TY - THES A1 - Regenstein, Wolfgang T1 - Absorptionsspektroskopische Untersuchungen zum Einfluß des Mediums und des Aggregatzustandes auf die Gestalt und Lage der Charge-Transfer-Bande N2 - An einigen CT-Modellkomplexen in verschiedenen Lösungsmitteln und bei Temperaturen von 113-300 K sollte der Einfluß der Umgebung auf die Form und Lage der Absorption von CT-Komplexen unterschiedlicher Bindungsfestigkeit untersucht werden. Dazu wurden bekannte Bandenprofilfunktionen auf ihre Anwendbar-keit geprüft. Da eine optimale Anpassung nicht möglich war, wurde eine neue Profilfunktion entwickelt, die eine bessere Beschreibung ergab. Nach der Bestimmung der Gleichgewichtskonstante und des Extink-tionskoeffizienten konnte mit der Profilfläche das Übergangsmoment berechnet werden. Die Lösungsmittelabhängigkeit wurde bei verschiedenen Brechzahlen und Dielektrizitätskonstanten untersucht. Für feste Komplexe wurde eine spezielle Präparationstechnik gewählt. Die beobachteten Feinstrukturen und der auftretende Streuuntergrund werden diskutiert. N2 - At some CT model complexes in various solvents and temperatures between 113- 300 K should investigate the influence of envirenment on the shape and position of CT complexes at various binding forces. Thereto known band profile functions were checked for their applicability. Because it was impossible to get an optimal accomodation a new profile function was developed, that results in a better description. After determination of equilibrium constant and extinction coefficient it was possible to calculate the transition moment with profiled area. The solvent dependence was investigated with various refractive indexes and dielectric constants. For solid complexes were selected a special preparation technique. The observed fine structures and the appered scattering underground were discussed. T2 - Absorption spectroscopic investigations on the influence of medium and aggregate state on the shape and position of CT bands KW - CT Komplex KW - Bandenprofil KW - Übergangsmoment KW - Lösungsmittelabhängigkeit KW - Präparation fester Komplexe KW - CT complex KW - band profile KW - transition moment KW - solvent dependence KW - solid complex preparation Y1 - 2021 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-496702 ER - TY - THES A1 - Regenstein, Wolfgang T1 - Fluoreszenzlöschung durch Elektronen- und Resonanzenergietransfer in Lösungen T1 - Fluorescence quenching through electron and resonant energy transfer in solutions N2 - Intermolekulare Desaktivierung zwischen einem angeregten Fluorophor und einem Löscher durch Elektronenübertragung kann mit dynamischer und statischer Löschung beschrieben werden. Es wird vorgeschlagen den dynamischen Löschprozess in Transport- und Wechselwirkungsphase einzuteilen. Ergebnisse der Löschung der N-Heteroarene durch Naphthalen bei hohen Löscherkonzentrationen werden mit der statischen Löschung beschrieben. Außerdem werden CT-Systeme untersucht. Nach einem Überblick über statische Modelle zum Resonanzenergietransfer wird ein aus der Treffertheorie abgeleitetes Modell vorgestellt und an Beispielen getestet. Die Experimente sind computergesteuert. N2 - The intermolecular deactivation through dynamic and static quenching can described with electron transition between an excited fluorophor and quencher. It is proposed to devide the dynamic quenching process in a transport and an interaction phase. Results oft the quenching of N-heteroarenes through naphthalenes by high concentrations are described with static quenching. CT-systems are also investigated. After giving an overview of statistical models of resonant energy transfer there is presented a model derived from the hit theory. The models were tested by examples. The experiments were executed computer-controlled. KW - Intermolekulare Desaktivierung KW - dynamische und statische Löschung KW - Transport- und Wechselwirkungsphase KW - Resonanzenergietransfer KW - statistische Modelle KW - Intermolecular deactivation KW - dynamic and static quenching KW - transport and interaction phase KW - resonant energy transfer KW - statistical models Y1 - 1989 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-491377 N1 - Überarbeitete Fassung der Habilitationsschrift aus dem Jahr 1989 ER - TY - INPR A1 - Feudel, Fred A1 - Seehafer, Norbert T1 - On the bifurcation phenomena in truncations of the 2D Navier-Stokes equations N2 - We have studied bifurcation phenomena for the incompressable Navier-Stokes equations in two space dimensions with periodic boundary conditions. Fourier representations of velocity and pressure have been used to transform the original partial differential equations into systems of ordinary differential equations (ODE), to which then numerical methods for the qualitative analysis of systems of ODE have been applied, supplemented by the simulative calculation of solutions for selected initial conditions. Invariant sets, notably steady states, have been traced for varying Reynolds number or strength of the imposed forcing, respectively. A complete bifurcation sequence leading to chaos is described in detail, including the calculation of the Lyapunov exponents that characterize the resulting chaotic branch in the bifurcation diagram. T3 - NLD Preprints - 1 Y1 - 1994 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13390 ER - TY - INPR A1 - Schwarz, Udo T1 - Einführung in die nichtlineare Dynamik N2 - Aus dem Inhalt: 1. Einführung 2. Motivation für die nichtlineare Dynamik 3. Logistische Abbildung (Parabel-Abbildung) 4. Lorenz-Gleichungen 5. Fraktale Selbstähnlichkeit 6. Die Brownsche Bewegung 7. Stöße & Billards 8. Körper mit gravitativer Wechselwirkung 9. Glossar 10. Turbo-Pascal-Texte 11. IDL-Texte 12. Reduce-Texte T3 - NLD Preprints - 8 Y1 - 1994 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13525 ER - TY - GEN A1 - Henkel, Carsten A1 - Steane, Andrew M. A1 - Kaiser, Robin A1 - Dalibard, Jean T1 - A modulated mirror for atomic interferometry N2 - A novel atomic beam splitter, using reflection of atoms off an evanescent light wave, is investigated theoretically. The intensity or frequency of the light is modulated in order to create sidebands on the reflected de Broglie wave. The weights and phases of the various sidevands are calculated using three different approaches: the Born approximation, a semiclassical path integral approach, and a numerical solution of the time-dependent Schrdinger equation. We show how this modulated mirror could be used to build practical atomic interferometers. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 102 Y1 - 1994 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-42279 ER - TY - GEN A1 - Henkel, Carsten A1 - Courtois, Jean-Yves A1 - Aspect, Alain T1 - Atomic diffraction by a thin phase grating N2 - We present a semiclassical perturbation method for the description of atomic diffraction by a weakly modulated potential. It proceeds in a way similar to the treatment of light diffraction by a thin phase grating, and consists in calculating the atomic wavefunction by means of action integrals along the classical trajectories of the atoms in the absence of the modulated part of the potential. The capabilities and the validity condition of the method are illustrated on the well-known case of atomic diffraction by a Gaussian standing wave. We prove that in this situation the perturbation method is equivalent to the Raman-Nath approximation, and we point out that the usually-considered Raman-Nath validity condition can lead to inaccuracies in the evaluation of the phases of the diffraction amplitudes. The method is also applied to the case of an evanescent wave reflection grating, and an analytical expression for the diffraction pattern at any incidence angle is obtained for the first time. Finally, the application of the method to other situations is briefly discussed. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 101 Y1 - 1994 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-42269 ER - TY - GEN A1 - Henkel, Carsten A1 - Courtois, Jean-Yves A1 - Kaiser, Robin A1 - Westbrook, C. A1 - Aspect, Alain T1 - Phase shifts of atomic de Broglie waves at an evanescent wave mirror N2 - A detailed theoretical investigation of the reflection of an atomic de Broglie wave at an evanescent wave mirror is presented. The classical and the semiclassical descriptions of the reflection process are reviewed, and a full wave-mechanical approach based on the analytical soution of the corresponding Schrödinger equation is presented. The phase shift at reflection is calculated exactly and interpreted in terms of instantaneous reflection of the atom at an effective mirror. Besides the semiclassical regime of reflection describable by the WKB method, a pure quantum regime of reflection is identified in the limit where the incident de Broglie wavelength is large compared to the evanescent wave decay length. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 103 Y1 - 1994 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-42289 ER - TY - INPR A1 - Pikovskij, Arkadij A1 - Feudel, Ulrike T1 - Characterizing strange nonchaotic attractors N2 - Strange nonchaotic attractors typically appear in quasiperiodically driven nonlinear systems. Two methods of their characterization are proposed. The first one is based on the bifurcation analysis of the systems, resulting from periodic approximations of the quasiperiodic forcing. Secondly, we propose th characterize their strangeness by calculating a phase sensitivity exponent, that measures the sensitivity with respect to changes of the phase of the external force. It is shown, that phase sensitivity appears if there is a non-zero probability for positive local Lyapunov exponents to occur. T3 - NLD Preprints - 2 Y1 - 1994 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13405 ER - TY - INPR A1 - Witt, Annette A1 - Kurths, Jürgen A1 - Krause, F. A1 - Fischer, K. T1 - On the validity of a model for the reversals of the Earth‘s magnetic field N2 - We have used techniques of nonlinear dynamics to compare a special model for the reversals of the Earth's magnetic field with the observational data. Although this model is rather simple, there is no essential difference to the data by means of well-known characteristics, such as correlation function and probability distribution. Applying methods of symbolic dynamics we have found that the considered model is not able to describe the dynamical properties of the observed process. These significant differences are expressed by algorithmic complexity and Renyi information. T3 - NLD Preprints - 4 Y1 - 1994 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13460 ER - TY - INPR A1 - Kurths, Jürgen A1 - Voss, A. A1 - Witt, Annette A1 - Saparin, P. A1 - Kleiner, H. J. A1 - Wessel, Niels T1 - Quantitative analysis of heart rate variability N2 - In the modern industrialized countries every year several hundred thousands of people die due to the sudden cardiac death. The individual risk for this sudden cardiac death cannot be defined precisely by common available, non-invasive diagnostic tools like Holter-monitoring, highly amplified ECG and traditional linear analysis of heart rate variability (HRV). Therefore, we apply some rather unconventional methods of nonlinear dynamics to analyse the HRV. Especially, some complexity measures that are basing on symbolic dynamics as well as a new measure, the renormalized entropy, detect some abnormalities in the HRV of several patients who have been classified in the low risk group by traditional methods. A combination of these complexity measures with the parameters in the frequency domain seems to be a promising way to get a more precise definition of the individual risk. These findings have to be validated by a representative number of patients. T3 - NLD Preprints - 5 Y1 - 1994 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13470 ER -