittency when the parameters leave these shrimps in different directions, indicating different bifurcation properties of the boundaries. The shrimps of different sizes offer promising ways to control the dynamics of such a complex system. KW - bifurcation analysis KW - recurrence plot KW - period doubling KW - intermittency Y1 - 2006 U6 - https://doi.org/10.1142/S0218127406016987 SN - 0218-1274 VL - 16 IS - 12 SP - 3567 EP - 3579 PB - World Scientific Publ. Co CY - Singapore ER - TY - THES A1 - Soriano, Manuel Flores T1 - Short-term evolution and coexistence of photospheric and chromospheric activity on LQ Hydrae Y1 - 2016 ER - TY - JOUR A1 - Medrano-T., R. O. A1 - Baptista, Murilo da Silva A1 - Caldas, Ibere Luiz T1 - Shilnikov homoclinic orbit bifurcations in the Chua’s circuit JF - Chaos : an interdisciplinary journal of nonlinear science N2 - We analytically describe the complex scenario of homoclinic bifurcations in the Chua’s circuit. We obtain a general scaling law that gives the ratio between bifurcation parameters of different nearby homoclinic orbits. As an application of this theoretical approach, we estimate the number of higher order subsidiary homoclinic orbits that appear between two consecutive lower order subsidiary orbits. Our analytical finds might be valid for a large class of dynamical systems and are numerically confirmed in the parameter space of the Chua’s circuit. Shilnikov homoclinic orbits are trajectories that depart from a fixed saddle-focus point, with specific eigenvalues, and return to it after an infinite amount of time (that is also true to time reversal evolution). That results in an orbit that is unstable and has an infinite period. These two main characteristics contribute in the hardness for its observation in a dynamical system as well as in nature. However, its presence reveals fundamental characteristics of the system involved, as the existence of unstable periodic orbits embedded in a chaotic set. Once the unstable periodic orbits give invariants quantities of this set,1 the Shilnikov homoclinic orbits are also related to the characteristics of the chaotic set. Their connection with the fundamental dynamical properties is verified in a wide variety of systems. A series of numerical and experimental investigations reveal how Shilnikov homoclinic orbits, in the vicinity of a chaotic attractor, determine its dynamical and topological properties.4 Thus, the Shilnikov orbits are related to the returning time of the trajectory of a CO2 laser,5 also to the topology of a glow-discharge system.6 Moreover, some class of spiking neurons are modeled by chaos governed by such orbits,7,8 and their presence are connected to the intermittence present in rabbit arteries.9 These orbits are shown to be behind the mechanism of noise-induced phenomena,10 and they are also responsible for the dynamics of an electrochemical oscillator.11 In this work, we contribute to the understanding of how Shilnikov homoclinic orbits appear on the parameter space of systems as the ones above mentioned, by showing that these orbits are not only distributed following an universal rule but also exist for large parameter variations. We then confirm our previsions in the Chua’s circuit system Y1 - 2006 U6 - https://doi.org/10.1063/1.2401060 SN - 1054-1500 VL - 16 IS - 4 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Feldmann, Johannes A1 - Reese, Ronja A1 - Winkelmann, Ricarda A1 - Levermann, Anders T1 - Shear-margin melting causes stronger transient ice discharge than ice-stream melting in idealized simulations JF - The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union N2 - Basal ice-shelf melting is the key driver of Antarctica's increasing sea-level contribution. In diminishing the buttressing force of the ice shelves that fringe the ice sheet, the melting increases the ice discharge into the ocean. Here we contrast the influence of basal melting in two different ice-shelf regions on the time-dependent response of an isothermal, inherently buttressed ice-sheet-shelf system. In the idealized numerical simulations, the basal-melt perturbations are applied close to the grounding line in the ice-shelf's (1) ice-stream region, where the ice shelf is fed by the fastest ice masses that stream through the upstream bed trough and (2) shear margins, where the ice flow is slower. The results show that melting below one or both of the shear margins can cause a decadal to centennial increase in ice discharge that is more than twice as large compared to a similar perturbation in the ice-stream region. We attribute this to the fact that melt-induced ice-shelf thinning in the central grounding-line region is attenuated very effectively by the fast flow of the central ice stream. In contrast, the much slower ice dynamics in the lateral shear margins of the ice shelf facilitate sustained ice-shelf thinning and thereby foster buttressing reduction. Regardless of the melt location, a higher melt concentration toward the grounding line generally goes along with a stronger response. Our results highlight the vulnerability of outlet glaciers to basal melting in stagnant, buttressing-relevant ice-shelf regions, a mechanism that may gain