TY - THES A1 - Vergin, Annika T1 - Charakterisierung von Metallosupramolekularen Polyelektrolyten mittels analytischer Ultrazentrifugation Y1 - 2008 CY - Potsdam ER - TY - BOOK A1 - Koetz, Joachim A1 - Kosmella, Sabine T1 - Polyelectrolytes and nanoparticles T3 - Springer laboratory manuals in polymer science Y1 - 2007 SN - 3-540-46381-X PB - Springer-Verlag CY - Heidelberg ER - TY - JOUR A1 - Koetz, Joachim A1 - Andres, S. A1 - Kosmella, Sabine A1 - Tiersch, Brigitte T1 - BaSO4 nanorods produced in polymer-modified bicontinuous microemulsions N2 - The influence of the water soluble polymer poly(ethylene glycol) (PEG) on structure formation in the quasiternary system sodium dodecylsulfate (SDS)/pentanol-xylene/water was checked by means of conductometry, rheology, and micro differential calorimetry. The polymer induces the formation of an isotropic phase channel between the o/w and w/o microemulsion. The transition from the normal as well as from the inverse micellar to the bicontinuous phase range can be detected by conductometry, rheology as well as micro-DSC. As a result of polymer-surfactant interactions, the spontaneous curvature of the surfactant film is changed and a sponge phase is formed. The bicontinuous phase is characterized by a moderate shear viscosity, a Newtonian flow behaviour, and the disappearence of interphasal water in the heating curve of the micro-DSC. When the polymer-modified bicontinuous phase is used as a template phase for the nanoparticle formation, spherical BaSO4 nanoparticles were formed. During the following solvent evaporation process the primarily formed spherical nanoparticles aggregate to nanorods and triangular structures due to the non-restriction of the bicontinuous template phase in longitudinal direction Y1 - 2006 UR - http://www.ingentaconnect.com/content/vsp/ci U6 - https://doi.org/10.1163/156855406777408629 SN - 0927-6440 ER - TY - JOUR A1 - Engelhard, Sonja A1 - Kumke, Michael Uwe A1 - Löhmannsröben, Hans-Gerd T1 - Examples of the application of optical process and quality sensing (OPQS) to beer brewing and polyurethane foaming processes N2 - Optical methods play an important role in process analytical technologies (PAT). Four examples of optical process and quality sensing (OPQS) are presented, which are based on three important experimental techniques: near- infrared absorption, luminescence quenching, and a novel method, photon density wave (PDW) spectroscopy. These are used to evaluate four process and quality parameters related to beer brewing and polyurethane (PU) foaming processes: the ethanol content and the oxygen (O-2) content in beer, the biomass in a bioreactor, and the cellular structures of PU foam produced in a pilot production plant Y1 - 2006 UR - http://www.springerlink.com/content/100417 U6 - https://doi.org/10.1007/s00216-005-3364-4 SN - 1618-2642 ER - TY - JOUR A1 - Kamm, Birgit A1 - Kamm, Michael A1 - Schmidt, Matthias A1 - Starke, Ines A1 - Kleinpeter, Erich T1 - Chemical and biochemical generation of carbohydrates from lignocellulose-feedstock (Lupinus nootkatensis) : quantification of glucose N2 - Different chemical and enzymatic methods were applied for the hydrolysis of main stems from Lupinus nootkatensis (harvest November 2002). The whole process (all steps) is based on the lignocellulose-feedstock biorefinery regime. The acid hydrolysis of L. was performed with concentrated hydrochloric acid; advantages in this process are exothermic hydrolysis and the possibility of acid recovery. Enzymatic hydrolysis achieved high yields of fermentable carbohydrates (regarding to input cellulose) with high selectivity. However, this way requires the generation of cellulose from L. by chemical pulping. Monosaccharide derivatives thus obtained were identified by their GC retention times and the corresponding MS fragmentation. Hexamethyldisilazane was used as derivatization reagent to prepare the trimethylsilyl derivatives of the carbohydrates and of the degradations products of cellulose from the different fractions. The glucose content was quantified by GC peak integration with respect to an internal standard. Y1 - 2006 UR - http://www.sciencedirect.com/science/journal/00456535 U6 - https://doi.org/10.1016/j.chemosphere.2005.03.073 SN - 0045-6535 ER - TY - JOUR A1 - Kumke, Michael Uwe A1 - Eidner, Sascha A1 - Krüger, Tobias T1 - Fluorescence quenching and luminescence sensitization in complexes of Tb3+ and Eu3+ with humic substances N2 - Intrinsic fluorescence quenching of humic substances (HS) and the sensitization of