TY - JOUR A1 - Gruner, David A1 - Hainich, Rainer A1 - Sander, Andreas Alexander Christoph A1 - Shenar, Tomer A1 - Todt, Helge Tobias A1 - Oskinova, Lidia M. A1 - Ramachandran, Varsha A1 - Ayres, T. A1 - Hamann, Wolf-Rainer T1 - The extreme O-type spectroscopic binary HD 93129A A quantitative, multiwavelength analysis JF - Astronomy and astrophysics : an international weekly journal N2 - Context. HD 93129A was classified as the earliest O-type star in the Galaxy (O2 If*) and is considered as the prototype of its spectral class. However, interferometry shows that this object is a binary system, while recent observations even suggest a triple configuration. None of the previous spectral analyses of this object accounted for its multiplicity. With new high-resolution UV and optical spectra, we have the possibility to reanalyze this key object, taking its binary nature into account for the first time. Aims. We aim to derive the fundamental parameters and the evolutionary status of HD 93129A, identifying the contributions of both components to the composite spectrum Results. Despite the similar spectral types of the two components, we are able to find signatures from each of the components in the combined spectrum, which allows us to estimate the parameters of both stars. We derive log(L/L-circle dot) = 6.15, T-eff = 52 kK, and log (M)over dot = -4.7[M-circle dot yr(-1)] for the primary Aa, and log(L/L-circle dot) = 5.58, T-eff = 45 kK, and log (M)over dot = -5.8 [M(circle dot)yr(-1)] for the secondary Ab. Conclusions. Even when accounting for the binary nature, the primary of HD 93129A is found to be one of the hottest and most luminous O stars in our Galaxy. Based on the theoretical decomposition of the spectra, we assign spectral types O2 If* and O3 III(f*) to components Aa and Ab, respectively. While we achieve a good fit for a wide spectral range, specific spectral features are not fully reproduced. The data are not sufficient to identify contributions from a hypothetical third component in the system. KW - stars: individual: HD 93129A KW - stars: atmospheres KW - stars: fundamental parameters KW - stars: early-typeP Y1 - 2018 U6 - https://doi.org/10.1051/0004-6361/201833178 SN - 1432-0746 VL - 621 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Robrade, Jan A1 - Oskinova, Lidia M. A1 - Schmitt, J. H. M. M. A1 - Leto, Paolo A1 - Trigilio, C. T1 - Outstanding X-ray emission from the stellar radio pulsar CU Virginis JF - Astronomy and astrophysics : an international weekly journal N2 - Context. Among the intermediate-mass magnetic chemically peculiar (MCP) stars, CU Vir is one of the most intriguing objects. Its 100% circularly polarized beams of radio emission sweep the Earth as the star rotates, thereby making this strongly magnetic star the prototype of a class of nondegenerate stellar radio pulsars. While CU Vir is well studied in radio, its high-energy properties are not known. Yet, X-ray emission is expected from stellar magnetospheres and confined stellar winds. Aims. Using X-ray data we aim to test CU Vir for intrinsic X-ray emission and investigate mechanisms responsible for its generation. Methods. We present X-ray observations performed with XMM-Newton and Chandra and study obtained X-ray images, light curves, and spectra. Basic X-ray properties are derived from spectral modelling and are compared with model predictions. In this context we investigate potential thermal and nonthermal X-ray emission scenarios. Results. We detect an X-ray source at the position of CU Vir. With LX approximate to 3 x 10(28) erg s(-1) it is moderately X-ray bright, but the spectrum is extremely hard compared to other Ap stars. Spectral modelling requires multi-component models with predominant hot plasma at temperatures of about T-X = 25MK or, alternatively, a nonthermal spectral component. Both types of model provide a virtually equivalent description of the X-ray spectra. The Chandra observation was performed six years later than those by XMM-Newton, yet the source has similar X-ray flux and spectrum, suggesting a steady and persistent X-ray emission. This is further confirmed by the X-ray light curves that show only mild X-ray variability. Conclusions. CU Vir is also an exceptional star at X-ray energies. To explain its full X-ray properties, a generating mechanism beyond standard explanations, like the presence of a low-mass companion or magnetically confined wind-shocks, is required. Magnetospheric activity might be present or, as proposed for fast-rotating strongly magnetic Bp stars, the X-ray emission of CU Vir is predominantly auroral in nature. KW - individual: CU Vir KW - stars: activity KW - stars: chemically peculiar KW - stars: magnetic field KW - X-rays: stars Y1 - 2018 U6 - https://doi.org/10.1051/0004-6361/201833492 SN - 1432-0746 VL - 619 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Leto, Paolo A1 - Trigilio, C. A1 - Oskinova, Lidia M. A1 - Ignace, R. A1 - Buemi, C. S. A1 - Umana, G. A1 - Ingallinera, A. A1 - Leone, Francesco A1 - Phillips, N. M. A1 - Agliozzo, Claudia A1 - Todt, Helge Tobias A1 - Cerrigone, L. T1 - A combined multiwavelength VLA/ALMA/Chandra study unveils the complex magnetosphere of the B-type star HR5907 JF - Monthly notices of the Royal Astronomical Society N2 - We present new radio/millimeter measurements of the hot magnetic star HR5907 obtained with the VLA and ALMA interferometers. We find that HR5907 is the most radio luminous early type star in the cm-mm band among those presently known. Its multi-wavelength radio light curves are strongly variable with an amplitude that increases with radio frequency. The radio emission can be explained by the populations of the non-thermal electrons accelerated in the current sheets on the outer border of the magnetosphere of this fast-rotating magnetic star. We classify HR5907 as another member of the growing class of strongly magnetic fast-rotating hot stars where the gyro-synchrotron emission mechanism efficiently operates in their magnetospheres. The new radio observations of HR5907 are combined with archival X-ray data to study the physical condition of its magnetosphere. The X-ray spectra of HR5907 show tentative evidence for the presence of non-thermal spectral component. We suggest that non-thermal X-rays originate a stellar X-ray aurora due to streams of non-thermal electrons impacting on the stellar surface. Taking advantage of the relation between the spectral indices of the X-ray power-law spectrum and the non-thermal electron energy distributions, we perform 3-D modelling of the radio emission for HR5907. The wavelength-dependent radio light curves probe magnetospheric layers at different heights above the stellar surface. A detailed comparison between simulated and observed radio light curves leads us to conclude that the stellar magnetic field of HR 5907 is likely non-dipolar, providing further indirect evidence of the complex magnetic field topology of HR5907. KW - stars: chemically peculiar KW - stars: early-type KW - stars: individual: HR 5907 KW - stars: magnetic field KW - radio continuum: stars KW - X-rays: stars Y1 - 2018 U6 - https://doi.org/10.1093/mnras/sty244 SN - 0035-8711 SN - 1365-2966 VL - 476 IS - 1 SP - 562 EP - 579 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Oskinova, Lidia M. A1 - Bulik, Tomasz A1 - Gomez-Moran, Ada Nebot T1 - Infrared outbursts as potential tracers of common-envelope events in high-mass X-ray binary formation JF - Astronomy and astrophysics : an international weekly journal N2 - Context. Classic massive binary evolutionary scenarios predict that a transitional common-envelope (CE) phase could be preceded as well as succeeded by the evolutionary stage when a binary consists of a compact object and a massive star, that is, a high-mass X-ray binary (HMXB). The observational manifestations of common envelope are poorly constrained. We speculate that its ejection might be observed in some cases as a transient event at mid-infrared (IR) wavelengths. Aims. We estimate the expected numbers of CE ejection events and HMXBs per star formation unit rate, and compare these theoretical estimates with observations. Methods. We compiled a list of 85 mid-IR transients of uncertain nature detected by the Spitzer Infrared Intensive Transients Survey and searched for their associations with X-ray, optical, and UV sources. Results. Confirming our theoretical estimates, we find that only one potential HMXB may be plausibly associated with an IR-transient and tentatively propose that X-ray source NGC4490-X40 could be a precursor to the SPIRITS 16az event. Among other interesting sources, we suggest that the supernova remnant candidate [BWL2012] 063 might be associated with SPIRITS 16ajc. We also find that two SPIRITS events are likely associated with novae, and seven have potential optical counterparts. Conclusions. The massive binary evolutionary scenarios that involve CE events do not contradict currently available observations of IR transients and HMXBs in star-forming galaxies. KW - X-rays: binaries KW - stars: massive KW - infrared: general KW - infrared: galaxies Y1 - 2018 U6 - https://doi.org/10.1051/0004-6361/201832925 SN - 0004-6361 SN - 1432-0746 VL - 613 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - González-Galán, Ana A1 - Oskinova, Lidia M. A1 - Popov, Sergei B. A1 - Haberl, F. A1 - Kühnel, M. A1 - Gallagher, John S. A1 - Schurch, Matthew A1 - Guerrero, Martín A. T1 - A multiwavelength study of SXP 1062, the long-period X-ray pulsar associated with a supernova remnant JF - Monthly notices of the Royal Astronomical Society N2 - SXP 1062 is a Be X-ray binary (BeXB) located in the Small Magellanic Cloud. It hosts a long-period X-ray pulsar and is likely associated with the supernova remnant MCSNR J0127−7332. In this work we present a multiwavelength view on SXP 1062 in different luminosity regimes. We consider monitoring campaigns in optical (OGLE survey) and X-ray (Swift telescope). During these campaigns a tight coincidence of X-ray and optical outbursts is observed. We interpret this as typical Type I outbursts as often detected in BeXBs at periastron passage of the neutron star (NS). To study different X-ray luminosity regimes in depth, during the source quiescence we observed it with XMM–Newton while Chandra observations followed an X-ray outburst. Nearly simultaneously with Chandra observations in X-rays, in optical the RSS/SALT telescope obtained spectra of SXP 1062. On the basis of our multiwavelength campaign we propose a simple scenario where the disc of the Be star is observed face-on, while the orbit of the NS is inclined with respect to the disc. According to the model of quasi-spherical settling accretion our estimation of the magnetic field of the pulsar in SXP 1062 does not require an extremely strong magnetic field at the present time. KW - stars: neutron KW - pulsars: individual: SXP 1062 KW - galaxies: individual: Small Magellanic Cloud KW - X-rays: binaries Y1 - 2017 U6 - https://doi.org/10.1093/mnras/stx3127 SN - 0035-8711 SN - 1365-2966 VL - 475 IS - 2 SP - 2809 EP - 2821 PB - Oxford University Press CY - Oxford ER - TY - JOUR A1 - Martinez-Chicharro, M. A1 - Torrejon, J. M. A1 - Oskinova, Lidia M. A1 - Furst, F. A1 - Postnov, K. A1 - Rodes-Roca, J. J. A1 - Hainich, Rainer A1 - Bodaghee, A. T1 - Evidence of Compton cooling during an X-ray flare supports a neutron star nature of the compact object in 4U1700-37 JF - Monthly notices of the Royal Astronomical Society N2 - Based on new Chandra X-ray telescope data, we present empirical evidence of plasma Compton cooling during a flare in the non-pulsating massive X-ray binary 4U1700-37. This behaviour might be explained by quasi-spherical accretion on to a slowly rotating magnetized neutron star (NS). In quiescence, the NS in 4U1700-37 is surrounded by a hot radiatively cooling shell. Its presence is supported by the detection of mHz quasi-periodic oscillations likely produced by its convection cells. The high plasma temperature and the relatively low X-ray luminosity observed during the quiescence, point to a small emitting area similar to 1 km, compatible with a hotspot on an NS surface. The sudden transition from a radiative to a significantly more efficient Compton cooling regime triggers an episode of enhanced accretion resulting in a flare. During the flare, the plasma temperature drops quickly. The predicted luminosity for such transitions, similar to 3 x 10(35) erg s(-1), is very close to the luminosity of 4U1700-37 during quiescence. The transition may be caused by the accretion of a clump in the stellar wind of the donor star. Thus, a magnetized NS nature of the compact object is strongly favoured. KW - stars: individual: 4U1700-37 KW - V*V884 Sco KW - X-rays: binaries Y1 - 2017 U6 - https://doi.org/10.1093/mnrasl/slx165 SN - 0035-8711 SN - 1365-2966 VL - 473 IS - 1 SP - L74 EP - L78 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Torrejon, J. M. A1 - Reig, Pablo A1 - Fürst, F. A1 - Martinez-Chicharro, M. A1 - Postnov, K. A1 - Oskinova, Lidia M. T1 - NuSTAR rules out a cyclotron line in the accreting magnetar candidate 4U2206+54 JF - Monthly notices of the Royal Astronomical Society N2 - Based on our new NuSTAR X-ray telescope data, we rule out any cyclotron line up to 60 keV in the spectra of the high-mass X-ray binary 4U2206+54. In particular, we do not find any evidence of the previously claimed line around 30 keV, independently of the source flux, along the spin pulse. The spin period has increased significantly, since the last observation, up to 5750 +/- 10 s, confirming the rapid spin-down rate (nu)over dot = -1.8 x 10(-14) Hz s(-1). This behaviour might be explained by the presence of a strongly magnetized neutron star (B-s > several times 10(13) G) accreting from the slow wind of its main-sequence O9.5 companion. KW - Stars: individual: 4U2206+54, BD+53 2790 KW - X-rays: binaries Y1 - 2018 U6 - https://doi.org/10.1093/mnras/sty1628 SN - 0035-8711 SN - 1365-2966 VL - 479 IS - 3 SP - 3366 EP - 3372 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Massa, Derck A1 - Oskinova, Lidia