TY - GEN A1 - Spiekermann, Georg A1 - Harder, M. A1 - Gilmore, Keith A1 - Zalden, Peter A1 - Sahle, Christoph J. A1 - Petitgirard, Sylvain A1 - Wilke, Max A1 - Biedermann, Nicole A1 - Weis, Thomas A1 - Morgenroth, Wolfgang A1 - Tse, John S. A1 - Kulik, E. A1 - Nishiyama, Norimasa A1 - Yavaş, Hasan A1 - Sternemann, Christian T1 - Persistent Octahedral Coordination in Amorphous GeO₂ Up to 100 GPa by Kβ'' X-Ray Emission Spectroscopy T2 - Postprints der Universität Potsdam Mathematisch-Naturwissenschaftliche Reihe N2 - We measure valence-to-core x-ray emission spectra of compressed crystalline GeO₂ up to 56 GPa and of amorphous GeO₂ up to 100 GPa. In a novel approach, we extract the Ge coordination number and mean Ge-O distances from the emission energy and the intensity of the Kβ'' emission line. The spectra of high-pressure polymorphs are calculated using the Bethe-Salpeter equation. Trends observed in the experimental and calculated spectra are found to match only when utilizing an octahedral model. The results reveal persistent octahedral Ge coordination with increasing distortion, similar to the compaction mechanism in the sequence of octahedrally coordinated crystalline GeO₂ high-pressure polymorphs. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 699 KW - rutile-type KW - glass KW - crystalline KW - pressures KW - complexes KW - silicon KW - oxygen KW - SIO₂ KW - MO KW - CU Y1 - 2019 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-427755 SN - 1866-8372 IS - 699 ER - TY - GEN A1 - Pick, Leonie A1 - Effenberger, Frederic A1 - Zhelavskaya, Irina A1 - Korte, Monika T1 - A Statistical Classifier for Historical Geomagnetic Storm Drivers Derived Solely From Ground-Based Magnetic Field Measurements T2 - Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe N2 - Solar wind observations show that geomagnetic storms are mainly driven by interplanetary coronal mass ejections (ICMEs) and corotating or stream interaction regions (C/SIRs). We present a binary classifier that assigns one of these drivers to 7,546 storms between 1930 and 2015 using ground‐based geomagnetic field observations only. The input data consists of the long‐term stable Hourly Magnetospheric Currents index alongside the corresponding midlatitude geomagnetic observatory time series. This data set provides comprehensive information on the global storm time magnetic disturbance field, particularly its spatial variability, over eight solar cycles. For the first time, we use this information statistically with regard to an automated storm driver identification. Our supervised classification model significantly outperforms unskilled baseline models (78% accuracy with 26[19]% misidentified interplanetary coronal mass ejections [corotating or stream interaction regions]) and delivers plausible driver occurrences with regard to storm intensity and solar cycle phase. Our results can readily be used to advance related studies fundamental to space weather research, for example, studies connecting galactic cosmic ray modulation and geomagnetic disturbances. They are fully reproducible by means of the underlying open‐source software (Pick, 2019, http://doi.org/10.5880/GFZ.2.3.2019.003) T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 982 KW - geomagnetic observatory data KW - geomagnetic storm drivers KW - historical geomagnetic storms KW - supervised machine learning Y1 - 2020 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-474996 SN - 1866-8372 IS - 982 SP - 2000 EP - 2015 ER -