importance under future global warming. Y1 - 2022 U6 - https://doi.org/10.5194/tc-16-1927-2022 SN - 1994-0416 SN - 1994-0424 VL - 16 IS - 5 SP - 1927 EP - 1940 PB - Copernicus CY - Göttingen ER - TY - JOUR A1 - Pasechnik, Sergey V. A1 - Shmeleva, Dina A1 - Saidgaziev, Ayvr Sh. A1 - Kharlamov, Semen A1 - Vasilieva, Aleksandra A. A1 - Santer, Svetlana T1 - Shear flows induced by electro-osmotic pumps in optofluidic liquid crystal cell for modulation of visible light and THz irradiation JF - Liquid Crystals and their Application : Russian Journal N2 - The work is devoted to the use of electrokinetic phenomena in liquid crystals to create a new class of microfluidics devices - optofluidics, designed to control electromagnetic radiation, including the THz frequency range. To achieve the goal, an optical method is used to study changes in the orientational structure in LC layers caused by a shear flow generated by electroosmotic pumps. Simula-tion of LC behaviour in an experimental cell containing electroosmotic pumps and flat layers of a nematic liquid crystal is fulfilled. The experimental depend-ences of the intensity of polarized radiation passing through flat LC layers on the control voltage applied to the electroosmotic pump and the results of calcu-lations of the hydrodynamic and mechano-optical characteristics of the experi-mental LC cell are presented. The propagation of THz irradiation across the multilayer structure of the optofluidic cell is considered taking into account the minimum number of re-reflections of waves from different layers and the ab-sorption of THz irradiation in a propylene and a liquid crystal. N2 - Работа посвящена использованию электрокинетических явлений в жидких кристаллах для создания нового класса микрофлюидных устройств – опто- флюидики, предназначенных для управления электромагнитным излуче- нием, в том числе терагерцового диапазона частот. Для достижения цели оптическим методом исследуются изменения ориентационной структуры в слоях ЖК, вызванные сдвиговым течением, генерируемым электроосмоти- ческими насосами. Проведено моделирование поведения ЖК в эксперимен- тальной ячейке, содержащей электроосмотические насосы и плоские слои нематического жидкого кристалла. Представлены экспериментальные за- висимости интенсивности поляризованного излучения, проходящего через плоские слои ЖК, от управляющего напряжения, подаваемого на электро- осмотический насос, и результаты расчетов гидродинамических и механо- оптических характеристик экспериментальной ЖК-ячейки. Рассмотрено распространение ТГц излучения по многослойной структуре оптофлюид- ной ячейки с учетом минимального числа переотражений волн от разных слоев и поглощения ТГц излучения в пропилене и жидком кристалле. KW - nematic liquid crystal KW - terahertz range KW - electrokinetic phenomena KW - osmotic flow KW - director configuration KW - optical irradiation intensity KW - E7 KW - polypropylene Y1 - 2022 U6 - https://doi.org/10.18083/LCAppl.2022.3.49 SN - 1991-3966 SN - 2499–9644 VL - 22 IS - 3 SP - 49 EP - 57 PB - Nanomaterials Research Institute CY - Ivanovo ER - TY - THES A1 - Pohl, Anna T1 - Shaping via binding BT - do mad proteins determine anisotropic growth of magnetite crystals? Y1 - 2018 ER - TY - JOUR A1 - Zeitz, Maria A1 - Levermann, Anders A1 - Winkelmann, Ricarda T1 - Sensitivity of ice loss to uncertainty in flow law parameters in an idealized one-dimensional geometry JF - The Cryosphere : TC ; an interactive open access journal of the European Geosciences Union N2 - Acceleration of the flow of ice drives mass losses in both the Antarctic and the Greenland Ice Sheet. The projections of possible future sea-level rise rely on numerical ice-sheet models, which solve the physics of ice flow, melt, and calving. While major advancements have been made by the ice-sheet modeling community in addressing several of the related uncertainties, the flow law, which is at the center of most process-based ice-sheet models, is not in the focus of the current scientific debate. However, recent studies show that the flow law parameters are highly uncertain and might be different from the widely accepted standard values. Here, we use an idealized flow-line setup to investigate how these uncertainties in the flow law translate into uncertainties in flow-driven mass loss. In order to disentangle the effect of future warming on the ice flow from other effects, we perform a suite of experiments with the Parallel Ice Sheet Model (PISM), deliberately excluding changes in the surface mass balance. We find that changes in the flow parameters within the observed range can lead up to a doubling of the flow-driven mass loss within the first centuries of warming, compared to standard parameters. The spread of ice loss due to the uncertainty in flow parameters is on the same order of magnitude as the increase in mass loss due to surface warming. While this study focuses on an idealized flow-line geometry, it is likely that this uncertainty carries over to realistic three-dimensional simulations of Greenland and Antarctica. Y1 - 2020 U6 - https://doi.org/10.5194/tc-14-3537-2020 SN - 1994-0416 SN - 1994-0424 VL - 14 IS - 10 SP - 3537 EP - 3550 PB - Copernicus CY - Göttingen ER -