Ln(3+) luminescence (Ln3+ Tb3+, Eu3+) in HS complexes were investigated. Both measurements yielded complementary information on the complexation of metals by HS. Large differences between fulvic acids(FA)and humic acids (HA) were found. From time-resolved luminescence measurements it is concluded that a combination of energy transfer and energy back transfer between HS and Ln(3+) is responsible for the observed luminescence decay characteristics. In the case of Eu3+, an additional participation of charge-transfer states is suggested. A new concept for the evaluation of the sensitized luminescence decays of Ln(3+) was adapted Y1 - 2005 ER - TY - JOUR A1 - Apitz, Sabine E. A1 - Bell, Elanor M. A1 - Damgaard, Lars A1 - Gilbert, Franck A1 - Glud, R A1 - Hall, P. O. J. A1 - Kershaw, P. J. A1 - Nickel, L A1 - Parker, R A1 - Rabouille, Christophe A1 - Shimmield, Grahamm A1 - Solan, Martin A1 - Soltwedel, Thomas A1 - Spagnoli, Federico A1 - Witte, Ursula T1 - Coastal Ocean Benthic Observatories (COBO) : integrated tools for the in situ observation and study of benthic ecosystem biogeochemical processes Y1 - 2005 ER - TY - JOUR A1 - Strehmel, Veronika A1 - Sarker, A. M. A1 - Lahti, P. M. A1 - Karasz, F. E. A1 - Heydenreich, Matthias A1 - Wetzel, Hendrik A1 - Haebel, Sophie A1 - Strehmel, Bernd T1 - One- and two-photon photochemistry and photophysics of poly(arylenevinylene)s containing a biphenyl moiety N2 - Photochemical and photophysical properties were investigated for poly(arylenevinylene)s containing a flexible biphenyl "hinge" unit by applying one-photon (OP) and two-photon (TP) excitation to explore excited-state properties. The poly(arylenevinylene)s were poly[(2,5-dihexyloxy-p-phenylenevinylene)-alt-(4,4'-dihexyloxy-3,3'-biph enylenevinylene)] (1), poly[(2,5-dihexyloxy-p-phenylenevinylene)-alt-(2,2'-dihexyloxy-3,3'-biph enylenevinylene)] (2), and poly[(2,5-dihexyloxy-p-phenylenevinylene)-alt-(2,2'-biphenylene-vinylene )] (3). Effective emission quantum yields and related photonic properties were evaluated on a realistic per-chromophore basis using effective conjugation lengths based on the Strickler-Berg relationship. intramolecular photocyclization was deduced to occur in the one case where the biphenyl molecular connectivity permitted the reaction, based on matrix- assisted loser desorption/ionization time-of-flight (MALDI-TOF), heteronuclear multiple-quantum coherence (HMQC)-NMR, and gel-permeation chromatography (GPC) results. The various photoprocesses could be induced by either OP or TP excitation, though the first excited singlet state is the photoactive state. The higher excitation energy 1 of the TP excited state favors indirect population of the S, state by electronic coupling between the TP and OP excited states [lambda(max)(TPE) (nm): 726; delta (GM)([9]): 1 = 229, 2 = 215, 3 = 109). Photochemical processes occurring from the lowest OP excited state (S-1) could therefore also be indirectly induced by TP excitation Y1 - 2005 SN - 1439-4235 ER - TY - JOUR A1 - Ritschel, Thomas A1 - Kuntz, Philip J. A1 - Zulicke, Lutz T1 - Structure and dynamics of cationic van-der-Waals clusters : I. Binding and structure of protonated argon clusters N2 - The geometric structure and bonding properties of medium-sized ArnH+ clusters (n = 2-35), in which a proton is wrapped up in a number of Ar atoms, are investigated by applying a diatomics-in-molecules (DIM) model with ab-initio input data generated by means of multi-reference configuration-interaction (MRCI) computations. For the smaller complexes, n = 2-7, cross-checking calculations employing the coupled-cluster approach (CCSD) with the same one-electron atomic basis set as for the input data calculations (aug-cc-pVTZ from Dunning), show good agreement thus justifying the extension of the DIM study to larger n. Local minima of the multi-dimensional potential-energy surfaces (PES) are determined by combining a Monte-Carlo sampling followed, for each generated point, by a steepest-descent optimization procedure. For the electronic ground state of the ArnH+ clusters, the global minimum (corresponding to the most stable structure of the cluster) as well as secondary minima are found and analyzed. The structural and energetic data obtained reveal the building-up regularities for the most stable structures and make it possible to formulate a simple increment scheme. The low-lying excited states are also calculated by the DIM approach; they all turn out to be globally repulsive Y1 - 2005 ER - TY - JOUR A1 - Löhmannsröben, Hans-Gerd T1 - Laser-induced