M. A1 - Prinja, Raman A1 - Ignace, Richard T1 - Coordinated UV and X-Ray Spectroscopic Observations of the O-type Giant xi Per BT - the Connection between X-Rays and Large-scale Wind Structure JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - We present new, contemporaneous Hubble Space Telescope STIS and XMM-Newton observations of the O7. III(n) ((f)) star xi Per. We supplement the new data with archival IUE spectra, to analyze the variability of the wind lines and X-ray flux of xi Per. The variable wind of this star is known to have a 2.086-day periodicity. We use a simple, heuristic spot model that fits the low-velocity (near-surface) IUE wind line variability very well, to demonstrate that the low-velocity absorption in the new STIS spectra of N IV lambda 1718 and Si IV lambda 1402 vary with the same 2.086-day period. It is remarkable that the period and amplitude of the STIS data agree with those of the IUE spectra obtained 22 yr earlier. We also show that the time variability of the new XMM-Newton fluxes is also consistent with the 2.086-day period. Thus, our new, multiwavelength coordinated observations demonstrate that the mechanism that causes the UV wind line variability is also responsible for a significant fraction of the X-rays in single O stars. The sequence of events for the multiwavelength light-curve minima is Si IV lambda 1402, N IV lambda 1718, and X-ray flux, each separated by a phase of about 0.06 relative to the 2.086-day period. Analysis of the X-ray fluxes shows that they become softer as they weaken. This is contrary to expectations if the variability is caused by periodic excess absorption. Furthermore, the high-resolution X-ray spectra suggest that the individual emission lines at maximum are more strongly blueshifted. If we interpret the low-velocity wind line light curves in terms of our model, it implies that there are two bright regions, i.e., regions with less absorption, separated by 180 degrees, on the surface of the star. We note that the presence and persistence of two spots separated by 180 degrees suggest that a weak dipole magnetic field is responsible for the variability of the UV wind line absorption and X-ray flux in xi Per. KW - stars: activity KW - stars: early-type KW - stars: winds, outflows KW - ultraviolet: stars KW - X-rays: stars Y1 - 2019 U6 - https://doi.org/10.3847/1538-4357/ab0283 SN - 0004-637X SN - 1538-4357 VL - 873 IS - 1 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Oskinova, Lidia M. A1 - Feldmeier, Achim A1 - Hamann, Wolf-Rainer T1 - High-resolution X-ray spectroscopy of bright O-type stars JF - Monthly notices of the Royal Astronomical Society N2 - Archival X-ray spectra of the four prominent single, non-magnetic O stars zeta Pup, zeta Ori, xi Per and zeta Oph, obtained in high resolution with Chandra HETGS/MEG have been studied. The resolved X-ray emission line profiles provide information about the shocked, hot gas which emits the X-radiation, and about the bulk of comparably cool stellar wind material which partly absorbs this radiation. In this paper, we synthesize X-ray line profiles with a model of a clumpy stellar wind. We find that the geometrical shape of the wind inhomogeneities is important: better agreement with the observations can be achieved with radially compressed clumps than with spherical clumps. The parameters of the model, i.e. chemical abundances, stellar radius, mass-loss rate and terminal wind velocity, are taken from existing analyses of UV and optical spectra of the programme stars. On this basis, we also calculate the continuum-absorption coefficient of the cool-wind material, using the Potsdam Wolf-Rayet (POWR) model atmosphere code. The radial location of X-ray emitting gas is restricted from analysing the FIR line ratios of helium-like ions. The only remaining free parameter of our model is the typical distance between the clumps; here, we assume that at any point in the wind there is one clump passing by per one dynamical time-scale of the wind. The total emission in a model line is scaled to the observation. There is a good agreement between synthetic and observed line profiles. We conclude that the X-ray emission line profiles in O stars can be explained by hot plasma embedded in a cool wind which is highly clumped in the form of radially compressed shell fragments. KW - stars : individual : zeta Pup KW - stars : individual : zeta Ori KW - stars : individual : xi Per KW - stars : individual : zeta Oph KW - X-rays : stars Y1 - 2006 U6 - https://doi.org/10.1111/j.1365-2966.2006.10858.x SN - 0035-8711 VL - 372 SP - 313 EP - 326 PB - Oxford University Press CY - Oxford ER - TY - GEN A1 - Kubatova, Brankica A1 - Hamann, Wolf-Rainer A1 - Kubat, Jiri A1 - Oskinova, Lidia M. T1 - 3D Monte Carlo Radiative Transfer in Inhomogeneous Massive Star Winds BT - Application to Resonance Line Formation T2 - Radiative signatures from the cosmos N2 - Already for decades it has been known that the winds of massive stars are inhomogeneous (i.e. clumped). To properly model observed spectra of massive star winds it is necessary to incorporate the 3-D nature of clumping into radiative transfer calculations. In this paper we present our full 3-D Monte Carlo radiative transfer code for inhomogeneous expanding stellar winds. We use a set of parameters to describe dense as well as the rarefied wind components. At the same time, we account for non-monotonic velocity fields. We show how the 3-D density and velocity wind inhomogeneities strongly affect the resonance line formation. We also show how wind clumping can solve the discrepancy between P v and H alpha mass-loss rate diagnostics. Y1 - 2019 SN - 978-1-58381-925-8 SN - 1050-3390 VL - 519 SP - 209 EP - 212 PB - Astronomical soc pacific CY - San Fransisco ER - TY - JOUR A1 - Hainich, Rainer A1 - Oskinova, Lidia M. A1 - Shenar, Tomer A1 - Marchant Campos, Pablo A1 - Eldridge, J. J. A1 - Sander, Andreas Alexander Christoph A1 - Hamann, Wolf-Rainer A1 - Langer, Norbert A1 - Todt, Helge Tobias T1 - Observational properties of massive black hole binary progenitors JF - Astronomy and astrophysics : an international weekly journal N2 - Context: The first directly detected gravitational waves (GW 150914) were emitted by two coalescing black holes (BHs) with masses of ≈ 36 M⊙ and ≈ 29 M⊙. Several scenarios have been proposed to put this detection into an astrophysical context. The evolution of an isolated massive binary system is among commonly considered models. Aims: Various groups have performed detailed binary-evolution calculations that lead to BH merger events. However, the question remains open as to whether binary systems with the predicted properties really exist. The aim of this paper is to help observers to close this gap by providing spectral characteristics of massive binary BH progenitors during a phase where at least one of the companions is still non-degenerate. Methods: Stellar evolution models predict fundamental stellar parameters. Using these as input for our stellar atmosphere code (Potsdam Wolf-Rayet), we compute a set of models for selected evolutionary stages of massive merging BH progenitors at different metallicities. Results: The synthetic spectra obtained from our atmosphere calculations reveal that progenitors of massive BH merger events start their lives as O2-3V stars that evolve to early-type blue supergiants before they undergo core-collapse during the Wolf-Rayet phase. When the primary has collapsed, the remaining system will appear as a wind-fed high-mass X-ray binary. Based on our atmosphere models, we provide feedback parameters, broad band magnitudes, and spectral templates that should help to identify such binaries in the future. Conclusions: While the predicted parameter space for massive BH binary progenitors is partly realized in nature, none of the known massive binaries match our synthetic spectra of massive BH binary progenitors exactly. Comparisons of empirically determined mass-loss rates with those assumed by evolution calculations reveal significant differences. The consideration of the empirical mass-loss rates in evolution calculations will possibly entail a shift of the maximum in the predicted binary-BH merger rate to higher metallicities, that is, more candidates should be expected in our cosmic neighborhood than previously assumed. KW - gravitational waves KW - binaries: close KW - stars: early-type KW - stars: atmospheres KW - stars: winds KW - outflows KW - stars: mass-loss Y1 - 2018 U6 - https://doi.org/10.1051/0004-6361/201731449 SN - 1432-0746 VL - 609 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Fulmer, Leah M. A1 - Gallagher, John S. A1 - Hamann, Wolf-Rainer A1 - Oskinova, Lidia M. A1 - Ramachandran, Varsha T1 - Testing massive star evolution, star-formation history, and feedback at low metallicity BT - photometric analysis of OB stars in the SMC Wing JF - Astronomy and astrophysics : an international weekly journal N2 - Context. The supergiant ionized shell SMC-SGS 1 (DEM 167), which is located in the outer Wing of the Small Magellanic Cloud (SMC), resembles structures that originate from an energetic star-formation event and later stimulate star formation as they expand into the ambient medium. However, stellar populations within and surrounding SMC-SGS 1 tell a different story. Aims. We present a photometric study of the stellar population encompassed by SMC-SGS 1 in order to trace the history of such a large structure and its potential influence on star formation within the low-density, low-metallicity environment of the SMC. Methods. For a stellar population that is physically associated with SMC-SGS 1, we combined near-ultraviolet (NUV) photometry from the Galaxy Evolution Explorer with archival optical (V-band) photometry from the ESO Danish 1.54 m Telescope. Given their colors and luminosities, we estimated stellar ages and masses by matching observed photometry to theoretical stellar isochrone models. Results. We find that the investigated region supports an active, extended star-formation event spanning similar to 25-40 Myr ago, as well as continued star formation into the present. Using a standard initial mass function, we infer a lower bound on the stellar mass from this period of similar to 3 x 10(4) M-circle dot, corresponding to a star-formation intensity of similar to 6 x 10(-3) M-circle dot kpc(-2) yr(-1). Conclusions. The spatial and temporal distributions of young stars encompassed by SMC-SGS 1 imply a slow, consistent progression of star formation over millions of years. Ongoing star formation, both along the edge and interior to SMC-SGS 1, suggests a combined stimulated and stochastic mode of star formation within the SMC Wing. We note that a slow expansion of the shell within this low-density environment may preserve molecular clouds within the volume of the shell, leaving them to form stars even after nearby stellar feedback expels local gas and dust. KW - galaxies KW - stellar content KW - stars KW - formation KW - individual KW - Small KW - Magellanic Cloud Y1 - 2020 U6 - https://doi.org/10.1051/0004-6361/201834314 SN - 0004-6361 SN - 1432-0746 VL - 633 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Toalá, Jesús Alberto A1 - Bowman, Dominic A1 - Van Reeth, Timothy A1 - Todt, Helge Tobias A1 - Dsilva, Karan A1 - Shenar, Tomer A1 - Koenigsberger, Gloria Suzanne A1 - Estrada-Dorado, Sandino A1 - Oskinova, Lidia M. A1 - Hamann, Wolf-Rainer T1 - Multiple variability time-scales of the early nitrogen-rich Wolf-Rayet star WR 7 JF - Monthly notices of the Royal Astronomical Society N2 - We present the analysis of the optical variability of the early, nitrogen-rich Wolf-Rayet (WR) star WR 7. The analysis of multisector Transiting Exoplanet Survey Satellite (TESS) light curves and high-resolution spectroscopic observations confirm multiperiodic variability that is modulated on time-scales of years. We detect a dominant period of 2.6433 +/- 0.0005 d in the TESS sectors 33 and 34 light curves in addition to the previously reported high-frequency features from sector 7. We discuss the plausible mechanisms that may be responsible for such variability in WR 7, including pulsations, binarity, co-rotating interaction regions (CIRs), and clumpy winds. Given the lack of strong evidence for the presence of a stellar or compact companion, we suggest that WR 7 may pulsate in quasi-coherent modes in addition to wind variability likely caused by CIRs on top of stochastic low-frequency variability. WR 7 is certainly a worthy target for future monitoring in both spectroscopy and photometry to sample both the short (less than or similar to 1 d) and long (greater than or similar to 1000 d) variability time-scales. KW - stars: atmospheres KW - stars: evolution KW - stars: individual: WR 7 KW - stars: winds KW - outflows KW - stars: Wolft-Rayet Y1 - 2022 U6 - https://doi.org/10.1093/mnras/stac1455 SN - 0035-8711 SN - 1365-2966 VL - 514 IS - 2 SP - 2269 EP - 2277 PB - Oxford University Press CY - Oxford ER - TY - JOUR A1 - Oskinova, Lidia M. A1 - Schaerer, Daniel T1 - Ionization of He II in star-forming galaxies by X-rays from cluster winds and superbubbles JF - Astronomy and astrophysics : an international weekly journal N2 - The nature of the sources powering nebular He II emission in star-forming galaxies remains debated, and various types of objects have been considered, including Wolf-Rayet stars, X-ray binaries, and Population III stars. Modern X-ray observations show the ubiquitous presence of hot gas filling star-forming galaxies. We use a collisional ionization plasma code to compute the specific He II ionizing flux produced by hot gas and show that if its temperature is not too high (less than or similar to 2.5 MK), then the observed levels of soft diffuse X-ray radiation could explain He II ionization in galaxies. To gain a physical understanding of this result, we propose a model that combines the hydrodynamics of cluster winds and hot superbubbles with observed populations of young massive clusters in galaxies. We find that in low-metallicity galaxies, the temperature of hot gas is lower and the