TY - GEN A1 - Kaafarani, Bilal R. A1 - Wex, Brigitte A1 - Strehmel, Bernd A1 - Neckers, Douglas C. T1 - Structural concept for fluorinated Y-enynes with solvatochromic properties N2 - An approach to the development of fluorescent probes to follow polymerizations in situ using fluorinated cross-conjugated enediynes (Y-enynes) is reported. Different substitution patterns in the Y-enynes result in distinct solvatochromic behavior. β,β-Bis(phenylethynyl)pentafluorostyrene 7, which bears no donor substituents and only fluorine at the styrene moiety, shows no solvatochromism. Donor substituted β,β-bis(3,4,5-trimethoxyphenylethynyl) pentafluorostyrene 8 and β,β-bis(4-butyl-2,3,5,6-tetrafluorophenylethynyl)-3,4,5-trimethoxystyrene 9 exhibit solvatochromism upon change of solvent polarity. Y-enyne 8 showed the largest solvatochromic shift (94 nm bathochromic shift) upon changing solvent from cyclohexane to acetonitrile. A smaller solvatochromic response (44 nm bathochromic shift) was observed for 9. Lippert–Mataga treatment of 8 and 9 yields slopes of -10,800 and -6,400 cm -1, respectively. This corresponds to a change in dipole moment of 9.6 and 6.9 D, respectively. The solvatochromic behavior in 8 and 9 supports the formation of an intramolecular charge transfer (ICT) state. The low fluorescence quantum yields are caused by competitive double bond rotation. The fluorescence decay time of 9 decreases in methyltetrahydrofuran from 2.1 ns at 77 K to 0.11 ns at 200 K. Efficient single bond rotation in 9 was frozen at -50 °C in a configuration in which the trimethoxyphenyl ring is perpendicular to the fluorinated rings. 7–9 are photostable compounds. The X-ray structure of 7 shows it is not planar and that its conjugation is distorted. Y-enyne 7 stacks in the solid state showing coulombic, actetylene–arene, and fluorine–π interactions. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - paper 027 Y1 - 2002 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13168 ER - TY - GEN A1 - Dosche, Carsten A1 - Mickler, Wulfhard A1 - Löhmannsröben, Hans-Gerd A1 - Agenet, Nicolas A1 - Vollhardt, K. Peter C. T1 - Photoinduced electron transfer in [N]phenylenes N2 - First studies of electron transfer in [N]phenylenes were performed in bimolecular quenching reactions of angular [3]- and triangular [4]phenylene with various electron acceptors. The relation between the quenching rate constants kq and the free energy change of the electron transfer (ΔG0CS ) could be described by the Rehm-Weller equation. From the experimental results, a reorganization energy λ of 0.7 eV was derived. Intramolecular electron transfer reactions were studied in an [N]phenylene bichomophore and a corresponding reference compound. Fluorescence lifetime and quantum yield of the bichromophor display a characteristic dependence on the solvent polarity, whereas the corresponding values of the reference compound remain constant. From the results, a nearly isoenergonic ΔG0CS can be determined. As the triplet quantum yield is nearly independent of the polarity, charge recombination leads to the population of the triplet state. T3 - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 23 KW - [N]phenylenes KW - photoinduced electron transfer KW - [N]phenylene dyads Y1 - 2007 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-12463 ER - TY - GEN A1 - Ludwig, Joachim A1 - Kielmann, Harald T1 - Beraten statt Verkünden : neue Wege in der gewerkschaftlichen Bildungsarbeit N2 - Es gibt aus unserer Sicht eine Reihe von Gründen, sich in der gewerkschaftlichen Bildungsarbeit von der Dominanz des Lehrplans abzuwenden und sich an Stelle dessen dem Lernenden in einer Weise zuzuwenden, die seine Deutungen, seine Handlungsmotive und seine Lerninteressen in den Vordergrund stellt. Für den Bildungspraktiker ergeben sich Gründe vor allem aus der wiederholten Erfahrung von Diskrepanzen. Erstens die Diskrepanzen, die zwischen der Definition von Lehrzielen und ihrem Erreichen in der Erwachsenenbildung bestehen. Zweitens die Diskrepanzen, die zwischen dem tatsächlich erlernten Wissen und seiner Umsetzung und Anwendung in der Praxis sich auftun. (aus dem Inhalt) T3 - Zweitveröffentlichungen der Universität Potsdam : Humanwissenschaftliche Reihe - paper 019 Y1 - 2000 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-13875 ER - TY - GEN A1 - Fischer, Christian T1 - Variation und Korrelation im Mittelniederdeutschen : Möglichkeiten und Grenzen der Variablenlinguistik Y1 - 2005 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-9975 ER - TY - GEN A1 - Weissberg, Liliane T1 - Die Unschuld des Namens und die ungeheure Unordnung der Welt Y1 - 2005 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-10008 ER - TY - GEN A1 - Willemyns, Roland A1 - Vanhecke, Eline A1 - Vandenbussche, Wim T1 - Politische Loyalität und Sprachwahl : eine Fallstudie aus dem Flandern des frühen 19. Jahrhunderts Y1 - 2005 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-10014 ER - TY - GEN A1 - Kindelberger, Kilian A1 - Schmidt, Heiko T1 - Terror, Glaubenskrieg und Fundamentalismus Y1 - 2002 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-9499 ER - TY - GEN A1 - Brabandt, Heike A1 - Locher, Birgit A1 - Prügl, Elisabeth T1 - Normen, Gender und Politikwandel : internationale Beziehungen aus der Geschlechterperspektive ; eine Einführung N2 - This introduction provides an overview of feminist approaches to International Relations. The authors compare the Anglo-American debate with the Germanspeaking discussion in order to reveal similarities and differences. They identify three particular areas of research that characterize the German-speaking feminist debate in International Relations: (1) works evolving out of peace studies; (2) research on globalization and international economic institutions; (3) studies focusing on women’s movements together with most current works centering around international norms. They argue that feminist approaches to norms constitute a particularly promising research area which provides new "tools" to account for international, regional or domestic policy-change. Gender-sensitive research on norms also allows to address ethical questions that are vital for feminist understandings of science. Moreover, this new focus on norms enables bridge-building between feminism and the mainstream. KW - gender KW - norms KW - International Relations KW - NGOs KW - feminism Y1 - 2002 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-9517 ER - TY - GEN A1 - Brill, Heinz T1 - Das Zeitalter der Globalisierung Y1 - 2002 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-9528 ER - TY - GEN A1 - Mols, Manfred T1 - Was sind und zu welchem Ende betreiben wir Regionalwissenschaften? : Eine politikwissenschaftliche Perspektive N2 - On the occasion of his farewell lecture, Manfred Mols looks back to his academic work of the last four decades, and discusses the essential meaning of area studies. He tries to clarify the important denotation of institutes for regional researchers. Area studies should help us to understand changing processes in international policies and they do. He underlines his critical point of view with the position and treatment of area studies among certain universities in Germany. KW - area studies KW - political science Y1 - 2002 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-9539 ER -