fluorescence (LIF) spectroscopy and laser-based ion mobility (IM) spectrometry for in-situ analysis of contaminated soils Y1 - 2005 ER - TY - JOUR A1 - Löhmannsröben, Hans-Gerd A1 - Lau, Steffen T1 - Isotope selectivity in environmental monitoring : NIR diode laser spectroscopy for isotope-selective sensing of soil-respired carbon dioxide Y1 - 2005 ER - TY - GEN A1 - Koetz, Joachim A1 - Reichelt, S. A1 - Kosmella, Sabine A1 - Tiersch, Brigitte T1 - Recovery of nanoparticles produced in phosphatidylcholine-based template phases N2 - This paper focuses on the characterization and use of polymer-modified phosphatidylcholine (PC)/sodium dodecyl sulfate (SDS)-based inverse microemulsions as a template phase for BaSO4 nanoparticle formation. The area of the optically clear inverse microemulsion phase in the isooctane/hexanol/water/PC/SDS system is not significantly changed by adding polyelectrolytes, i.e., poly(diallyldimethylammonium chloride) (PDADMAC), or amphoteric copolymers of diallyldimethylammonium chloride and maleamid acid to the SDS-modified inverse microemulsion. Shear experiments show non- Newtonian flow behavior and oscillation experiments show a frequency-dependent viscosity increase (dilatant behavior) of the microemulsions. Small amounts of bulk water were identified by means of differential scanning calorimetry. One can conclude that the macromolecules are incorporated into the individual droplets, and polymer-filled microemulsions are formed. The polymer-filled microemulsions were used as a template phase for the synthesis of BaSO4 nanoparticles. After solvent evaporation the nanoparticles were redispersed in water and isooctane, respectively. The polymers incorporated into the microemulsion are involved in the redispersion process and influence the size and shape of the redispersed BaSO4 particles in a specific way. The crystallization process mainly depends on the type of solvent and the polymer component added. In the presence of the cationic polyelectrolyte PDADMAC the crystallization to larger cubic crystals is inhibited, and layers consisting of polymer-stabilized spherical nanoparticles of BaSO4 (6 nm in size) will be observed. (c) 2004 Elsevier Inc. All rights reserved Y1 - 2005 SN - 0021-9797 ER - TY - JOUR A1 - Kamm, Birgit A1 - Kamm, Michael T1 - Biorefinery : Carbohydrate line : Product line lactic acid Y1 - 2004 SN - 0065-7727 ER - TY - JOUR A1 - Dosche, Carsten A1 - Kumke, Michael Uwe A1 - Löhmannsröben, Hans-Gerd A1 - Ariese, Freek A1 - Bader, Arjen N. A1 - Gooijer, Cees A1 - Miljanic, Ognjen S. A1 - Iwamoto, M. A1 - Vollhardt, K. Peter C. A1 - Puchta, Ralph A1 - Hommes, N. J. R. V. T1 - Deuteration effects on the vibronic structure of the fluorescence spectra and the internal conversion rates of triangular [4]phenylene N2 - Deuteration effects on the vibronic structure of the emission and excitation spectra of triangular [ 4] phenylene (D-3h [4]phenylene) were studied using laser-excited Shpol'skii spectroscopy (LESS) in an octane matrix at 4.2 K. For correct assignment of the vibrational modes, the experimental results were compared with calculated frequencies (B3LYP/6-31G*). CH vibrations were identified by their characteristic isotopic shifts in the spectra of deuterated triangular [4]phenylenes. Two CC stretching modes, at 100 cm(-1) and 1176 cm(-1), suitable as probes for bond strength changes in the excited state, were identified. The isotope effect on the internal conversion rates of triangular [4] phenylene was evaluated from measurements of temperature dependent lifetime. Isotope dependency and the magnitude of the internal conversion rates indicate that internal conversion in triangular [4] phenylene is most likely induced by CH vibrations. The results obtained by LESS and lifetime measurements were compared with PM3 PECI calculations of the excited state structure. The theoretical results and the relation between ground and excited state vibration energies of the 1176 cm(-1) probe vibration indicate a reduction of bond alternation of the central cyclohexatriene ring in the excited state Y1 - 2004 SN - 1463-9076 ER - TY - JOUR A1 - Kamm, Birgit A1 - Kamm, Michael T1 - Polycarnitine : a new biomaterial Y1 - 2004 SN - 0065-7727 ER - TY - JOUR A1 - Koetz, Joachim A1 - Bahnemann, Jennifa A1 - Lucas, Gordon A1 - Tiersch, Brigitte A1 - Kosmella, Sabine T1 - Polyelectrolyte-modified microemulsions as new templates for the formation of nanoparticles N2 - The paper is focused on the formation and redispersion of monodisperse BaSO4 nanoparticles