production rate of He II ionizing photons is higher compared to high-metallicity galaxies. The reason is that the slower stellar winds of massive stars in lower-metallicity galaxies input less mechanical energy in the ambient medium. Furthermore, we show that ensembles of star clusters up to similar to 10-20 Myr old in galaxies can produce enough soft X-rays to induce nebular He II emission. We discuss observations of the template low-metallicity galaxy I Zw 18 and suggest that the He II nebula in this galaxy is powered by a hot superbubble. Finally, appreciating the complex nature of stellar feedback, we suggest that soft X-rays from hot superbubbles are among the dominant sources of He II ionizing flux in low-metallicity star-forming galaxies. KW - galaxies KW - ISM KW - high-redshift KW - bubbles KW - X-rays Y1 - 2022 U6 - https://doi.org/10.1051/0004-6361/202142520 SN - 0004-6361 SN - 1432-0746 VL - 661 PB - EDP Sciences CY - Les Ulis ER - TY - THES A1 - Banerjee, Abhirup T1 - Characterizing the spatio-temporal patterns of extreme events BT - from recurrence to prediction N2 - Over the past decades, there has been a growing interest in ‘extreme events’ owing to the increasing threats that climate-related extremes such as floods, heatwaves, droughts, etc., pose to society. While extreme events have diverse definitions across various disciplines, ranging from earth science to neuroscience, they are characterized mainly as dynamic occurrences within a limited time frame that impedes the normal functioning of a system. Although extreme events are rare in occurrence, it has been found in various hydro-meteorological and physiological time series (e.g., river flows, temperatures, heartbeat intervals) that they may exhibit recurrent behavior, i.e., do not end the lifetime of the system. The aim of this thesis to develop some sophisticated methods to study various properties of extreme events. One of the main challenges in analyzing such extreme event-like time series is that they have large temporal gaps due to the paucity of the number of observations of extreme events. As a result, existing time series analysis tools are usually not helpful to decode the underlying information. I use the edit distance (ED) method to analyze extreme event-like time series in their unaltered form. ED is a specific distance metric, mainly designed to measure the similarity/dissimilarity between point process-like data. I combine ED with recurrence plot techniques to identify the recurrence property of flood events in the Mississippi River in the United States. I also use recurrence quantification analysis to show the deterministic properties and serial dependency in flood events. After that, I use this non-linear similarity measure (ED) to compute the pairwise dependency in extreme precipitation event series. I incorporate the similarity measure within the framework of complex network theory to study the collective behavior of climate extremes. Under this architecture, the nodes are defined by the spatial grid points of the given spatio-temporal climate dataset. Each node is associated with a time series corresponding to the temporal evolution of the climate observation at that grid point. Finally, the network links are functions of the pairwise statistical interdependence between the nodes. Various network measures, such as degree, betweenness centrality, clustering coefficient, etc., can be used to quantify the network’s topology. We apply the methodology mentioned above to study the spatio-temporal coherence pattern of extreme rainfall events in the United States and the Ganga River basin, which reveals its relation to various climate processes and the orography of the region. The identification of precursors associated with the occurrence of extreme events in the near future is extremely important to prepare the masses for an upcoming disaster and mitigate the potential risks associated with such events. Under this motivation, I propose an in-data prediction recipe for predicting the data structures that typically occur prior to extreme events using the Echo state network, a type of Recurrent Neural Network which is a part of the reservoir computing framework. However, unlike previous works that identify precursory structures in the same variable in which extreme events are manifested (active variable), I try to predict these structures by using data from another dynamic variable (passive variable) which does not show large excursions from the nominal condition but carries imprints of these extreme events. Furthermore, my results demonstrate that the quality of prediction depends on the magnitude of events, i.e., the higher the magnitude of the extreme, the better is its predictability skill. I show quantitatively that this is because the input signals collectively form a more coherent pattern for an extreme event of higher magnitude, which enhances the efficiency of the machine to predict the forthcoming extreme events. N2 - In den letzten Jahrzehnten hat das Interesse an ‘Extremereignissen’ aufgrund der zunehmenden Bedrohung, die klimabedingte Extreme wie Überschwemmungen, Hitzewellen, Dürren usw. für die Gesellschaft darstellen, zugenommen. Obwohl Extremereignisse in verschiedenen Disziplinen - von der Geowissenschaft bis zu den Neurowissenschaften - unterschiedlich definiert werden, werden sie hauptsächlich als dynamische Ereignisse innerhalb eines begrenzten Zeitrahmens charakterisiert, die das normale Funktionieren eines Systems beeinträchtigen. Obwohl Extremereignisse selten vorkommen, wurde festgestellt, dass verschiedene hydro-meteorologische und physiologische Zeitreihen (z. B. Stromabflussmengen, Temperaturen, Herzschlagintervalle) rekurrentes Verhalten. Das heißt, sie enden nicht an der Lebensdauer des Systems. Das Ziel dieser Arbeit ist es, fortschrittliche Methoden zur Untersuchung verschiedener Eigenschaften von Extremereignissen zu entwickeln. Eine der größten Herausforderungen bei der Analyse solcher extremen Ereignisse ist, dass sie große zeitliche Lücken aufweisen, da die Anzahl beobachteter Extremereignissen gering ist. Bestehende Zeitreihenanalysetools sind daher in der Regel nicht hilfreich, um die zugrundeliegenden Informationen zu entschlüsseln. Ich verwende die Edit-Distanz (ED) Methode, um extremeereignisähnliche Zeitreihen in ihrer unveränderten Form zu analysieren. ED ist eine spezielle Abstandsmetrik, die hauptsächlich zur Messung der Ähnlichkeit/Unähnlichkeit zwischen punktprozessähnlichen Daten entwickelt wurde. Ich kombiniere ED mit Rekurrenzplots, um die Wiederkehr-Eigenschaften von Hochwasserereignissen am Mississippi in den Vereinigten Staaten zu ermitteln. Außerdem werte ich die Wiederkehr-Eigenschaften quantitativ aus, um die deterministische Charakteristik und die serielle Abhängigkeit bei Hochwasserereignissen aufzuzeigen. Anschließend verwende ich dieses nichtlineare Ähnlichkeitsmaß(ED), um die paarweise Abhängigkeit in extremen Niederschlagsereignisreihen zu berechnen. Ich verknüpfe das Ähnlichkeitsmaß mit der Theorie komplexer Netzwerke, um das kollektive Verhalten von Klimaextremen zu untersuchen. In diesem Fall werden die Knoten durch die räumlichen Gitterpunkte des zu untersuchenden raumzeitlichen Klimadatensatzes definiert. Jeder Knoten repräsentiert eine Zeitreihe, die die zeitliche Entwicklung der Klimabeobachtung an diesem Gitterpunkt beschreibt. Schließlich sind die Netzwerkverbindungen Funktionen der paarweisen statistischen Interdependenz zwischen den Knotenpunkten. Zur Quantifizierung der Netztopologie können verschiedene Netzwerkmaße wie unter anderem der Grad, die Betweenness-Zentralität, oder der Clustering-Koeffizient verwendet werden. Wir wenden die oben erwähnte Methodik an, um das raumzeitliche Kohärenzmuster extremer Niederschlagsereignisse in den Vereinigten Staaten und im Einzugsgebiet des Ganges zu untersuchen. Die Ergebnisse zeigen, dass ein Zusammenhang zwischen dem Kohärenzmuster und verschiedenen Klimaprozessen und der Orographie der Region besteht. Die Identifizierung von Vorläufern, die mit dem Auftreten von Extremereignissen in naher Zukunft verbunden sind, ist äußerst wichtig, um die Bevölkerung auf eine bevorstehende Katastrophe vorzubereiten und potenziell resultierende Risiken zu mindern. Deshalb schlage ich ein datenbasiertes Vorhersageverfahren zur Bestimmung der Datenstrukturen vor, die typischerweise vor extremen Ereignissen auftreten. Das Verfahren basiert auf dem Echo-State Netzwerk, einem rekurrenten neuronalen Netz, das dem Reservoir-Computing zugeordnet wird. Im Gegensatz zu früheren Arbeiten, die Vorläuferstrukturen in der Variablen identifizieren, in der sich Extremereignisse manifestieren (aktive Variable), versuche ich die Strukturen anhand anderer dynamischer Variablen (passive Variablen) vorherzusagen. Diese Variablen weichen selbst nicht sonderlich von ihrem eigenen Sollzustand ab, aber sie besitzen eine Aussagekraft gegenüber den Extremereignissen. Meine Ergebnisse zeigen, dass die Qualität der Vorhersage von der Magnitude der Ereignisse abhängt, d.h. je extremer ein Ereignis ist, desto besser kann es vorhergesagt werden. Ich belege quantitativ, dass dieser Zusammenhang darauf basiert, dass die gesammelten Eingangssignale aussagekräftigere Kohärenzmuster für Extremereignisse hoher Magnitude bilden. Dies erhöht die Wirksamkeit des Ansatzes bei der Vorhersage bevorstehender Extremereignisse. KW - extreme events KW - Extremereignisse KW - floods KW - extreme precipitation KW - edit distance KW - recurrence plot KW - complex network KW - echo state network KW - Überschwemmungen KW - Extremniederschläge KW - Edit-Distanz KW - Rekurrenzplot KW - komplexes Netzwerk KW - Echo-State Netzwerk Y1 - 2022 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-559839 ER - TY - THES A1 - Novakovic-Marinkovic, Nina T1 - Optical control of bubble domains and skyrmions in thin films T1 - Optische Kontrolle von Blasendomänen und Skyrmionen in dünnen Schichten N2 - Laser induced switching offers an attractive possibility to manipulate small magnetic domains for prospective memory and logic devices on ultrashort time scales. Moreover, optical control of magnetization without high applied magnetic fields allows manipulation of magnetic domains individually and locally, without expensive heat dissipation. One of the major challenges for developing novel optically controlled magnetic memory and logic devices is reliable formation and annihilation of non-volatile magnetic domains that can serve as memory bits in ambient conditions. Magnetic skyrmions, topologically nontrivial spin textures, have been studied intensively since their discovery due to their stability and scalability in potential spintronic devices. However, skyrmion formation and, especially, annihilation processes are still not completely understood and further investigation on such mechanisms are needed. The aim of this thesis is to contribute to better understanding of the physical processes behind the optical control of magnetism in thin films, with the goal of optimizing material parameters and methods for their potential use in next generation memory and logic devices. First part of the thesis is dedicated to investigation of all-optical helicity-dependent switching (AO-HDS) as a method for magnetization manipulation. AO-HDS in Co/Pt multilayer and CoFeB alloys with and without the presence of Dzyaloshinskii-Moriya interaction (DMI), which is a type of exchange interaction, have been investigated by magnetic imaging using photo-emission electron microscopy (PEEM) in combination with X-ray magnetic circular dichroism (XMCD). The results show that in a narrow range of the laser fluence, circularly polarized laser light induces a drag on domain walls. This enables a local deterministic transformation of the magnetic domain pattern from stripes to bubbles in out-of-plane magnetized Co/Pt multilayers, only controlled by the helicity of ultrashort laser pulses. The temperature and characteristic fields at which the stripe-bubble transformation occurs has been calculated using theory for isolated magnetic bubbles, using as parameters experimentally determined average size of stripe domains and the magnetic layer thickness. The second part of the work aims at purely optical formation and annihilation of magnetic skyrmions by a single laser pulse. The presence of a skyrmion phase in the investigated CoFeB alloys was first confirmed using a Kerr microscope. Then the helicity-dependent skyrmion manipulation was studied using AO-HDS at different laser fluences. It was found that formation or annihilation individual skyrmions using AO-HDS is possible, but not always reliable, as fluctuations in the laser fluence or position can easily overwrite the helicity-dependent effect of AO-HDS. However, the experimental results and magnetic simulations showed that the threshold values for the laser fluence for the formation and annihilation of skyrmions are different. A higher fluence is required for skyrmion formation, and existing skyrmions can be annihilated by pulses with a slightly lower fluence. This provides a further option for controlling formation and annihilation of skyrmions using the laser fluence. Micromagnetic simulations provide additional insights into the formation and annihilation mechanism. The ability to manipulate the magnetic state of individual skyrmions is of fundamental importance for magnetic data storage technologies. Our results show for the first time that the optical formation and annihilation of skyrmions is possible without changing the external field. These results enable further investigations to optimise the magnetic layer to maximise the energy gap between the formation and annihilation barrier. As a result, unwanted switching due to small laser fluctuations can be avoided and fully deterministic optical switching can be achieved. N2 - Laser induziertes Schalten bietet eine attraktive Möglichkeit zur Manipulation kleiner magnetischer Domänen für zukünftige Speicher- und Logikbauteile auf ultrakurzen Zeitskalen. Darüber hinaus ermöglicht die rein optische Kontrolle der