in polyelectrolyte- modified microemulsions. It is shown that a cationic polyelectrolyte of low molar mass, e.g. poly(dially1dimethylammonium chloride) (PDADMAC), can be incorporated into the individual inverse microemulsion droplets (L2 phase) consisting of heptanol, water, and an amphoteric surfactant with a sulfobetaine head group. These PDADMAC- filled microemulsion droplets can be successfully used as a template phase for the nanoparticle formation. The monodisperse BaSO4 nanoparticles are produced by a simple mixing procedure and can be redispersed after solvent evaporation without a change in particle dimensions. Dynamic and electrophoretical light scattering in combination with sedimentation experiments in the analytical Ultracentrifuge of the redispersed powder show polyelectrolyte-stabilized nanoparticles with diameters of about 6 nm. The polyelectrolyte shows a "size control effect", which can be explained by the polyelectrolyte-surfactant interactions in relation to the polyelectrolyte-nanoparticle interactions during the particle growth, solvent evaporation and redispersion process. However, the approach used here opens away to produce different types of polyelectrolyte-stabilized nanoparticles (including rare metals, semiconductors, carbonates or oxides) of very small dimensions. (C) 2004 Elsevier B.V. All rights reserved Y1 - 2004 SN - 0927-7757 ER - TY - JOUR A1 - Mahapatra, Susanta A1 - Ritschel, Thomas T1 - Multistate vibronic interactions and nonadiabatic wave packet dynamics in the second photoelectron band of chlorine dioxide N2 - We report theoretical investigations on the second photoelectron band of chlorine dioxide molecule by ab initio quantum dynamical methods. This band exhibits a highly complex structure and represents a composite portrait of five excited energetically close-lying electronic states of ClO2+. Much of this complexity is likely to be arising due to strong vibronic interactions among these electronic states - which we address and examine herein. The near equilibrium MRCI potential energy surfaces (PESs) of these five cationic states reported by Peterson and Werner [J. Chem. Phys. 99 (1993) 302] for the C2v configuration, are extended for the Cs geometry assuming a harmonic vibration along the asymmetric stretching mode. The strength of the vibronic coupling parameters of the Hamiltonian are calculated by ab initio CASSCF-MRCI method and conical intersections of the PESs are established. The diabatic Hamiltonian matrix is constructed within a linear vibronic coupling scheme and the resulting PESs are employed in the nuclear dynamical simulations, carried out with the aid of a time-dependent wave packet approach. Companion calculations are performed for transitions to the uncoupled electronic states in order to reveal explicitly the impact of the nonadiabatic coupling on the photoelectron dynamics. The theoretical findings are in good accord with the experimental observations. The femtosecond nonradiative decay dynamics of ClO2+ excited electronic states mediated by conical intersections is also examined and discussed. Y1 - 2003 ER - TY - JOUR A1 - Plantenberg, Thomas A1 - Koetz, Joachim T1 - Liquid Crystalline Polyanion/Polycation/Water Systems Y1 - 2001 ER - TY - THES A1 - Willert, Mirjam A. T1 - Prinzipien und Anwendungsmöglichkeiten nichtwäßriger und inverser Miniemulsionen Y1 - 2001 SN - 3-89873-329-7 PB - Cuvillier CY - Göttingen ER - TY - THES A1 - Polarz, Sebastian T1 - Konzepte der Nanochemie auf der Basis von porösen Materialien Y1 - 2001 ER - TY - THES A1 - Krasteva, Nadejda T1 - Influence of soluble sugars and DMSO on interactions and phase behaviour of phospholipid monolayers, thin foam films and bilayer dispersions Y1 - 2001 ER - TY - THES A1 - Rudloff, Jan T1 - Doppelthydrophile Blockcopolymere : Synthese und Einsatz in der biomimetischen Morphosynthese von CaCO3 Y1 - 2001 ER - TY - THES A1 - Drechsler, Ulrich T1 - Statische Lichtstreuung an Cellulose in Lösungsmittelsystemen mit N-Methylmorpholin-N-oxid Y1 - 2001 ER - TY - THES A1 - Tiarks, Franca T1 - Neue Strukturen und Synthesen durch die Miniemulsionspolymerisation: Polyaddition, Nanokapseln und Hybridpartikel Y1 - 2001 SN - 3-8265-8997-1 SN - 0945-070X PB - Shaker CY - Aachen ER - TY - THES A1 - Sapich, Beate T1 - Einfluss photochemischer Prozesse auf Dynamik und Ordnung photochromer Polymere Y1 - 2001 ER - TY - THES A1 - Smarsly, Bernd T1 - Charakterisierung poröser Materialien mit Methoden der Kleinwinkelstreuung Y1 - 2001 ER - TY - THES A1 - Schmitt, Cristopher T1 - Endfunktionalisierte Polyfluorene und konjugierte Blockcopolymere auf Polyfluorenbasis Y1 - 2001 ER - TY - THES A1 - Koehler, Bernhard T1 - Chirale Makrozyklen und Polymere aus Oligoarylen- und Spiroindan-Bausteinen Y1 - 2001 ER - TY - THES A1 - Lauter, Robert T1 - Struktur von Monoschichten bipolarer Amphiphile an der Wasser-Luft Grenzfläche Y1 - 2001 ER - TY - THES A1 - Moya, Sergio Enrique T1 - Architecture, permeability, electrical and mechanical properties of polyelectrolyte lipid composite capsules Y1 - 2001 ER - TY - JOUR A1 - Koetz, Joachim A1 - Kosmella, Sabine T1 - Interactions between Polyelectrolytes and Kaolin Y1 - 2001 ER - TY - BOOK A1 - Bechmann, Wolfgang A1 - Schmidt, Joachim A1 - Elschenbroich, Christoph A1 - Hensel, Friedrich A1 - Hopf, Henning T1 - Einstieg in die Physikalische Chemie für Nebenfächler T3 - Teubner Studienbücher Chemie N2 - Mit einer ausgewogenen Stoffauswahl wird der Leser an das Studium der Physikalischen Chemie herangeführt. Das Verständnis der Theorie wird durch zahlreiche Aufgabenstellungen und die Angabe ihrer Lösungswege erleichtert. Das vorliegende Buch gibt dem Studenten darüber hinaus Anregungen für ausgewählte Experimente zu den behandelten Teilgebieten. In der Durchführung und Auswertung der Experimente kann der Student erneut überprüfen, wie gut es ihm gelungen ist, ein Grundverständnis für physikalisch-chemische Zusammenhänge zu entwickeln. Y1 - 2001 SN - 3-519-00352-X U6 - https://doi.org/10.1007/978-3-322-94876-2 PB - Vieweg+Teubner Verlag CY - Wiesbaden ER - TY - JOUR A1 - Koetz, Joachim A1 - Kosmella, Sabine A1 - Beitz, Toralf T1 - Self-assembled Polyelectrolyte Systems Y1 - 2001 ER - TY - JOUR A1 - Heinze, Thomas A1 - Heinze, Ute A1 - Grothe, Carsten A1 - Koetz, Joachim A1 - Lazik, Waldemar T1 - Starch derivatives of high degree of functionalization : 4. Homogeneous tritylation of starch an subsequent carboxymethylation Y1 - 2001 ER - TY - JOUR A1 - Koetz, Joachim A1 - Bogen, Iris A1 - Heinze, Thomas A1 - Heinze, Ute A1 - Kulicke, Werner-Michael A1 - Lange, Silke T1 - Pecularities in the physico-chemical behaviour of non-statistically substituted carboxymethylcelluloses Y1 - 2001 ER - TY - JOUR A1 - Strehmel, Bernd T1 - Fluorescence Probes for Material Science Y1 - 2001 ER - TY - JOUR A1 - Kallies, Bernd A1 - Meier, R. T1 - The electronic structure od 3 [M(H20)6)3+ions from Sc(III)till Fe (III) : a quantum mechanical study based on DFT computations and natural bond orbital analyses Y1 - 2001 ER - TY - JOUR A1 - Illenseer, C. T1 - Investigation of ion-molecule collisions with laser-based ion mobility spectrometry Y1 - 2001 ER - TY - JOUR A1 - Strehmel, Bernd A1 - Henbest, K. B. A1 - Sarker, A. M. A1 - Malpert, J. H. A1 - Chen, D. Y. A1 - Rodgers, M. A. J. A1 - Neckers, D. C. T1 - Ion induced man ipulation of photochemical pathways in crown ether compounends based on fluorinated oligophenylenevinylenes Y1 - 2001 PB - Journal of nanoscience and nanotechnology. - 1 (2001), 1, S. 107 - 124 ER - TY - JOUR A1 - Beitz, Toralf A1 - Koetz, Joachim A1 - Wolf, Gunter A1 - Kleinpeter, Erich A1 - Friberg, Stig E. T1 - Poly(N-vinyl-2-pyrrolidone) and 1-octyl-2-pyrrolidinone modified ionic microemulsions Y1 - 2001 ER - TY - JOUR A1 - Schael, Frank A1 - Reich, Oliver T1 - In-situ-Analytik heterogener Medien mit frequenz- und leistungsmodulierten Diodenlasern N2 - Electronic intensity and frequency modulation of diode lasers enables new perspectives for highly sensitive analytical in-situ techniques. For analyis of "heterogeneous" media, which may consist of coexisting gaseous, liquid, and solid phases and often show multiple light scattering, non-invasive techniques with outstanding performance characteristics can be developed. Analysis of photon density waves launched by intensity-modulated lasers provide an elegant way for the determination of absorption and scattering coefficients of multiple scattering media. The absorption coefficient can be used for qualitative and quantitative analysis of chemical constituents (which absorb in the range of the laser wavelengths). The scattering coefficient allows characterization of physical and morphological properties of the sample. In the current work, applicability of appropriate radiation transport models was investigated with simple light scattering solutions and compared with results obtained from the treatment according to the theory of Kubelka and Munk. Measurements of human blood samples are discussed. A new method for determination of water vapor partial pressure in a polyurethane foam with a frequency-modulated external cavity diode laser is discussed. Y1 - 2001 ER - TY - JOUR A1 - Schael, Frank A1 - Engelhard, Sonja A1 - Reich, Oliver T1 - Optische Sensorik für die in-situ-Analytik von Brauprozessen Y1 - 2001 ER - TY - JOUR A1 - Koetz, Joachim A1 - Beitz, Toralf A1 - Kosmella, Sabine A1 - Tiersch, Brigitte T1 - Polymer-modified microemulsions Y1 - 2000 ER - TY - JOUR A1 - Koetz, Joachim A1 - Tiersch, Brigitte A1 - Bogen, Iris T1 - Polyelectrolyte induced vesicle-formation in lamellar liquid crystalline model systems Y1 - 2000 ER - TY - THES A1 - Thünemann, Andreas F. T1 - Self-assembly, ordered nanostructures and functionality of polyelectrolyte-amphiphile complexes Y1 - 2000 ER - TY - THES A1 - Beyermann, Jochen T1 - Immobilisierung von Vitamin A-Säure mit kationischen Polyelektrolyten : Polyelektrolyt-Tensid-Komplexe als potentielle Wirkstoffträger Y1 - 2000 ER - TY - THES A1 - Schütte, Markus T1 - Metallosupramolekulare Polyelektrolytfilme Y1 - 2000 ER - TY - THES A1 - Schellenberg, Carsten T1 - Nanaostrukturierte Polymermaterialien auf der Basis von Kern-Schale Dispersionen T2 - Berichte aus der Chemie Y1 - 2000 SN - 3-8265-7635-7 PB - Shaker CY - Aachen ER - TY - THES A1 - Putlitz, Bodo zu T1 - Neue Tensidstrukturen und ihre Eigenschaften Y1 - 2000 SN - 3-89712-901-9 PB - Cuvillier CY - Göttingen ER - TY - THES A1 - Ruppelt, Dirk T1 - Polyelektrolyt-Tensid-Komplexe als elektrooptische Materialien Y1 - 2000 ER - TY - THES A1 - Börger, Lars T1 - Biomimetische Mineralisationsprozesse und deren Charakterisierung Y1 - 2000 ER - TY - BOOK A1 - Bechmann, Wolfgang A1 - Schmidt, Joachim T1 - Struktur- und Stoffanalytik mit spektroskopischen Methoden T3 - Teubner Studienbücher Chemie Y1 - 2000 SN - 3-519-03552-9 U6 - https://doi.org/10.1007/978-3-322-80123-4 PB - Vieweg+Teubner Verlag CY - Wiesbaden ER - TY - JOUR A1 - Kamm, Birgit A1 - Kamm, Michael A1 - Kromus, Stefan A1 - Narodoslawsky, Michael T1 - Green Biorefinery - European Network for the Implementation of Biorefineries (NIB) Y1 - 2000 ER - TY - JOUR A1 - Löhmannsröben, Hans-Gerd A1 - Lemke, Matthias A1 - Schober, Lars A1 - Schultze, Rainer T1 - In-situ Analytik von organischen Bodenkontaminationen mit Laser-induzierter Fluoreszenz Y1 - 2000 ER - TY - JOUR A1 - Löhmannsröben, Hans-Gerd A1 - Theo, Hengstermann A1 - Lemke, Matthias A1 - Schober, Lars A1 - Schultze, Rainer T1 - Entwicklung eines optischen Meßsystems zur in-situ Bestimmung von Fluoreszenztracern, Sauerstoff und pH- Wert in Gewässern (FLUTRAS: Fluorescence Tracer Detection System) Y1 - 2000 ER - TY - JOUR A1 - Koetz, Joachim T1 - Adsorption von polyelektrolyten an kolloidalen Partikeln Y1 - 2000 SN - 3-8265-7819-8 ER - TY - JOUR A1 - Schober, Lars A1 - Löhmannsröben, Hans-Gerd T1 - Determination of optical parameters for light penetration in particulate materials and soils with diffuse reflectance (DR) spectroscopy Y1 - 2000 ER - TY - JOUR A1 - Kallies, Bernd A1 - Kunz, Iris A1 - Klaus, Susanne A1 - Schorr, Ulrike A1 - Sharma, Arya M. T1 - Kinetic analysis of the thermic effect of food and its relationship to body composition in humans N2 - The course of energy expenditure after a meal can vary widely with regard to the slope of onset, amplitude, and duration of the thermic effect. The aim of the present study was to explore the relationship between the thermic effect of food (TEF), as characterized by kinetic analysis of postprandial energy expenditure, body composition, and variables related to the metabolic syndrome including central obesity, hypertension, and glucose tolerance. A total of 181 men and women (body mass index [BMI] range, 19.4 to 52.2 kg/m2) were characterized for body composition, blood pressure, oral glucose tolerance, and energy expenditure after a test meal. Energy expenditure, as measured by indirect calorimetry, was analyzed over a 6-hour period by 3-parameter curve fitting using equations derived from kinetics describing a biphasic reaction involving 2 consecutive first-order reactions (A->B->C). Apart from total thermic effect of food (TEFk), the curve also provided an estimate of time of peak (Tp) and amplitude of peak (Ap) for each subject. Multiple stepwise regression analysis with TEFk, Ap, and Tp as dependent variables showed significant effects of sex, age, body weight, body fat, -blockade, and body composition on TEF curve parameters. Cluster analysis based on Tp shown 2 distinct clusters with significant differences in age and body fat mass. This study shows that kinetic analysis of postprandial energy expenditure can