Magnetisierung ohne hohe angelegte Magnetfelder eine individuelle und lokale Manipulation magnetischer Domänen ohne teure Wärmeverluste. Eine der größten Herausforderungen bei der Entwicklung neuartiger optisch kontrollierter magnetischer Speicher- und Logikbauteile ist das zuverlässige Schreiben stabiler magnetischer Domänen, die unter Umgebungsbedingungen als Speicherbits dienen können. Magnetische Skyrmionen, topologisch nichttriviale wirbelf¨ormige Spin-Texturen, wurden seit ihrer Entdeckung aufgrund ihrer Stabilität und Skalierbarkeit in potenziellen spintronischen Bauelementen intensiv untersucht. Allerdings sind die Prozesse der Skyrmionenbildung und vor allem der Skyrmionenvernichtung noch immer nicht vollständig verstanden, so dass weitere Untersuchungen zu diesen Mechanismen erforderlich sind. Ziel dieser Arbeit ist es, zu einem besseren Verständnis der physikalischen Prozesse beizutragen, die der optischen Kontrolle magnetischer Texturen in dünnen Filmen zugrunde liegen, mit dem Ziel, die Materialparameter und Methoden für ihren potenziellen Einsatz in Speicher- und Logikbauteilen der nächsten Generation zu optimieren. Der erste Teil der Arbeit widmet sich der Untersuchung des rein optischen helizitätsabhängigen Schaltens (AO-HDS) als Methode zur Manipulation der Magnetisierung. AO-HDS wurde in Co/Pt-Multilayern und CoFeB-Legierungen mit und ohne DMI (Dzyaloshinskii-Moriya-Wechselwirkung), einer Art Austauschwechselwirkung, mittels magnetischer Bildgebung durch Photoemissions-Elektronenmikroskopie (PEEM) in Kombination mit magnetischem Röntgendichroismus (XMCD) untersucht. Die Ergebnisse zeigen, dass zirkular polarisiertes Licht in einem bestimmten Bereich der Laserfluenz einen Zug auf Domänenwände ausübt. Dies ermöglicht eine lokale deterministische Umwandlung des magnetischen Domänenmusters von Streifen zu Blasen Domänen in unmagnetisierten Co/Pt- Multilagen, die ausschließlich durch die Helizität der ultrakurzen Laserpulse gesteuert wird. Die Temperatur und die charakteristischen Felder, bei denen die Umwandlung von Streifen zu Blasen Domänen stattfindet, wurden mithilfe der Theorie für isolierte magnetische Blasen berechnet, wobei die experimentell ermittelte durchschnittliche Größe der Streifendom¨anen und die Dicke der magnetischen Schicht als Parameter verwendet wurden. Der zweite Teil der Arbeit zielt darauf ab, optimale Parameter zu ermitteln, die für das rein optische Schreiben und Löschen von magnetischen Skyrmionen in einem einzigen Laser Puls erforderlich sind. Das Vorhandensein einer Skyrmion-Phase in dafür verwendeten CoFeB-Legierungen wurde zunächst mit Hilfe eines Kerr-Mikroskops bestätigt. Dann wurde die helizitätsabhängige Skyrmion-Manipulation mittels AOHDS für verschiedene Laserfluenzen untersucht. Es zeigte sich, dass eine Schreiben oder Löschen einzelner Skyrmionen mittels AO-HDS zwar möglich ist, aber nicht immer zuverlässig, da Fluktuationen in der Laserfluenz oder Position den helizitätsabhängigen Effekt von AO-HDS leicht überschreiben können. Die experimentellen Ergebnisse und magnetischen Simulationen zeigten allerdings, dass die Schwellenwerte für die Laserfluenz zur Bildung und Vernichtung von Skyrmionen unterschiedlich sind. Für die Skyrmionenbildung wird eine höhere Fluenz benötigt, und bereits existierende Skyrmionen können durch Laser Pulse mit etwas geringerer Fluenz gelöscht werden. Dadurch bietet sich eine weitere Möglichkeit das Schreiben und Löschen von Skyrmionen durch die Laserfluenz zu kontrollieren. Mikromagnetische Simulationen liefern zusätzliche Erkenntnisse über den Schreib- und Löschmechanismus. Die Möglichkeit, den magnetischen Zustand einzelner Skyrmionen zu manipulieren, ist von grundlegender Bedeutung für magnetische Datenspeichertechnologien. Unsere Ergebnisse zeigen erstmalig, dass die optische Bildung und Vernichtung von Skyrmionen ohne Änderung des externen Feldes möglich ist. Diese Ergebnisse ermöglichen weitere Untersuchungen zur Optimierung der magnetischen Schicht, um die Energielücke zwischen Bildungs- und Vernichtungsbarriere zu maximieren. Dadurch kann unerwünschtes Schalten aufgrund kleiner Laserfluktuationen vermieden und vollständig deterministisches optisches Schalten erreicht werden. KW - Skyrmions KW - bubble domains KW - magnetism KW - Skyrmionen KW - Blasendomänen KW - Magnetismus KW - dünne Schichten KW - thin films Y1 - 2024 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-647069 ER - TY - JOUR A1 - Serrano-Munoz, Itziar A1 - Roveda, Ilaria A1 - Kupsch, Andreas A1 - Müller, Bernd R. A1 - Bruno, Giovanni T1 - Synchrotron X-ray refraction detects microstructure and porosity evolution during in-situ heat treatments JF - Materials Science and Engineering A: Structural Materials: Properties, Microstructure and Processing N2 - For the first time, synchrotron X-ray refraction radiography (SXRR) has been paired with in-situ heat treatment to monitor microstructure and porosity evolution as a function of temperature. The investigated material was a laser powder bed fusion (LPBF) manufactured AlSi10Mg, where the initial eutectic Si network is known to disintegrate and spherodize into larger particles with increasing temperature. Such alloy is also prone to ther-mally induced porosity (TIP). We show that SXRR allows detecting the changes in the Si-phase morphology upon heating, while this is currently possible only using scanning electron microscopy. SXRR also allows observing the growth of pores, usually studied via X-ray computed tomography, but on much smaller fields-of-view. Our results show the great potential of in-situ SXRR as a tool to gain in-depth knowledge of the susceptibility of any material to thermally induced damage and/or microstructure evolution over statistically relevant volumes. KW - synchrotron X-ray refraction radiography (SXRR) KW - Si network disintegration KW - thermally induced porosity (TIP) KW - laser powder bed fusion (LPBF) AlSi10Mg alloy KW - statistically relevant volumes Y1 - 2022 U6 - https://doi.org/10.1016/j.msea.2022.142732 SN - 0921-5093 SN - 1873-4936 VL - 838 PB - Elsevier CY - Lausanne ER - TY - JOUR A1 - Tönjes, Ralf A1 - Kori, Hiroshi T1 - Phase and frequency linear response theory for hyperbolic chaotic oscillators JF - Chaos : an interdisciplinary journal of nonlinear science N2 - We formulate a linear phase and frequency response theory for hyperbolic flows, which generalizes phase response theory for autonomous limit cycle oscillators to hyperbolic chaotic dynamics. The theory is based on a shadowing conjecture, stating the existence of a perturbed trajectory shadowing every unperturbed trajectory on the system attractor for any small enough perturbation of arbitrary duration and a corresponding unique time isomorphism, which we identify as phase such that phase shifts between the unperturbed trajectory and its perturbed shadow are well defined. The phase sensitivity function is the solution of an adjoint linear equation and can be used to estimate the average change of phase velocity to small time dependent or independent perturbations. These changes in frequency are experimentally accessible, giving a convenient way to define and measure phase response curves for chaotic oscillators. The shadowing trajectory and the phase can be constructed explicitly in the tangent space of an unperturbed trajectory using co-variant Lyapunov vectors. It can also be used to identify the limits of the regime of linear response. Y1 - 2022 U6 - https://doi.org/10.1063/5.0064519 SN - 1054-1500 SN - 1089-7682 VL - 32 IS - 4 PB - AIP Publishing CY - Melville ER - TY - JOUR A1 - Zheng, Chunming A1 - Tönjes, Ralf A1 - Pikovskij, Arkadij T1 - Transition to synchrony in a three-dimensional swarming model with helical trajectories JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We investigate the transition from incoherence to global collective motion in a three-dimensional swarming model of agents with helical trajectories, subject to noise and global coupling. Without noise this model was recently proposed as a generalization of the Kuramoto model and it was found that alignment of the velocities occurs discontinuously for arbitrarily small attractive coupling. Adding noise to the system resolves this singular limit and leads to a continuous transition, either to a directed collective motion or to center-of-mass rotations. Y1 - 2021 U6 - https://doi.org/10.1103/PhysRevE.104.014216 SN - 2470-0045 SN - 2470-0053 VL - 104 IS - 1 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Tönjes, Ralf A1 - Pikovsky, Arkady T1 - Low-dimensional description for ensembles of identical phase oscillators subject to Cauchy noise JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We study ensembles of globally coupled or forced identical phase oscillators subject to independent white Cauchy noise. We demonstrate that if the oscillators are forced in several harmonics, stationary synchronous regimes can be exactly described with a finite number of complex order parameters. The corresponding distribution of phases is a product of wrapped Cauchy distributions. For sinusoidal forcing, the Ott-Antonsen low-dimensional reduction is recovered. Y1 - 2020 U6 - https://doi.org/10.1103/PhysRevE.102.052315 SN - 2470-0045 SN - 2470-0053 VL - 102 IS - 5 PB - American Physical Society CY - College Park ER - TY - THES A1 - Tönjes, Ralf T1 - Pattern formation through synchronization in systems of nonidentical autonomous oscillators T1 - Musterbildung durch Synchronisation in Systemen nicht identischer, autonomer Oszillatoren N2 - This work is concerned with the spatio-temporal structures that emerge when non-identical, diffusively coupled oscillators synchronize. It contains analytical results and their confirmation through extensive computer simulations. We use the Kuramoto model which reduces general oscillatory systems to phase dynamics. The symmetry of the coupling plays an important role for the formation of patterns. We have studied the ordering influence of an asymmetry (non-isochronicity) in the phase coupling function on the phase profile in synchronization and the intricate interplay between this asymmetry and the frequency heterogeneity in the system. The thesis is divided into three main parts. Chapter 2 and 3 introduce the basic model of Kuramoto and conditions for stable synchronization. In Chapter 4 we characterize the phase profiles in synchronization for various special cases and in an exponential approximation of the phase coupling function, which allows for an analytical treatment. Finally, in the third part (Chapter 5) we study the influence of non-isochronicity on the synchronization frequency in continuous, reaction diffusion systems and discrete networks of oscillators. N2 - Die vorliegende Arbeit beschäftigt sich in Theorie und Simulation mit den raum-zeitlichen Strukturen, die entstehen, wenn nicht-identische, diffusiv gekoppelte Oszillatoren synchronisieren. Wir greifen dabei auf die von Kuramoto hergeleiteten Phasengleichungen zurück. Eine entscheidene Rolle für die Musterbildung spielt die Symmetrie der Kopplung. Wir untersuchen den ordnenden Einfluss von Asymmetrie (Nichtisochronizität) in der Phasenkopplungsfunktion auf das Phasenprofil in Synchronisation und das Zusammenspiel zwischen dieser Asymmetrie und der Frequenzheterogenität im System. Die Arbeit gliedert sich in drei Hauptteile. Kapitel 2 und 3 beschäftigen sich mit den grundlegenden Gleichungen und den Bedingungen für stabile Synchronisation. Im Kapitel 4 charakterisieren wir die Phasenprofile in Synchronisation für verschiedene Spezialfälle sowie in der von uns eingeführten exponentiellen Approximation der Phasenkopplungsfunktion. Schliesslich untersuchen wir im dritten Teil (Kap.5) den Einfluss von Nichtisochronizität auf die Synchronisationsfrequenz in kontinuierlichen, oszillatorischen Reaktions-Diffusionssystemen und diskreten Netzwerken von Oszillatoren. KW - Synchronisation KW - Musterbildung KW - Phasen-Gleichungen KW - Phasen-Oszillatoren KW - Kuramoto Modell KW - synchronization KW - pattern formation KW - phase equations KW - phase oscillators KW - Kuramoto model Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-15973 ER - TY - JOUR A1 - Gong, Chen Chris A1 - Zheng, Chunming A1 - Tönjes, Ralf A1 - Pikovskij, Arkadij T1 - Repulsively coupled Kuramoto-Sakaguchi phase oscillators ensemble subject to common noise JF - Chaos : an interdisciplinary journal of nonlinear science N2 - We consider the Kuramoto-Sakaguchi model of identical coupled phase oscillators with a common noisy forcing. While common noise always tends to synchronize the oscillators, a strong repulsive coupling prevents the fully synchronous state and leads to a nontrivial distribution of oscillator phases. In previous numerical simulations, the formation of stable multicluster states has been observed in this regime. However, we argue here that because identical phase oscillators in the Kuramoto-Sakaguchi model form a partially integrable system according to the Watanabe-Strogatz theory, the formation of clusters is impossible. Integrating with various time steps reveals that clustering is a numerical artifact, explained by the existence of higher order Fourier terms in the errors of the employed numerical integration schemes. By monitoring the induced change in certain integrals of motion, we quantify these errors. We support these observations by showing, on the basis of the analysis of the corresponding Fokker-Planck equation, that two-cluster states are non-attractive. On the other hand, in ensembles of general limit cycle oscillators, such as Van der Pol oscillators, due to an anharmonic phase response function as well as additional amplitude dynamics, multiclusters can occur naturally. Published under license by AIP Publishing. Y1 - 2019 U6 - https://doi.org/10.1063/1.5084144 SN - 1054-1500 SN - 1089-7682 VL - 29 IS - 3 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Gong, Chen Chris A1 - Tönjes, Ralf A1 - Pikovsky, Arkady T1 - Coupled Möbius maps as a tool to model Kuramoto phase synchronization JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We propose Mobius maps as a tool to model synchronization phenomena in coupled phase oscillators. Not only does the map provide fast computation of phase synchronization, it also reflects the underlying group structure of the sinusoidally coupled continuous phase dynamics. We study map versions of various known continuous-time collective dynamics, such as the synchronization transition in the Kuramoto-Sakaguchi model of nonidentical oscillators, chimeras in two coupled populations of identical phase oscillators, and Kuramoto-Battogtokh chimeras on a ring, and demonstrate similarities and differences between the iterated map models and their known continuous-time counterparts. Y1 - 2020 U6 - https://doi.org/10.1103/PhysRevE.102.022206 SN - 2470-0045 SN - 2470-0053 SN - 1063-651X SN - 2470-0061 SN - 1550-2376 VL - 102 IS - 2 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Zheng, Chunming A1 - Tönjes, Ralf T1 - Noise-induced swarming of active particles JF - Physical review : E, Statistical, nonlinear and soft matter physics N2 - We report on the effect of spatially correlated noise on the velocities of self-propelled particles. Correlations in the random forces acting on self-propelled particles can induce directed collective motion, i.e., swarming. Even with repulsive coupling in the velocity directions, which favors a disordered state, strong correlations in the fluctuations can align the velocities locally leading to a macroscopic, turbulent velocity field. On the other hand, while spatially correlated noise is aligning the velocities locally, the swarming transition to globally directed motion is inhibited when the correlation length of the noise is nonzero, but smaller than the system size. We analyze the swarming transition in d-dimensional space in a mean field model of globally coupled velocity vectors. Y1 - 2022 U6 - https://doi.org/10.1103/PhysRevE.106.064601 SN - 2470-0045 SN - 2470-0053 VL - 106 IS - 6 PB - American Physical Society CY - College Park ER - TY - GEN A1 - Rosenblum, Michael A1 - McClintock, Peter V. E. T1 - In memoriam - Polina S. Landa (15 February 1931-21 October 2022) T2 - Chaos : an interdisciplinary journal of nonlinear science Y1 - 2022 U6 - https://doi.org/10.1063/5.0136898 SN - 1054-1500 SN - 1089-7682 VL - 32 IS - 12 PB - American Institute of Physics CY - Woodbury, NY ER - TY - JOUR A1 - Pasechnik, Sergey V. A1 - Shmeleva, Dina A1 - Saidgaziev, Ayvr Sh. A1 - Kharlamov, Semen A1 - Vasilieva, Aleksandra A. A1 - Santer, Svetlana T1 - Shear flows induced by electro-osmotic pumps in optofluidic liquid crystal cell for modulation of visible light and THz irradiation JF - Liquid Crystals and their Application : Russian Journal N2 - The work is devoted to the use of electrokinetic phenomena in liquid crystals to create a new class of microfluidics devices - optofluidics, designed to control electromagnetic radiation, including the THz frequency range. To achieve the goal, an optical method is used to study changes in the orientational structure in LC layers caused by a shear flow generated by electroosmotic pumps. Simula-tion of LC behaviour in an experimental cell containing electroosmotic pumps and flat layers of a nematic liquid crystal is fulfilled. The experimental depend-ences of the intensity of polarized radiation passing through flat LC layers on the control voltage applied to the electroosmotic pump and the results of calcu-lations of the hydrodynamic and mechano-optical characteristics of the experi-mental LC cell are presented. The propagation of THz irradiation across the multilayer structure of the optofluidic cell is considered taking into account the minimum number of re-reflections of waves from different layers and the ab-sorption of THz irradiation in a propylene and a liquid crystal. N2 - Работа посвящена использованию электрокинетических явлений в жидких кристаллах для создания нового класса микрофлюидных устройств – опто- флюидики, предназначенных для управления электромагнитным излуче- нием, в том числе терагерцового диапазона частот. Для достижения цели оптическим методом исследуются изменения ориентационной структуры в слоях ЖК, вызванные сдвиговым течением, генерируемым электроосмоти- ческими насосами. Проведено моделирование поведения ЖК в эксперимен- тальной ячейке, содержащей электроосмотические насосы и плоские слои нематического жидкого кристалла. Представлены экспериментальные за- висимости интенсивности поляризованного излучения, проходящего через плоские слои ЖК, от управляющего напряжения, подаваемого на электро- осмотический насос, и результаты расчетов гидродинамических и механо- оптических характеристик экспериментальной ЖК-ячейки. Рассмотрено распространение ТГц излучения по многослойной структуре оптофлюид- ной ячейки с учетом минимального числа переотражений волн от разных слоев и поглощения ТГц излучения в пропилене и жидком кристалле. KW - nematic liquid crystal KW - terahertz range KW - electrokinetic phenomena KW - osmotic flow KW - director configuration KW - optical irradiation intensity KW - E7 KW - polypropylene Y1 - 2022 U6 - https://doi.org/10.18083/LCAppl.2022.3.49 SN - 1991-3966 SN - 2499–9644 VL - 22 IS - 3 SP - 49 EP - 57 PB - Nanomaterials Research Institute CY - Ivanovo ER - TY - THES A1 - Valencia Sanmiguel, Antonio T1 - Condensation and crystallization on patterned surfaces N2 - Condensation and crystallization are omnipresent phenomena in nature. The formation of droplets or crystals on a solid surface are familiar processes which, beyond their scientific interest, are required in many technological applications. In recent years, experimental techniques have been developed which allow patterning a substrate with surface domains of molecular thickness, surface area in the mesoscopic scale, and different wettabilities (i.e., different degrees of preference for a substance that is in contact with the substrate). The existence of new patterned surfaces has led to increased theoretical efforts to understand wetting phenomena in such systems. In this thesis, we deal with some problems related to the equilibrium of phases (e.g., liquid-vapor coexistence) and the kinetics of phase separation in the presence of chemically patterned surfaces. Two different cases are considered: (i) patterned surfaces in contact with liquid and vapor, and (ii) patterned surfaces in contact with a crystalline phase. One of the problems that we have studied is the following: It is widely believed that if air containing water vapor is cooled to its dew point, droplets of water are immediately formed. Although common experience seems to support this view, it is not correct. It is only when air is cooled well below its dew point that the phase transition occurs immediately. A vapor cooled slightly below its dew point is in a metastable state, meaning that the liquid phase is more stable than the vapor, but the formation of droplets requires some time to occur, which can be very long. It was first pointed out by J. W. Gibbs that the metastability of a vapor depends on the energy necessary to form a nucleus (a droplet of a critical size). Droplets smaller than the critical size will tend to disappear, while droplets larger than the critical size will tend to grow. This is consistent with an energy barrier that has its maximum at the critical size, as is the case for droplets formed directly in the vapor or in contact with a chemically uniform planar wall. Classical nucleation theory describes the time evolution of the condensation in terms of the random process of droplet growth through this energy barrier. This process is activated by thermal fluctuations, which eventually will form a droplet of the critical size. We consider nucleation of droplets from a vapor on a substrate patterned with easily wettable (lyophilic) circular domains. Under certain conditions of pressure and temperature, the condensation of a droplet on a lyophilic circular domain proceeds through a barrier with two maxima (a double barrier). We have extended classical nucleation theory to account for the kinetics of nucleation through a double barrier, and applied this extension to nucleation on lyophilic circular domains. N2 - Kondensation und Kristallisation sind allgegenwärtige Phänomene in der Natur. Die Bildung von Tröpfchen oder Kristallen auf einer festen Oberfläche sind vertraute Prozesse, die über ihr wissenschaftliches Interesse hinaus in vielen technologischen Anwendungen erforderlich sind. In den letzten Jahren wurden experimentelle Techniken entwickelt, die es ermöglichen, ein Substrat mit Oberflächendomänen von molekularer Dicke, mesoskopischer Oberflächengröße und unterschiedlichen Benetzbarkeiten (d.h. unterschiedlichen Graden der Präferenz für eine Substanz, die mit dem Substrat in Kontakt steht) zu strukturieren. Die Existenz neuer strukturierter Oberflächen hat zu verstärkten theoretischen Bemühungen geführt, Benetzungsphänomene in solchen Systemen zu verstehen. In dieser Arbeit befassen wir uns mit einigen Problemen im Zusammenhang mit dem Gleichgewicht von Phasen (z.B. Flüssig-Dampf-Koexistenz) und der Kinetik der Phasentrennung in Gegenwart von chemisch strukturierten Oberflächen. Zwei verschiedene Fälle werden betrachtet: (i) strukturierte Oberflächen in Kontakt mit Flüssigkeit und Dampf und (ii) strukturierte Oberflächen in Kontakt mit einer kristallinen Phase. Eines der Probleme, die wir untersucht haben, ist das folgende: Es wird allgemein angenommen, dass sich bei Abkühlung von wasserdampfhaltiger Luft auf ihren Taupunkt sofort Wassertröpfchen bilden. Obwohl die allgemeine Erfahrung diese Ansicht zu unterstützen scheint, ist sie nicht korrekt. Erst wenn die Luft deutlich unter ihren Taupunkt gekühlt wird, tritt der Phasenübergang sofort ein. Ein leicht unter seinen Taupunkt gekühlter Dampf befindet sich in einem metastabilen Zustand, was bedeutet, dass die flüssige Phase stabiler als der Dampf ist, aber die Bildung von Tröpfchen einige Zeit benötigt, die sehr lang sein kann. J. W. Gibbs wies erstmals darauf hin, dass die Metastabilität eines Dampfes von der Energie abhängt, die zur Bildung eines Keims (eines Tröpfchens kritischer Größe) notwendig ist. Tröpfchen, die kleiner als die kritische Größe sind, neigen dazu zu verschwinden, während Tröpfchen, die größer als die kritische Größe sind, dazu neigen zu wachsen. Dies stimmt mit einer Energiebarriere überein, die ihr Maximum bei der kritischen Größe hat, wie es bei Tröpfchen der Fall ist, die sich direkt im Dampf oder in Kontakt mit einer chemisch einheitlichen ebenen Wand bilden. Die klassische Nukleationstheorie beschreibt die zeitliche Entwicklung der Kondensation als zufälligen Prozess des Tröpfchenwachstums durch diese Energiebarriere. Dieser Prozess wird durch thermische Fluktuationen aktiviert, die schließlich ein Tröpfchen kritischer Größe bilden. Wir betrachten die Nukleation von Tröpfchen aus einem Dampf auf einem Substrat, das mit leicht benetzbaren (lyophilen) kreisförmigen Domänen strukturiert ist. Unter bestimmten Druck- und Temperaturbedingungen verläuft die Kondensation eines Tröpfchens auf einer lyophilen kreisförmigen Domäne durch eine Barriere mit zwei Maxima (eine Doppelbarriere). Wir haben die klassische Nukleationstheorie erweitert, um die Kinetik der Nukleation durch eine Doppelbarriere zu berücksichtigen, und haben diese Erweiterung auf die Nukleation auf lyophilen kreisförmigen Domänen angewendet. KW - Chemical physics KW - Condensation KW - Nucleation KW - Crystallization KW - Computer simulation KW - Soft condensed matter KW - Phase transitions KW - Chemically patterned surfaces KW - Monte Carlo simulation KW - Kondensation KW - Kristallisation KW - Oberfläche KW - Keimbildung KW - Mathematisches Modell Y1 - 2003 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-651950 ER - TY - JOUR A1 - Grassl, Sandra A1 - Ritter, Christoph A1 - Schulz, Alexander T1 - The nature of the Ny-Alesund wind field analysed by high-resolution windlidar data JF - Remote sensing N2 - In this work we present windlidar data for the research village Ny-Alesund located on Svalbard in the European Arctic (78.923 degrees N, 11.928 degrees F) from 2013 to 2021. The data have a resolution of 50 m and 10 min with an overlapping height of about 150 m. The maximum range depends on the meteorologic situation. Up to 1000 m altitude the data availability is better than 71%. We found that the highest wind speeds occur in November and December, the lowest ones in June and July, up to 500 m altitude the wind is channelled strongly in ESE to NW direction parallel to the fjord axis and the synoptic conditions above 1000 m altitude already dominate. While the fraction of windy days (v > 10 m/s) varies significantly from month to month, there is no overall trend of the wind visible in our data set. We define gusts and jets by the requirement of wind maxima v > 2 m/s above and below a wind maximum. In total, more than 24,000 of these events were identified (corresponding to 6% of the time), of which 223 lasted for at least 100 min ("Long Jets"). All of these events are fairly equally distributed over the months relatively to the available data. Further, gusts and jets follow different distributions (in terms of altitude or depths) and occur more frequently for synoptic flow from roughly a southerly direction. Jets do not show a clear correlation between occurrence and synoptic flow. Gusts and jets are not related to cloud cover. We conclude that the atmosphere from 400 m to 1000 m above Ny-Alesund is dominated by a turbulent wind shear zone, which connects the micrometeorology in the atmospheric boundary layer (ABL) with the synoptic flow. KW - windlidar KW - wind field KW - wind channelling KW - jets KW - Ny-Alesund KW - Svalbard KW - Kongsfjord KW - wind speed KW - wind direction KW - turbulent wind shear zone Y1 - 2022 U6 - https://doi.org/10.3390/rs14153771 SN - 2072-4292 VL - 14 IS - 15 PB - MDPI CY - Basel ER - TY - JOUR A1 - Horvat, Anja Kranjc A1 - Wiener, Jeff A1 - Schmeling, Sascha Marc A1 - Borowski, Andreas T1 - What does the curriculum say? Review of the particle physics content in 27 high-school physics