be used to examine the determinants of the time course of the thermic effect of food in man. Y1 - 2000 ER - TY - THES A1 - Stapff, Inga Heike T1 - Mechanische Abbildung nanostrukturierter Polymerfilme Y1 - 2000 ER - TY - THES A1 - Holzwarth, Andrea T1 - Molekulare Ordnung und Benetzungsverhalten von Alkanen an der Luft-Si/SiO2-Grenzfläche Y1 - 2000 ER - TY - THES A1 - Krämer, Eckart T1 - Amphiphile Blockcopolymere : lyotropes Phasenverhalten und ihre Nutzung zur Morphosynthese T2 - Berichte aus der Chemie Y1 - 2000 SN - 3-8265-7030-8 SN - 0945-070X PB - Shaker CY - Aachen ER - TY - THES A1 - Cölfen, Helmut T1 - Biomimetric mineralisation using hydrophilic copolymers : synthesis of hybrid colloids with complex from and pathways towards their analysis in solution Y1 - 2000 ER - TY - JOUR A1 - Kumke, Michael Uwe A1 - Specht, C. H. A1 - Frimmel, Fritz Hartmann T1 - Characterization of NOM adsorption to clay minerals by sizs exclusion chromatography Y1 - 2000 ER - TY - JOUR A1 - Löhmannsröben, Hans-Gerd T1 - In situ Laser-induced fluorescence (LIF) analysis pf petroleum product-contaminared soil samples Y1 - 2000 ER - TY - JOUR A1 - Kumke, Michael Uwe A1 - Zwiener, Christian A1 - Abbt-Braun, Gudrun A1 - Frimmel, Fritz Hartmann T1 - Spectroscopic characterization of fulvic acid fractions of a contaminated groundwater Y1 - 2000 ER - TY - JOUR A1 - Haitzer, Markus A1 - Löhmannsröben, Hans-Gerd A1 - Steinberg, Christian E. W. A1 - Zimmermann, Ute T1 - In vivo laser-induced fluorescence detection of pyrene in nematodes and determination of pyrene binding constants for humic substances by fluorescences quenching and bioaccumulation experiments Y1 - 2000 ER - TY - JOUR A1 - Kumke, Michael Uwe A1 - Ohlenbusch, G. A1 - Frimmel, Fritz Hartmann T1 - Sorption of phenols to dissolved organic matter investigaded by solid phase micriextrakrion Y1 - 2000 ER - TY - JOUR A1 - Grote, Matthias A1 - Klinnert, Silke A1 - Bechmann, Wolfgang T1 - Comparison of degradation state and stability of different humic acids by means of chemolysis with tetramethylammonium hydroxide (TMAH) Y1 - 2000 ER - TY - THES A1 - Laudien, Robert T1 - Mechanismen der basischen und sauren Hydrolyse der Phenylkohlensäurederivate Y1 - 2000 ER - TY - JOUR A1 - Schael, Frank A1 - Reich, Oliver A1 - Löhmannsröben, Hans-Gerd T1 - Near infrared diode laser spectroscopy of organic compounds in turbid aqueous solutions N2 - Diffuse reflectance measurements and photon migration studies with near infrared (NIR) diode lasers were employed to elucidate experimental methods for determining absorption and scattering coefficients and species concentrations in highly scattering solutions. Applicability of theoretical approaches were established by investigating model systems with absorbing (e.g. ink, malachite green) and scattering (e.g. milk powder, caolinit) species in aqueous solution. While diffuse reflectance measurements practically requires calibration procedures, photon migration studies allow quantitative determination of absorption and scattering coefficients of turbid solutions consistent with absorptions coefficients obtained from Lambert-Beer's law. Furthermore, NIR absorption spectra of water, chlorinated hydrocarbons (chloroform, 1,2-dichloroethane, trichloroethene) and of various sugars ($alpha$-D-glucose, sucrose, maltose) are discussed. Spectral variations of NIR water absorption with temperature and solvents are exammined. Exemplary, NIR diode laser detection of water in acetone/water mixtures is performed. Y1 - 2000 SN - 0-9528666-1-7 ER - TY - JOUR A1 - Löhmannsröben, Hans-Gerd A1 - Schael, Frank A1 - Reich, Oliver A1 - Lemke, Matthias A1 - Schober, Lars T1 - Untersuchung von organischer Bodensubstanz und Bodengasen mit laser-spektroskopischer in-situ Meßtechnik Y1 - 2000 ER - TY - JOUR A1 - Bechthold, Nina A1 - Tiersch, Brigitte A1 - Koetz, Joachim A1 - Friberg, Stig E. T1 - Structure Formation in polymer-modified liquid crystals Y1 - 1999 ER - TY - JOUR A1 - Koetz, Joachim A1 - Beitz, Toralf A1 - Tiersch, Brigitte T1 - Self assembled polymer-surfactant systems Y1 - 1999 ER - TY - THES A1 - Regenbrecht, Matthias T1 - Untersuchung des Benetzungsverhaltens wasserlöslicher mizellarer Polyelektrolyt-Diblockcopolymer-Aggregate an der Luft/Festkörper- und Flüssig/Festkörper-Grenzfläche auf Nanometer-Skala mit der Rasterkraftmikroskopie Y1 - 1999 ER - TY - JOUR A1 - Koetz, Joachim A1 - Kosmella, Sabine T1 - Polymers in lyotropic liquid crystals Y1 - 1999 ER - TY - JOUR A1 - Koetz, Joachim T1 - Interactions between charged colloids