curricula JF - Physics N2 - This international curricular review provides a structured overview of the particle physics content in 27 state, national, and international high-school physics curricula. The review was based on a coding manual that included 60 concepts that were identified as relevant for high-school particle physics education. Two types of curricula were reviewed, namely curricula with a dedicated particle physics chapter and curricula without a dedicated particle physics chapter. The results of the curricular review show that particle physics concepts are explicitly or implicitly present in all reviewed curricula. However, the number of particle physics concepts that are featured in a curriculum varies greatly across the reviewed curricula. We identified core particle physics concepts that can be found in most curricula. Here, elementary particles, fundamental interactions, and charges were identified as explicit particle physics concepts that are featured in more than half of the reviewed curricula either as content or context. Indeed, theoretical particle physics concepts are more prominent in high-school physics curricula than experimental particle physics concepts. Overall, this international curricular review provides the basis for future curricular development with respect to particle physics and suggests an increased inclusion of experimental particle physics concepts in high-school physics curricula. KW - curricular review KW - particle physics KW - high-school education Y1 - 2022 U6 - https://doi.org/10.3390/physics4040082 SN - 2624-8174 VL - 4 IS - 4 SP - 1278 EP - 1298 PB - MDPI CY - Basel ER - TY - THES A1 - Fulat, Karol T1 - Electron acceleration at quasi-perpendicular shocks in supernova remnants N2 - Astrophysical shocks, driven by explosive events such as supernovae, efficiently accelerate charged particles to relativistic energies. The majority of these shocks occur in collisionless plasmas where the energy transfer is dominated by particle-wave interactions.Strong nonrelativistic shocks found in supernova remnants are plausible sites of galactic cosmic ray production, and the observed emission indicates the presence of nonthermal electrons. To participate in the primary mechanism of energy gain - Diffusive Shock Acceleration - electrons must have a highly suprathermal energy, implying a need for very efficient pre-acceleration. This poorly understood aspect of the shock acceleration theory is known as the electron injection problem. Studying electron-scale phenomena requires the use of fully kinetic particle-in-cell (PIC) simulations, which describe collisionless plasma from first principles. Most published studies consider a homogenous upstream medium, but turbulence is ubiquitous in astrophysical environments and is typically driven at magnetohydrodynamic scales, cascading down to kinetic scales. For the first time, I investigate how preexisting turbulence affects electron acceleration at nonrelativistic shocks using the fully kinetic approach. To accomplish this, I developed a novel simulation framework that allows the study of shocks propagating in turbulent media. It involves simulating slabs of turbulent plasma separately, which are further continuously inserted into a shock simulation. This demands matching of the plasma slabs at the interface. A new procedure of matching electromagnetic fields and currents prevents numerical transients, and the plasma evolves self-consistently. The versatility of this framework has the potential to render simulations more consistent with turbulent systems in various astrophysical environments. In this Thesis, I present the results of 2D3V PIC simulations of high-Mach-number nonrelativistic shocks with preexisting compressive turbulence in an electron-ion plasma. The chosen amplitudes of the density fluctuations ($\lesssim15\%$) concord with \textit{in situ} measurements in the heliosphere and the local interstellar medium. I explored how these fluctuations impact the dynamics of upstream electrons, the driving of the plasma instabilities, electron heating and acceleration. My results indicate that while the presence of the turbulence enhances variations in the upstream magnetic field, their levels remain too low to influence the behavior of electrons at perpendicular shocks significantly. However, the situation is different at oblique shocks. The external magnetic field inclined at an angle between $50^\circ \lesssim \theta_\text{Bn} \lesssim 75^\circ$ relative to the shock normal allows the escape of fast electrons toward the upstream region. An extended electron foreshock region is formed, where these particles drive various instabilities. Results of an oblique shock with $\theta_\text{Bn}=60^\circ$ propagating in preexisting compressive turbulence show that the foreshock becomes significantly shorter, and the shock-reflected electrons have higher temperatures. Furthermore, the energy spectrum of downstream electrons shows a well-pronounced nonthermal tail that follows a power law with an index up to -2.3. The methods and results presented in this Thesis could serve as a starting point for more realistic modeling of interactions between shocks and turbulence in plasmas from first principles. N2 - Astrophysikalische Schocks, die durch explosive Ereignisse wie Supernovae ausgelöst werden, beschleunigen geladene Teilchen effizient auf relativistische Energien. Die meisten dieser Schocks treten in kollisionsfreien Plasmen auf, in denen die Energieübertragung durch Teilchen-Wellen-Wechselwirkungen dominiert wird. Starke nichtrelativistische Schocks, die in Supernovaüberresten gefunden werden, sind plausible Orte der galaktischen kosmischen Strahlungsproduktion, und die beobachtete Emission deutet auf das Vorhandensein von nichtthermischen Elektronen hin. Um am primären Mechanismus der Energiegewinnung - der diffusiven Schockbeschleunigung - teilzunehmen, müssen die Elektronen eine hochgradig suprathermische Energie haben, was eine sehr effiziente Vorbeschleunigung voraussetzt. Dieser schlecht verstandene Aspekt der Stoßbeschleunigungstheorie ist als Elektroneninjektionsproblem bekannt. Die Untersuchung von Phänomenen auf der Elektronenskala erfordert den Einsatz von vollständig kinetischen Partikel-in-Zellen-Simulationen (PIC), die ein kollisionsfreies Plasma nach ersten Prinzipien beschreiben. Die meisten veröffentlichten Studien gehen von einem homogenen stromaufwärts gelegenen Medium aus, aber Turbulenzen sind in astrophysikalischen Umgebungen allgegenwärtig und werden typischerweise auf magnetohydrodynamischen Skalen angetrieben und kaskadieren hinunter zu kinetischen Skalen. Zum ersten Mal untersuche ich, wie sich eine bereits vorhandene Turbulenz auf die Elektronenbeschleunigung an nichtrelativistischen Schocks auswirkt, indem ich einen vollständig kinetischen Ansatz verwende. Zu diesem Zweck habe ich einen neuartigen Simulationsrahmen entwickelt, der die Untersuchung von Schocks ermöglicht, die sich in turbulenten Medien ausbreiten. Dabei werden die Platten des turbulenten Plasmas separat simuliert, die dann kontinuierlich in eine Schocksimulation eingefügt werden. Dies erfordert eine Anpassung der Plasmaplatten an der Grenzfläche. Ein neues Verfahren zur Anpassung elektromagnetischer Felder und Ströme verhindert numerische Transienten, und das Plasma entwickelt sich selbstkonsistent. Die Vielseitigkeit dieses Rahmens hat das Potenzial, Simulationen mit turbulenten Systemen in verschiedenen astrophysikalischen Umgebungen konsistenter zu machen. In dieser Arbeit präsentiere ich die Ergebnisse von 2D3V PIC-Simulationen von nichtrelativistischen Schocks mit hoher Mach-Zahl und bereits vorhandener kompressiver Turbulenz in einem Elektron-Ionen-Plasma. Die gewählten Amplituden der Dichtefluktuationen ($\lesssim15\%$) stimmen mit \textit{in situ} Messungen in der Heliosphäre und dem lokalen interstellaren Medium überein. Ich habe untersucht, wie sich diese Fluktuationen auf die Dynamik der stromaufwärts befindlichen Elektronen, den Antrieb der Plasmainstabilitäten, die Elektronenheizung und -beschleunigung auswirken. Meine Ergebnisse deuten darauf hin, dass das Vorhandensein von Turbulenzen zwar die Schwankungen des stromaufwärts gelegenen Magnetfelds verstärkt, dass aber die Schwankungen zu gering sind, um das Verhalten der Elektronen an senkrechten Schocks wesentlich zu beeinflussen. Bei schrägen Stößen ist die Situation jedoch anders. Das äußere Magnetfeld, das in einem Winkel zwischen $50^\circ \lesssim \theta_\text{Bn} \lesssim 75^\circ$ relativ zur Schocknormalen ermöglicht das Entweichen schneller Elektronen in Richtung der stromaufwärts gelegenen Region. Es bildet sich eine ausgedehnte Elektronenvorstoßregion, in der diese Teilchen verschiedene Instabilitäten auslösen. Die Ergebnisse eines schrägen Schocks mit $\theta_\text{Bn}=60^\circ$, der sich in einer vorher existierenden kompressiven Turbulenz ausbreitet, zeigen, dass der Vorschock deutlich kürzer wird und die vom Schock reflektierten Elektronen höhere Temperaturen aufweisen. Darüber hinaus zeigt das Energiespektrum der stromabwärts gerichteten Elektronen einen ausgeprägten nichtthermischen Schweif, der einem Potenzgesetz mit einem Index von bis zu -2,3 folgt. Die in dieser Arbeit vorgestellten Methoden und Ergebnisse könnten als Ausgangspunkt für eine realistischere Modellierung der Wechselwirkungen zwischen Schocks und Turbulenz in Plasmen nach ersten Prinzipien dienen. T2 - Elektronenbeschleunigung bei quasi senkrechten Schocks in Supernovaüberresten KW - astrophysical shocks KW - plasma physics KW - particle acceleration KW - astrophysikalische Schocks KW - Plasmaphysik KW - Teilchenbeschleunigung Y1 - 2024 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-651365 ER - TY - THES A1 - Braun, Tobias T1 - Recurrences in past climates T1 - Rekurrenzen in vergangenen Klimaperioden BT - novel concepts & tools for the study of Palaeoseasonality and beyond BT - neue Konzepte und Methoden zur Analyse von Paläosaisonalität und darüber hinaus N2 - Our ability to predict the state of a system relies on its tendency to recur to states it has visited before. Recurrence also pervades common intuitions about the systems we are most familiar with: daily routines, social rituals and the return of the seasons are just a few relatable examples. To this end, recurrence plots (RP) provide a systematic framework to quantify the recurrence of states. Despite their conceptual simplicity, they are a versatile tool in the study of observational data. The global climate is a complex system for which an understanding based on observational data is not only of academical relevance, but vital for the predurance of human societies within the planetary boundaries. Contextualizing current global climate change, however, requires observational data far beyond the instrumental period. The palaeoclimate record offers a valuable archive of proxy data but demands methodological approaches that adequately address its complexities. In this regard, the following dissertation aims at devising novel and further developing existing methods in the framework of recurrence analysis (RA). The proposed research questions focus on using RA to capture scale-dependent properties in nonlinear time series and tailoring recurrence quantification analysis (RQA) to characterize seasonal variability in palaeoclimate records (‘Palaeoseasonality’). In the first part of this thesis, we focus on the methodological development of novel approaches in RA. The predictability of nonlinear (palaeo)climate time series is limited by abrupt transitions between regimes that exhibit entirely different dynamical complexity (e.g. crossing of ‘tipping points’). These possibly depend on characteristic time scales. RPs are well-established for detecting transitions and capture scale-dependencies, yet few approaches have combined both aspects. We apply existing concepts from the study of self-similar textures to RPs to detect abrupt transitions, considering the most relevant time scales. This combination of methods further results in the definition of a novel recurrence based nonlinear dependence measure. Quantifying lagged interactions between multiple variables is a common problem, especially in the characterization of high-dimensional complex systems. The proposed ‘recurrence flow’ measure of nonlinear dependence offers an elegant way to characterize such couplings. For spatially extended complex systems, the coupled dynamics of local variables result in the emergence of spatial patterns. These patterns tend to recur in time. Based on this observation, we propose a novel method that entails dynamically distinct regimes of atmospheric circulation based on their recurrent spatial patterns. Bridging the two parts of this dissertation, we next turn to methodological advances of RA for the study of Palaeoseasonality. Observational series of palaeoclimate ‘proxy’ records involve inherent limitations, such as irregular temporal sampling. We reveal biases in the RQA of time series with a non-stationary sampling rate and propose a correction scheme. In the second part of this thesis, we proceed with applications in Palaeoseasonality. A review of common and promising time series analysis methods shows that numerous valuable tools exist, but their sound application requires adaptions to archive-specific limitations and consolidating transdisciplinary knowledge. Next, we study stalagmite proxy records from the Central Pacific as sensitive recorders of mid-Holocene El Niño-Southern Oscillation (ENSO) dynamics. The records’ remarkably high temporal resolution allows to draw links between ENSO and seasonal dynamics, quantified by RA. The final study presented here examines how seasonal predictability could play a role for the stability of agricultural societies. The Classic Maya underwent a period of sociopolitical disintegration that has been linked to drought events. Based on seasonally resolved stable isotope records from Yok Balum cave in Belize, we propose a measure of seasonal predictability. It unveils the potential role declining seasonal