and polyelectrolytes (invited lecture) Y1 - 1999 SN - 0-89852- 748-1 ER - TY - THES A1 - Priester, Torsten T1 - Zur Lösung eines thermodynamischen Phänomens der Adsorption amphiphiler Stoffe an fluiden Phasengrenzflächen : die lineare Abhängigkeit der Gleichgewichtsoberflächenspannung vom Logarithmus der Volumenkonzentration T2 - UFO Dissertation Y1 - 1999 SN - 3-930803-71-2 VL - 372 PB - UFO Atelier für Gestaltung und Verl. CY - Allensbach ER - TY - THES A1 - Mallwitz, Frank T1 - Synthese und Charakterisierung monomolekularer dicker Polyisobutenfilme mit ionischen Ankergruppen Y1 - 1999 ER - TY - THES A1 - Gau, Astrid T1 - Polymerbedeckte Lipidvesikel Y1 - 1999 CY - Potsdam ER - TY - THES A1 - Deckwer, Roland T1 - Oligomere in der Emulsionspolymerisation von Styrol : Eigenschaften und Charakterisierung Y1 - 1999 ER - TY - THES A1 - Roosterman, Dirk T1 - Untersuchungen zur Agonisten-induzierten Internalisierung der Somatostatin-Rezeptoren Y1 - 1999 ER - TY - THES A1 - Berton, Beate T1 - Bildung und Struktur mesoporöser Silikatgläser mit Funktionalität Y1 - 1999 CY - Potsdam ER - TY - THES A1 - Bogen, Iris T1 - Physikochemische Eigenschaften und Strukturbildungsverhalten von neuartig substituierten Carboxymethylcellulosen Y1 - 1999 ER - TY - THES A1 - Schilling, Kristian T1 - Charakterisierung mizellarer Systeme mit der Analytischen Ultrazentrifuge : Synthese von Titandioxid in mizellaren Reaktionsräumen Y1 - 1999 SN - 3-89712-739-3 PB - Cuvillier CY - Göttingen ER - TY - THES A1 - Toca-Herrara, José Luis = Herrera T1 - Wechselwirkungskräfte und Struktur in Phospholipid-Schaumfilmen Y1 - 1999 CY - Potsdam ER - TY - THES A1 - Schladitz, Claudia T1 - Proteinsekundärstrukturen an der fluiden Grenzfläche - in situ - Untersuchungen mit der IRRAS Y1 - 1999 CY - Potsdam ER - TY - JOUR A1 - Tschochner, Bernd A1 - Blumenstein, Oswald A1 - Krüger, Wolfgang A1 - Bechmann, Wolfgang T1 - Geoökologische Aspekte der Schadstoffdynamik in einem antarktischen Geosystem Y1 - 1999 ER - TY - JOUR A1 - Schwarz, W. H. Eugen A1 - Andrae, Dirk A1 - Arnold, S. R. A1 - Heidberg, Joachim A1 - Hellmann jr., H. A1 - Hinze, J. A1 - Karachalios, A. A1 - Kovner, M. A. A1 - Schmidt, P. C. A1 - Zülicke, Lutz T1 - Hans G. Hellmann (1903 - 1938) : ein deutscher Pionier der Quantenchemie in Moskau Y1 - 1999 ER - TY - JOUR A1 - Schwarz, W. H. Eugen A1 - Andrae, Dirk A1 - Arnold, S. R. A1 - Heidberg, Joachim A1 - Hellmann jr., H. A1 - Hinze, J. A1 - Karachalios, A. A1 - Kovner, M. A. A1 - Schmidt, P. C. A1 - Zülicke, Lutz T1 - Hans G. Hellmann (1903 - 1938) : ein Pionier der Quantenchemie Y1 - 1999 ER - TY - JOUR A1 - Zuhrt, Christian A1 - Neumann, Rainer A1 - Zülicke, Lutz T1 - Investigation of vibrational states of the ArHCl+ cation in the electronic ground state Y1 - 1999 ER - TY - THES A1 - Netz, Roland R. T1 - Field-theoretic approaches to clasical charged systems Y1 - 1999 ER - TY - JOUR A1 - Kosmella, Sabine A1 - Koetz, Joachim A1 - Shirahama, K. T1 - Binding of dodecylpyridinium chloride to anionic co-polymers and their complexes Y1 - 1999 ER - TY - JOUR A1 - Beitz, Toralf A1 - Koetz, Joachim A1 - Friberg, Stig E. T1 - Polymer-modified ionic microemulsion formed in the system SDS/Water/Xylene/Pentanol Y1 - 1999 ER - TY - JOUR A1 - Beyermann, Jochen A1 - Koetz, Joachim A1 - Jäger, Werner A1 - Friberg, Stig E. T1 - Influence of charge density of anionic polyelectrolytes on structure formation in liquid crystalline systems Y1 - 1999 ER - TY - JOUR A1 - Tessmann, Joachim A1 - Beitz, Toralf A1 - Bechmann, Wolfgang A1 - Mitzner, Rolf T1 - Untersuchungen zu Toxizitätsänderungen in Photoreaktionen von Azaarenen Y1 - 1999 ER - TY - JOUR A1 - Beitz, Toralf A1 - Bechmann, Wolfgang A1 - Mitzner, Rolf T1 - Investigation on the photoreactions of Nitrate and Nitrite ions with selected Azaarenes in water Y1 - 1999 ER - TY - JOUR A1 - Koetz, Joachim A1 - Bogen, Iris A1 - Heinze, Ute A1 - Heinze, Thomas A1 - Klemm, D. A1 - Lange, Silke A1 - Kulicke, Werner-Michael T1 - Kolloideigenschaften statistisch, blockartig und regioselektiv substituierter Carboxymethylcellulosen Y1 - 1998 SN - 0031-1340 ER - TY - JOUR A1 - Koetz, Joachim A1 - Plantenberg, Thomas T1 - Self-assembled polyanion-polycation systems Y1 - 1998 SN - 0-9585708-1-7 ER - TY - THES A1 - Richter, Bernd T1 - Selbstorganisierte Hetero-Mulitschichtstrukturen als elektrolumineszierende Bauelemente Y1 - 1998 CY - Potsdam ER - TY - THES A1 - Giersig, Michael T1 - Physikalisch-chemische Charakterisierung von kolloidalen Halbleiter- und Metallteilchen Y1 - 1998 CY - Potsdam ER -