predictability could have played in destabilizing agricultural and sociopolitical systems of Classic Maya populations. The methodological approaches and applications presented in this work reveal multiple exciting future research avenues, both for RA and the study of Palaeoseasonality. N2 - Unsere Fähigkeit, den Zustand eines Systems vorherzusagen, hängt grundlegend von der Tendenz des Systems ab, zu früheren Zuständen zurückzukehren. Solche "Rekurrenzen" sind sogar Bestandteil unserer Intuition und alltäglichen Erfahrungswelt: regelmäßige Routinen, soziale Zusammentreffen and die Wiederkehr der Jahreszeiten sind hierfür nur vereinzelte Beispiele. Rekurrenzplots (RPs) stellen uns in diesem Kontext eine systematische Methode zur Verfügung, um die Wiederkehreigenschaften von Systemzuständen quantitativ zu untersuchen. Obwohl RPs konzeptionell vergleichsweise simpel sind, stellen sie eine vielseitige Methode zur Analyse von gemessenen Beobachtungsdaten dar. Das globale Klimasystem ist ein komplexes System, bei dem ein datenbasiertes Verständnis nicht lediglich von rein akademischen Wert ist – es ist viel mehr relevant für das Fortbestehen der Gesellschaft innerhalb der natürlichen planetaren Grenzen. Um die heute beobachteten Klimaveränderungen allerdings in einen langfristigen Kontext einzuordnen, benötigen wir empirische Daten, die weit über die Periode hinaus gehen, für die instrumentelle Daten verfügbar sind. Paläoklimatologische Datenreihen repräsentieren hier ein wertvolles Archiv, dessen Auswertung jedoch Analysemethoden erfordert, die an die Komplexitäten von paläoklimatologischen ‘Proxydaten’ angepasst sind. Um einen wissenschaftlichen Beitrag zu dieser Problemstellung zu leisten, befasst sich diese Doktorarbeit mit der Konzeptionierung neuer Methoden und der problemstellungsbezogenen Anpassung bewährter Methoden in der Rekurrenzanalyse (RA). Die hier formulierten zentralen Forschungsfragen konzentrieren sich auf den Nachweis zeitskalen-abhängiger Eigenschaften in nichtlinearen Zeitreihen und, insbesondere, der Anpassung von quantitativen Maßen in der RA, um paläosaisonale Proxydaten zu charakterisieren (‘Paläosaisonalität’). Im ersten Teil dieser Arbeit liegt der Schwerpunkt auf der Entwicklung neuer methodischer Ansätze in der RA. Die Vorhersagbarkeit nichtlinearer (paläo)klimatologischer Zeitreihen ist durch abrupte Übergänge zwischen dynamisch grundlegend verschiedenen Zuständen erschwert (so zum Beispiel das Übertreten sogenannter ‘Kipppunkte’). Solche Zustandsübergänge zeigen oft charakteristische Zeitskalen-Abhängigkeiten. RPs haben sich als Methode zum Nachweis von Zustandsübergängen bewährt und sind darüber hinaus geeignet, Skalenabhängigkeiten zu identifizieren. Dennoch wurden beide Aspekte bislang selten methodisch zusammengeführt. Wir kombinieren hier bestehende Konzepte aus der Analyse selbstähnlicher Strukturen und RPs, um abrupte Zustandsübergänge unter Einbezug der relevantesten Zeitskalen zu identifizieren. Diese Kombination von Konzepten führt uns ferner dazu, ein neues rekurrenzbasiertes, nichtlineares Abhängigkeitsmaß einzuführen. Die quantitative Untersuchung zeitversetzter Abhängigkeiten zwischen zahlreichen Variablen ist ein zentrales Problem, das insbesondere in der Analyse hochdimensionaler komplexer Systeme auftritt. Das hier definierte ‘Rekurrenzfluß’-Abhängigkeitsmaß ermöglicht es auf elegante Weise, derartige Abhängigkeiten zu charakterisieren. Bei räumlich ausgedehnten komplexen Systemen führen Interaktionen zwischen lokalen Variablen zu der Entstehung räumlicher Muster. Diese räumlichen Muster zeigen zeitliche Rekurrenzen. In einer auf dieser Beobachtung aufbauenden Publikation stellen wir eine neue Methode vor, mit deren Hilfe differenzierbare, makroskopische Zustände untersucht werden können, die zu zentralen, zeitlich wiederkehrenden räumlichen Mustern korrespondieren. Folgend leiten wir über zum zweiten Teil dieser Arbeit, indem wir uns Anpassungen von Methoden zur Untersuchung von Paläosaisonalität zuwenden. Messreihen paläoklimatologischer Proxydaten geben uns nur indirekt Informationen über die ihnen zugrunde liegenden Klimavariablen und weisen inhärente Limitationen auf, wie zum Beispiel unregelmäßige Zeitabstände zwischen Datenpunkten. Wir zeigen statistische Verzerrungseffekte auf, die in der quantitativen RA auftreten, wenn Signale mit nichtstationärer Abtastrate untersucht werden. Eine Methode zur Korrektur wird vorgestellt und anhand von Messdaten validiert. Der zweite Teil dieser Dissertation befasst sich mit angewandten Analysen von paläosaisonalen Zeitreihen. Eine Literaturauswertung verbreiteter und potentiell vielversprechender Zeitreihenanalysemethoden zeigt auf, dass es eine Vielzahl solcher Methoden gibt, deren adäquate Anwendung aber Anpassungen an Klimaarchiv-spezifische Grenzen und Probleme sowie eine Zusammenführung interdisziplinärer Fähigkeiten erfordert. Daraufhin untersuchen wir an einem Stalagmiten gemessene Proxydaten aus der zentralen Pazifikregion als ein natürliches Archiv für potentielle Veränderungen der El Niño-Southern Oscillation (ENSO) währen des mittleren Holozäns. Die bemerkenswert hohe zeitliche Auflösung der Proxy-Zeitreihen erlaubt es uns, Verbindungen zwischen der Ausprägung der ENSO und saisonalen Zyklen herzustellen, wobei wir erneut Gebrauch von der RA machen. Die letzte Publikation in dieser Arbeit untersucht, in wie fern die Vorhersagbarkeit saisonaler Veränderungen eine Rolle für die Stabilität von Gesellschaften spielen könnte, deren Nahrungsversorgung auf Landwirtschaft beruht. Die klassische Maya-Zivilisation erlitt zwischen 750-950 CE eine drastische Fragmentierung urbaner Zentren, die mit regionalen Dürren in Verbindung gebracht werden. Auf Grundlage von saisonal-aufgelösten Proxydaten aus der Yok Balum Höhle in Belize, definieren wir ein quantitatives Maß für saisonale Vorhersagbarkeit. Dies erlaubt Schlussfolgerungen über die potentielle Rolle, die ein Verlust saisonaler Vorhersagbarkeit für die sich destablisierenden agrarwirtschaftlichen und soziopolitischen Systeme der Maya gehabt haben könnte. Die methodischen Ansätze und Anwendungen in dieser Arbeit zeigen vielseitige, spannende Forschungsfragen für zukünftige Untersuchungen in der RA und Paläosaisonalität auf. KW - recurrence analysis KW - palaeoclimate KW - seasonality KW - nonlinear time series analysis KW - self-similarity KW - regime shifts KW - climate impact research KW - Klimafolgenforschung KW - nichtlineare Zeitreihenanalyse KW - Paläoklima KW - Rekurrenzanalyse KW - abrupte Übergänge KW - Selbstähnlichkeit Y1 - 2023 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-586900 ER - TY - THES A1 - Schemenz, Victoria T1 - Correlations between osteocyte lacuno-canalicular network and material characteristics in bone adaptation and regeneration T1 - Korrelationen zwischen dem lakuno-kanalikulären Netzwerk der Osteozyten und Materialeigenschaften bei der Knochenanpassung und -regeneration N2 - The complex hierarchical structure of bone undergoes a lifelong remodeling process, where it adapts to mechanical needs. Hereby, bone resorption by osteoclasts and bone formation by osteoblasts have to be balanced to sustain a healthy and stable organ. Osteocytes orchestrate this interplay by sensing mechanical strains and translating them into biochemical signals. The osteocytes are located in lacunae and are connected to one another and other bone cells via cell processes through small channels, the canaliculi. Lacunae and canaliculi form a network (LCN) of extracellular spaces that is able to transport ions and enables cell-to-cell communication. Osteocytes might also contribute to mineral homeostasis by direct interactions with the surrounding matrix. If the LCN is acting as a transport system, this should be reflected in the mineralization pattern. The central hypothesis of this thesis is that osteocytes are actively changing their material environment. Characterization methods of material science are used to achieve the aim of detecting traces of this interaction between osteocytes and the extracellular matrix. First, healthy murine bones were characterized. The properties analyzed were then compared with three murine model systems: 1) a loading model, where a bone of the mouse was loaded during its life time; 2) a healing model, where a bone of the mouse was cut to induce a healing response; and 3) a disease model, where the Fbn1 gene is dysfunctional causing defects in the formation of the extracellular tissue. The measurement strategy included routines that make it possible to analyze the organization of the LCN and the material components (i.e., the organic collagen matrix and the mineral particles) in the same bone volumes and compare the spatial distribution of different data sets. The three-dimensional network architecture of the LCN is visualized by confocal laser scanning microscopy (CLSM) after rhodamine staining and is then subsequently quantified. The calcium content is determined via quantitative backscattered electron imaging (qBEI), while small- and wide-angle X-ray scattering (SAXS and WAXS) are employed to determine the thickness and length of local mineral particles. First, tibiae cortices of healthy mice were characterized to investigate how changes in LCN architecture can be attributed to interactions of osteocytes with the surrounding bone matrix. The tibial mid-shaft cross-sections showed two main regions, consisting of a band with unordered LCN surrounded by a region with ordered LCN. The unordered region is a remnant of early bone formation and exhibited short and thin mineral particles. The surrounding, more aligned bone showed ordered and dense LCN as well as thicker and longer mineral particles. The calcium content was unchanged between the two regions. In the mouse loading model, the left tibia underwent two weeks of mechanical stimulation, which results in increased bone formation and decreased resorption in skeletally mature mice. Here the specific research question addressed was how do bone material characteristics change at (re)modeling sites? The new bone formed in response to mechanical stimulation showed similar properties in terms of the mineral particles, like the ordered calcium region but lower calcium content compared to the right, non-loaded control bone of the same mice. There was a clear, recognizable border between mature and newly formed bone. Nevertheless, some canaliculi went through this border connecting the LCN of mature and newly formed bone. Additionally, the question should be answered whether the LCN topology and the bone matrix material properties adapt to loading. Although, mechanically stimulated bones did not show differences in calcium content compared to controls, different correlations were found between the local LCN density and the local Ca content depending on whether the bone was loaded or not. These results suggest that the LCN may serve as a mineral reservoir. For the healing model, the femurs of mice underwent an osteotomy, stabilized with an external fixator and were allowed to heal for 21 days. Thus, the spatial variations in the LCN topology with mineral properties within different tissue types and their interfaces, namely calcified cartilage, bony callus and cortex, could be simultaneously visualized and compared in this model. All tissue types showed structural differences across multiple length scales. Calcium content increased and became more homogeneous from calcified cartilage to bony callus to lamellar cortical bone. The degree of LCN organization increased as well, while the lacunae became smaller, as did the lacunar density between these different tissue types that make up the callus. In the calcified cartilage, the mineral particles were short and thin. The newly formed callus exhibited thicker mineral particles, which still had a low degree of orientation. While most of the callus had a woven-like structure, it also served as a scaffold for more lamellar tissue at the edges. The lamelar bone callus showed thinner mineral particles, but a higher degree of alignment in both, mineral particles and the LCN. The cortex showed the highest values for mineral length, thickness and degree of orientation. At the same time, the lacunae number density was 34% lower and the lacunar volume 40% smaller compared to bony callus. The transition zone between cortical and callus regions showed a continuous convergence of bone mineral properties and lacunae shape. Although only a few canaliculi connected callus and the cortical region, this indicates that communication between osteocytes of both tissues should be possible. The presented correlations between LCN architecture and mineral properties across tissue types may suggest that osteocytes have an active role in mineralization processes of healing. A mouse model for the disease marfan syndrome, which includes a genetic defect in the fibrillin-1 gene, was investigated. In humans, Marfan syndrome is characterized by a range of clinical symptoms such as long bone overgrowth, loose joints, reduced bone mineral density, compromised bone microarchitecture, and increased fracture rates. Thus, fibrillin-1 seems to play a role in the skeletal homeostasis. Therefore, the present work studied how marfan syndrome alters LCN architecture and the surrounding bone matrix. The mice with marfan syndrome showed longer tibiae than their healthy littermates from an age of seven weeks onwards. In contrast, the cortical development appeared retarded, which was observed across all measured characteristics, i. e. lower endocortical bone formation, looser and less organized lacuno-canalicular network, less collagen orientation, thinner and shorter mineral particles. In each of the three model systems, this study found that changes in the LCN architecture spatially correlated with bone matrix material parameters. While not knowing the exact mechanism, these results provide indications that osteocytes can actively manipulate a mineral reservoir located around the canaliculi to make a quickly accessible contribution to mineral homeostasis. However, this interaction is most likely not one-sided, but could be understood as an interplay between osteocytes and extra-cellular matrix, since the bone matrix contains biochemical signaling molecules (e.g. non-collagenous proteins) that can change osteocyte behavior. Bone (re)modeling can therefore not only be understood as a method for removing defects or adapting to external mechanical stimuli, but also for increasing the efficiency of possible osteocyte-mineral interactions during bone homeostasis. With these findings, it seems reasonable to consider osteocytes as a target for drug development related to bone diseases that cause changes in bone composition and mechanical properties. It will most likely require the combined effort of materials scientists, cell biologists, and molecular biologists to gain a deeper understanding of how bone cells respond to their material environment. N2 - Knochen haben eine komplexe hierarchische Struktur, die einen lebenslangen Umbauprozess durchläuft, bei dem der Knochen sich seinen mechanischen Anforderungen anpasst. Um ein gesundes und stabiles Organ zu erhalten müssen Knochenresorption (durch Osteoklasten) und Knochenbildung (durch Osteoblasten) ausgewogen sein. Osteozyten lenken dieses Wechselspiel, indem sie mechanische Belastungen wahrnehmen und sie in biochemische Signale übersetzen. Die Osteozyten sitzen in Lakunen und sind durch Kanälchen untereinander und mit anderen Knochenzellen über ein Netzwerk (LCN) verbunden, das in der Lage ist, Ionen zu transportieren und eine Kommunikation von Zelle zu Zelle zu ermöglichen. Außerdem vermutet man, dass Osteozyten auch durch direkte Wechselwirkungen mit der umgebenden Matrix zur Mineralhomöostase beitragen könnten. Im Mittelpunkt dieser Arbeit steht die Frage, ob Osteozyten ihre materielle Umgebung aktiv verändern können. Um Spuren dieser Wechselwirkung zwischen Osteozyten und der extrazellulären Matrix nachzuweisen, werden materialwissenschaftliche Charakterisierungsmethoden eingesetzt. Zunächst wurden gesunde Mäuseknochen charakterisiert. Die erworbenen Ergebnisse wurden dann mit drei murinen Modellsystemen verglichen: 1) einem Belastungsmodell; 2) ein Heilungsmodell und 3) ein Krankheitsmodell, bei dem das Fbn1-Gen dysfunktional ist und Defekte in der Bildung des extrazellulären Gewebes verursacht werden. Die Messstrategie umfasste Routinen, die es ermöglichen, die Organisation des LCN und der Materialkomponenten (d.h. die organische Kollagenmatrix und die mineralischen Partikel) in denselben Knochenvolumina zu analysieren und die räumliche Verteilung der verschiedenen Datensätze zu vergleichen. Die dreidimensionale Netzwerkarchitektur des LCN wird durch konfokale Laser-Scanning-Mikroskopie nach Rhodamin-Färbung gemessen und anschließend quantifiziert. Der Kalziumgehalt wird mittels quantitativer Rückstreuelektronenbildgebung bestimmt, während Klein- und Weitwinkel-Röntgenstreuung verwendet werden, um die Dicke und Länge der Mineralpartikel zu bestimmen. Zunächst wurden Querschnitte der Unterschenkel von gesunden Mäusen charakterisiert, um zu untersuchen, ob Veränderungen in der LCN-Architektur auf Wechselwirkungen von Osteozyten mit der umgebenden Knochenmatrix zurückgeführt werden können. Die Kortizes zeigten zwei Hauptregionen, ein Band mit ungeordneter LCN-Architektur, umgeben von einer Region mit geordneter LCN. Die ungeordnete Region ist ein Überbleibsel der frühen Knochenbildung und wies kurze und dünne Mineralpartikel auf. Der umgebende, stärker ausgerichtete Knochen zeigte ein geordnetes und dichtes LCN, sowie dickere und längere Mineralpartikel. Der Kalziumgehalt blieb bei beiden Regionen unverändert. Im Mausbelastungsmodell wurde das linke Schienbein zwei Wochen lang mechanisch stimuliert, was zu einer erhöhten Knochenbildung führt. Hier sollte die Forschungsfrage beantwortet werden, wie sich Knochenmaterialeigenschaften an (Re-)Modellierungsstellen aufgrund von Belastung ändern. Der, als Reaktion auf die mechanische Stimulation, gebildete neue Knochen zeigte ähnliche Eigenschaften in Bezug auf die Mineralpartikel, wie die geordnete Kortexregion. Es gab eine klar erkennbare Grenze zwischen reifem und neu gebildetem Knochen. Trotzdem gingen einige Kanälchen durch diese Grenze, die die LCN aus reifem und neu gebildetem Knochen verband. Für das Heilungsmodell wurden die Oberschenkel von Mäusen einer Osteotomie unterzogen (einer Operation, bei der durch einen Schnitt in der Diaphyse ein Bruch erzeugt wird). Danach konnte die Fraktur 21 Tage heilen. Dadurch konnten in diesem Modell gleichzeitig verkalkter Knorpel, knöcherner Kallus und Kortex untersucht werden. Dafür wurde die räumliche Verteilung der LCN-Topologie sowie die Mineraleigenschaften der verschiedenen Gewebetypen und ihrer Grenzflächen visualisiert und verglichen. Alle Gewebetypen zeigten strukturelle Unterschiede über mehrere Längenskalen hinweg. Der Kalziumgehalt nahm von kalzifiziertem Knorpel zu knöchernem Kallus zu lamellarem kortikalem Knochen zu und wurde homogener. Der Grad der LCN-Organisation nahm ebenfalls zu, während die Lakunen vom Kallus zum Kortexgewebe kleiner wurden, ebenso wie die Lakunendichte. Im verkalkten Knorpel waren die Mineralpartikel kurz und dünn. Der größte Teil des Kallus wies eine Geflechtsknochenstruktur auf und diente als Gerüst für lamellares Gewebe, das dünnere Mineralpartikel, aber einen höheren Grad an Ausrichtung sowohl in den Mineralpartikeln als auch im LCN aufwies. Der Kortex zeigte die höchsten Werte für Minerallänge, Dicke und Orientierungsgrad. Obwohl nur wenige Kanälchen den Kallus und kortikale Regionen verbinden, weist dies darauf hin, dass eine Kommunikation zwischen Osteozyten beider Gewebe möglich sein sollte. Es wurde auch ein Mausmodell für das Marfan-Syndrom untersucht, das einen Gendefekt im Fibrillin-1-Gen beinhaltet. Beim Menschen ist das Marfan-Syndrom durch eine Reihe klinischer Symptome gekennzeichnet, wie z. B. übermäßiges Wachstum der Gliedmaßen, überstreckbare Gelenke, verringerte Knochenmineraldichte, beeinträchtigte Knochenmikroarchitektur und erhöhte Frakturraten. Somit scheint Fibrillin-1 eine Rolle in der Skeletthomöostase zu spielen. Deswegen untersuchte die vorliegende Arbeit, ob und wie das Marfan-Syndrom die LCN-Architektur und die umgebende Knochenmatrix verändert. Die Mäuse mit Marfan-Syndrom zeigten bereits ab einem Alter von sieben Wochen längere Schienbeine als ihre gesunden Wurfgeschwister. Im Gegensatz dazu erschien die kortikale Entwicklung verzögert, was über alle gemessenen Merkmale hinweg beobachtet wurde, d.h. niedrigere endokortikale Knochenbildung, lockereres und weniger organisiertes LCN, geringerer Grad an Kollagenorientierung sowie ein Trend zu dünneren und kürzeren Mineralpartikel. In jedem der drei Modellsysteme fand diese Studie, dass Änderungen in der LCN-Architektur räumlich mit Parametern des Knochenmatrixmaterials korrelierten. Obwohl der genaue Mechanismus nicht bekannt ist, liefern diese Ergebnisse Hinweise darauf, dass Osteozyten ein Mineralreservoir aktiv manipulieren können. Dieses Reservoir befindet sich um die Kanälchen herum und dieser Prozess würde es ermöglichen, einen schnell zugänglichen Beitrag zur Mineralhomöostase zu leisten. Diese Interaktion ist jedoch höchstwahrscheinlich nicht einseitig, sondern könnte als Wechselspiel zwischen Osteozyten und extrazellulärer Matrix verstanden werden, da die Knochenmatrix biochemische Signalmoleküle enthält, die das Verhalten von Osteozyten verändern können. Knochen(re)modellierung kann daher nicht nur als Methode zur Defektbeseitigung oder Anpassung an äußere mechanische Reize verstanden werden, sondern auch zur Effizienzsteigerung möglicher Osteozyten-Mineral-Interaktionen während der Knochenhomöostase. Angesichts dieser Ergebnisse erscheint es sinnvoll, Osteozyten als Ziel für die Arzneimittelentwicklung im Zusammenhang mit Knochenerkrankungen in Betracht zu ziehen, die Veränderungen der Knochenzusammensetzung und deren mechanischen Eigenschaften verursachen. KW - bone KW - lacunae KW - mineralization KW - SAXS KW - lacuno-canalicular network KW - µCT KW - CLSM KW - konfokales Laser-Scanning-Mikroskop KW - Kleinwinkelröntgenstreuung KW - Knochen KW - Lakunen KW - lakuno-kanaliculäres Netzwerk KW - Mineralisierung KW - µCT Y1 - 2022 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-559593 ER - TY - JOUR A1 - Sorgenfrei, Nomi A1 - Giangrisostomi, Erika A1 - Kühn, Danilo A1 - Ovsyannikov, Ruslan A1 - Föhlisch, Alexander T1 - Time and angle-resolved time-of-flight electron spectroscopy for functional materials science JF - Molecules : a journal of synthetic chemistry and natural product chemistry N2 - Electron spectroscopy with the unprecedented transmission of angle-resolved time-of-flight detection, in combination with pulsed X-ray sources, brings new impetus to functional materials science. We showcase recent developments towards chemical sensitivity from electron spectroscopy for chemical analysis and structural information from photoelectron diffraction using the phase transition properties of 1T-TaS2. Our development platform is the SurfaceDynamics instrument located at the Femtoslicing facility at BESSY II, where femtosecond and picosecond X-ray pulses can be generated and extracted. The scientific potential is put into perspective to the current rapidly developing pulsed X-ray source capabilities from Lasers and Free-Electron Lasers. KW - photoelectron spectroscopy KW - surface science KW - time-resolved KW - ultrafast KW - instrumentation KW - dichalcogenides KW - phase transition Y1 - 2022 U6 - https://doi.org/10.3390/molecules27248833 SN - 1420-3049 VL - 27 IS - 24 PB - MDPI CY - Basel ER - TY - JOUR A1 - Lever, Fabiano A1 - Mayer, Dennis A1 - Metje, Jan A1 - Alisauskas, Skirmantas A1 - Calegari, Francesca A1 - Düsterer, Stefan A1 - Feifel, Raimund A1 - Niebuhr, Mario A1 - Manschwetus, Bastian A1 - Kuhlmann, Marion A1 - Mazza, Tommaso A1 - Robinson, Matthew Scott A1 - Squibb, Richard J. A1 - Trabattoni, Andrea A1 - Wallner, Måns A1 - Wolf, Thomas J. A. A1 - Gühr, Markus T1 - Core-level spectroscopy of 2-thiouracil at the sulfur L1 and L2,3 edges utilizing a SASE free-electron-laser JF - Molecules N2 - In this paper, we report X-ray absorption and core-level electron spectra of the nucleobase derivative 2-thiouracil at the sulfur L1- and L2,3-edges. We used soft X-rays from the free-electron laser FLASH2 for the excitation of isolated molecules and dispersed the outgoing electrons with a magnetic bottle spectrometer. We identified photoelectrons from the 2p core orbital, accompanied by an electron correlation satellite, as well as resonant and non-resonant Coster–Kronig and Auger–Meitner emission at the L1- and L2,3-edges, respectively. We used the electron yield to construct X-ray absorption spectra at the two edges. The experimental data obtained are put in the context of the literature currently available on sulfur core-level and 2-thiouracil spectroscopy. KW - X-ray KW - photoelectron KW - sulfur KW - thiouracil KW - nucleobases KW - Coster–Kronig KW - Auger–Meitner KW - NEXAFS KW - FLASH Y1 - 2021 U6 - https://doi.org/10.3390/molecules26216469 SN - 1420-3049 VL - 26 IS - 21 PB - MDPI CY - Basel ER - TY - JOUR A1 - Tian, Peibo A1 - Liang, Yingjie T1 - Material coordinate driven variable-order fractal derivative model of water anomalous adsorption in swelling soil JF - Chaos, solitons & fractals N2 - The diffusion process of water in swelling (expansive) soil often deviates from normal Fick diffusion and belongs to anomalous diffusion. The process of water adsorption by swelling soil often changes with time, in which the microstructure evolves with time and the absorption rate changes along a fractal dimension gradient function. Thus, based on the material coordinate theory, this paper proposes a variable order derivative fractal model to describe the cumulative adsorption of water in the expansive soil, and the variable order is time dependent linearly. The cumulative adsorption is a power law function of the anomalous sorptivity, and patterns of the variable order. The variable-order fractal derivative model is tested to describe the cumulative adsorption in chernozemic surface soil, Wunnamurra clay and sandy loam. The results show that the fractal derivative model with linearly time dependent variable-order has much better accuracy than the fractal derivative model with a constant derivative order and the integer order model in the application cases. The derivative order can be used to distinguish the evolution of the anomalous adsorption process. The variable-order fractal derivative model can serve as an alternative approach to describe water anomalous adsorption in swelling soil. KW - water adsorption KW - variable order KW - fractal derivative KW - swelling soil KW - material coordinate Y1 - 2022 U6 - https://doi.org/10.1016/j.chaos.2022.112754 SN - 0960-0779 SN - 1873-2887 VL - 164 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Schneider, Sebastian A1 - Bytyqi, Kushtrim A1 - Kohaut, Stephan A1 - Bügel, Patrick A1 - Weinschenk, Benjamin A1 - Marz, Michael A1 - Kimouche, Amina A1 - Fink, Karin A1 - Hoffmann-Vogel, Regina T1 - Molecular self-assembly of DBBA on Au(111) at room temperature JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - We have investigated the self-assembly of the graphene nanoribbon molecular precursor 10,10'-dibromo-9,9'-bianthryl (DBBA) on Au(111) with frequency modulation scanning force microscopy (FM-SFM) at room temperature combined with ab initio calculations. For low molecular coverages, the molecules aggregate along the substrate herringbone reconstruction main directions while remaining mobile. At intermediate coverage, two phases coexist, zigzag stripes of monomer chains and decorated herringbones. For high coverage, the molecules assemble in a dimer-striped phase. The adsorption behaviour of DBBA molecules and their interactions are discussed and compared with the results from ab initio calculations. Y1 - 2022 U6 - https://doi.org/10.1039/d2cp02268k SN - 1463-9076 SN - 1463-9084 VL - 24 IS - 46 SP - 28371 EP - 28380 PB - Royal Society of Chemistry CY - Cambridge ER -