TY - JOUR A1 - Acciari, V. A. A1 - Aliu, E. A1 - Arlen, T. A1 - Aune, T. A1 - Beilicke, M. A1 - Benbow, W. A1 - Bradbury, S. M. A1 - Buckley, J. H. A1 - Bugaev, V. A1 - Byrum, K. A1 - Cannon, A. A1 - Cesarini, A. A1 - Ciupik, L. A1 - Collins-Hughes, E. A1 - Cui, W. A1 - Dickherber, R. A1 - Duke, C. A1 - Errando, M. A1 - Finley, J. P. A1 - Finnegan, G. A1 - Fortson, L. A1 - Furniss, A. A1 - Galante, N. A1 - Gall, D. A1 - Gillanders, G. H. A1 - Godambe, S. A1 - Griffin, S. A1 - Grube, J. A1 - Guenette, R. A1 - Gyuk, G. A1 - Hanna, D. A1 - Holder, J. A1 - Hughes, J. P. A1 - Hui, C. M. A1 - Humensky, T. B. A1 - Kaaret, P. A1 - Karlsson, N. A1 - Kertzman, M. A1 - Kieda, D. A1 - Krawczynski, H. A1 - Krennrich, F. A1 - Lang, M. J. A1 - LeBohec, S. A1 - Madhavan, A. S. A1 - Maier, G. A1 - Majumdar, P. A1 - McArthur, S. A1 - McCann, A. A1 - Moriarty, P. A1 - Mukherjee, R. A1 - Ong, R. A. A1 - Orr, M. A1 - Otte, A. N. A1 - Pandel, D. A1 - Park, N. H. A1 - Perkins, J. S. A1 - Pohl, Martin A1 - Quinn, J. A1 - Ragan, K. A1 - Reyes, L. C. A1 - Reynolds, P. T. A1 - Roache, E. A1 - Rose, H. J. A1 - Saxon, D. B. A1 - Schroedter, M. A1 - Sembroski, G. H. A1 - Senturk, G. Demet A1 - Slane, P. A1 - Smith, A. W. A1 - Tesic, G. A1 - Theiling, M. A1 - Thibadeau, S. A1 - Tsurusaki, K. A1 - Varlotta, A. A1 - Vassiliev, V. V. A1 - Vincent, S. A1 - Vivier, M. A1 - Wakely, S. P. A1 - Ward, J. E. A1 - Weekes, T. C. A1 - Weinstein, A. A1 - Weisgarber, T. A1 - Williams, D. A. A1 - Wood, M. A1 - Zitzer, B. T1 - Discovery of OF TeV Gamma-Ray emission from tycho's supernova remnant JF - The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters N2 - We report the discovery of TeV gamma-ray emission from the Type Ia supernova remnant (SNR) G120.1+1.4, known as Tycho's SNR. Observations performed in the period 2008-2010 with the VERITAS ground-based gamma-ray observatory reveal weak emission coming from the direction of the remnant, compatible with a point source located at 00(h)25(m)27(s).0, +64 degrees 10'50 '' (J2000). The TeV photon spectrum measured by VERITAS can be described with a power law dN/dE = C(E/3.42 TeV)(-Gamma) with Gamma = 1.95 +/- 0.51(stat) +/- 0.30(sys) and C = (1.55 +/- 0.43(stat) +/- 0.47(sys)) x 10(-14) cm(-2) s(-1) TeV-1. The integral flux above 1 TeV corresponds to similar to 0.9% of the steady Crab Nebula emission above the same energy, making it one of the weakest sources yet detected in TeV gamma rays. We present both leptonic and hadronic models that can describe the data. The lowest magnetic field allowed in these models is similar to 80 mu G, which may be interpreted as evidence for magnetic field amplification. KW - gamma rays: general KW - ISM: individual objects (G120.1+01.4, Tycho=VER J0025+641) Y1 - 2011 U6 - https://doi.org/10.1088/2041-8205/730/2/L20 SN - 2041-8205 VL - 730 IS - 2 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Aliu, E. A1 - Arlen, T. A1 - Aune, T. A1 - Beilicke, M. A1 - Benbow, W. A1 - Boettcher, Markus A1 - Bouvier, A. A1 - Bradbury, S. M. A1 - Buckley, J. H. A1 - Bugaev, V. A1 - Cannon, A. A1 - Cesarini, A. A1 - Ciupik, L. A1 - Collins-Hughes, E. A1 - Connolly, M. P. A1 - Cui, W. A1 - Dickherber, R. A1 - Errando, M. A1 - Falcone, A. A1 - Finley, J. P. A1 - Fortson, L. A1 - Furniss, A. A1 - Galante, N. A1 - Gall, D. A1 - Gillanders, G. H. A1 - Godambe, S. A1 - Griffin, S. A1 - Grube, J. A1 - Gyuk, G. A1 - Hanna, D. A1 - Holder, J. A1 - Huan, H. A1 - Hughes, G. A1 - Hui, C. M. A1 - Humensky, T. B. A1 - Kaaret, P. A1 - Karlsson, N. A1 - Kertzman, M. A1 - Kieda, D. A1 - Krawczynski, H. A1 - Krennrich, F. A1 - Madhavan, A. S. A1 - Maier, G. A1 - Majumdar, P. A1 - McArthur, S. A1 - McCann, A. A1 - Moriarty, P. A1 - Mukherjee, R. A1 - Ong, R. A. A1 - Orr, M. A1 - Otte, A. N. A1 - Park, N. A1 - Perkins, J. S. A1 - Pichel, A. A1 - Pohl, Martin A1 - Prokoph, H. A1 - Quinn, J. A1 - Ragan, K. A1 - Reyes, L. C. A1 - Reynolds, P. T. A1 - Roache, E. A1 - Rose, H. J. A1 - Ruppel, J. A1 - Saxon, D. B. A1 - Schroedter, M. A1 - Sembroski, G. H. A1 - Skole, C. A1 - Smith, A. W. A1 - Staszak, D. A1 - Tesic, G. A1 - Theiling, M. A1 - Thibadeau, S. A1 - Tsurusaki, K. A1 - Tyler, J. A1 - Varlotta, A. A1 - Vincent, S. A1 - Vivier, M. A1 - Wakely, S. P. A1 - Ward, J. E. A1 - Weinstein, A. A1 - Weisgarber, T. A1 - Williams, D. A. T1 - Veritas observations of unusual extragalactic transient swift J164449.3+573451 JF - The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters N2 - We report on very high energy (>100 GeV) gamma-ray observations of Swift J164449.3+573451, an unusual transient object first detected by the Swift Observatory and later detected by multiple radio, optical, and X-ray observatories. A total exposure of 28 hr was obtained on Swift J164449.3+573451 with the Very Energetic Radiation Imaging Telescope Array System ( VERITAS) during 2011 March 28-April 15. We do not detect the source and place a differential upper limit on the emission at 500 GeV during these observations of 1.4 x 10(-12) erg cm(-2) s(-1) (99% confidence level). We also present time-resolved upper limits and use a flux limit averaged over the X-ray flaring period to constrain various emission scenarios that can accommodate both the radio-through-X-ray emission detected from the source and the lack of detection by VERITAS. KW - accretion, accretion disks KW - galaxies: active KW - gamma rays: galaxies KW - radiation mechanisms: non-thermal Y1 - 2011 U6 - https://doi.org/10.1088/2041-8205/738/2/L30 SN - 2041-8205 VL - 738 IS - 2 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Aliu, E. A1 - Arlen, T. A1 - Aune, T. A1 - Beilicke, M. A1 - Benbow, W. A1 - Bouvier, A. A1 - Bradbury, S. M. A1 - Buckley, J. H. A1 - Bugaev, V. A1 - Byrum, K. A1 - Cannon, A. A1 - Cesarini, A. A1 - Christiansen, J. L. A1 - Ciupik, L. A1 - Collins-Hughes, E. A1 - Connolly, M. P. A1 - Cui, W. A1 - Dickherber, R. A1 - Duke, C. A1 - Errando, M. A1 - Falcone, A. A1 - Finley, J. P. A1 - Finnegan, G. A1 - Fortson, L. A1 - Furniss, A. A1 - Galante, N. A1 - Gall, D. A1 - Gibbs, K. A1 - Gillanders, G. H. A1 - Godambe, S. A1 - Griffin, S. A1 - Grube, J. A1 - Guenette, R. A1 - Gyuk, G. A1 - Hanna, D. A1 - Holder, J. A1 - Huan, H. A1 - Hughes, G. A1 - Hui, C. M. A1 - Humensky, T. B. A1 - Imran, A. A1 - Kaaret, P. A1 - Karlsson, N. A1 - Kertzman, M. A1 - Kieda, D. A1 - Krawczynski, H. A1 - Krennrich, F. A1 - Lang, M. J. A1 - Lyutikov, M. A1 - Madhavan, A. S. A1 - Maier, G. A1 - Majumdar, P. A1 - McArthur, S. A1 - McCann, A. A1 - McCutcheon, M. A1 - Moriarty, P. A1 - Mukherjee, R. A1 - Nunez, P. A1 - Ong, R. A. A1 - Orr, M. A1 - Otte, A. N. A1 - Park, N. A1 - Perkins, J. S. A1 - Pizlo, F. A1 - Pohl, Martin A1 - Prokoph, H. A1 - Quinn, J. A1 - Ragan, K. A1 - Reyes, L. C. A1 - Reynolds, P. T. A1 - Roache, E. A1 - Rose, H. J. A1 - Ruppel, J. A1 - Saxon, D. B. A1 - Schroedter, M. A1 - Sembroski, G. H. A1 - Sentuerk, G. D. A1 - Smith, A. W. A1 - Staszak, D. A1 - Tesic, G. A1 - Theiling, M. A1 - Thibadeau, S. A1 - Tsurusaki, K. A1 - Tyler, J. A1 - Varlotta, A. A1 - Vassiliev, V. V. A1 - Vincent, S. A1 - Vivier, M. A1 - Wakely, S. P. A1 - Ward, J. E. A1 - Weekes, T. C. A1 - Weinstein, A. A1 - Weisgarber, T. A1 - Williams, D. A. A1 - Zitzer, B. T1 - Detection of pulsed Gamma Rays Above 100 GeV from the Crab Pulsar JF - Science N2 - We report the detection of pulsed gamma rays from the Crab pulsar at energies above 100 giga-electron volts (GeV) with the Very Energetic Radiation Imaging Telescope Array System (VERITAS) array of atmospheric Cherenkov telescopes. The detection cannot be explained on the basis of current pulsar models. The photon spectrum of pulsed emission between 100 mega-electron volts and 400 GeV is described by a broken power law that is statistically preferred over a power law with an exponential cutoff. It is unlikely that the observation can be explained by invoking curvature radiation as the origin of the observed gamma rays above 100 GeV. Our findings require that these gamma rays be produced more than 10 stellar radii from the neutron star. Y1 - 2011 U6 - https://doi.org/10.1126/science.1208192 SN - 0036-8075 VL - 334 IS - 6052 SP - 69 EP - 72 PB - American Assoc. for the Advancement of Science CY - Washington ER - TY - JOUR A1 - Ackermann, Margit A1 - Ajello, M. A1 - Allafort, A. J. A1 - Baldini, L. A1 - Ballet, J. A1 - Barbiellini, G. A1 - Bastieri, D. A1 - Belfiore, A. A1 - Bellazzini, R. A1 - Berenji, B. A1 - Blandford, R. D. A1 - Bloom, E. D. A1 - Bonamente, E. A1 - Borgland, A. W. A1 - Bottacini, E. A1 - Brigida, M. A1 - Bruel, P. A1 - Buehler, R. A1 - Buson, S. A1 - Caliandro, G. A. A1 - Cameron, R. A. A1 - Caraveo, P. A. A1 - Casandjian, J. M. A1 - Cecchi, C. A1 - Chekhtman, A. A1 - Cheung, C. C. A1 - Chiang, J. A1 - Ciprini, S. A1 - Claus, R. A1 - Cohen-Tanugi, J. A1 - de Angelis, A. A1 - de Palma, F. A1 - Dermer, C. D. A1 - do Couto e Silva, E. A1 - Drell, P. S. A1 - Dumora, D. A1 - Favuzzi, C. A1 - Fegan, S. J. A1 - Focke, W. B. A1 - Fortin, P. A1 - Fukazawa, Y. A1 - Fusco, P. A1 - Gargano, F. A1 - Germani, S. A1 - Giglietto, N. A1 - Giordano, F. A1 - Giroletti, M. A1 - Glanzman, T. A1 - Godfrey, G. A1 - Grenier, I. A. A1 - Guillemot, L. A1 - Guiriec, S. A1 - Hadasch, D. A1 - Hanabata, Y. A1 - Harding, A. K. A1 - Hayashida, M. A1 - Hayashi, K. A1 - Hays, E. A1 - Johannesson, G. A1 - Johnson, A. S. A1 - Kamae, T. A1 - Katagiri, H. A1 - Kataoka, J. A1 - Kerr, M. A1 - Knoedlseder, J. A1 - Kuss, M. A1 - Lande, J. A1 - Latronico, L. A1 - Lee, S. -H. A1 - Longo, F. A1 - Loparco, F. A1 - Lott, B. A1 - Lovellette, M. N. A1 - Lubrano, P. A1 - Martin, P. A1 - Mazziotta, Mario Nicola A1 - McEnery, J. E. A1 - Mehault, J. A1 - Michelson, P. F. A1 - Mitthumsiri, W. A1 - Mizuno, T. A1 - Monte, C. A1 - Monzani, M. E. A1 - Morselli, A. A1 - Moskalenko, I. V. A1 - Murgia, S. A1 - Naumann-Godo, M. A1 - Nolan, P. L. A1 - Norris, J. P. A1 - Nuss, E. A1 - Ohsugi, T. A1 - Okumura, A. A1 - Orlando, E. A1 - Ormes, J. F. A1 - Ozaki, M. A1 - Paneque, D. A1 - Parent, D. A1 - Pesce-Rollins, M. A1 - Pierbattista, M. A1 - Piron, F. A1 - Pohl, Martin A1 - Prokhorov, D. A1 - Raino, S. A1 - Rando, R. A1 - Razzano, M. A1 - Reposeur, T. A1 - Ritz, S. A1 - Parkinson, P. M. Saz A1 - Sgro, C. A1 - Siskind, E. J. A1 - Smith, P. D. A1 - Spinelli, P. A1 - Strong, A. W. A1 - Takahashi, H. A1 - Tanaka, T. A1 - Thayer, J. G. A1 - Thayer, J. B. A1 - Thompson, D. J. A1 - Tibaldo, L. A1 - Torres, D. F. A1 - Tosti, G. A1 - Tramacere, A. A1 - Troja, E. A1 - Uchiyama, Y. A1 - Vandenbroucke, J. A1 - Vasileiou, V. A1 - Vianello, G. A1 - Vitale, V. A1 - Waite, A. P. A1 - Wang, P. A1 - Winer, B. L. A1 - Wood, K. S. A1 - Yang, Z. A1 - Zimmer, S. A1 - Bontemps, S. T1 - A cocoon of freshly accelerated cosmic rays detected by fermi in the cygnus superbubble JF - Science N2 - The origin of Galactic cosmic rays is a century-long puzzle. Indirect evidence points to their acceleration by supernova shockwaves, but we know little of their escape from the shock and their evolution through the turbulent medium surrounding massive stars. Gamma rays can probe their spreading through the ambient gas and radiation fields. The Fermi Large Area Telescope (LAT) has observed the star-forming region of Cygnus X. The 1- to 100-gigaelectronvolt images reveal a 50-parsec-wide cocoon of freshly accelerated cosmic rays that flood the cavities carved by the stellar winds and ionization fronts from young stellar clusters. It provides an example to study the youth of cosmic rays in a superbubble environment before they merge into the older Galactic population. Y1 - 2011 U6 - https://doi.org/10.1126/science.1210311 SN - 0036-8075 VL - 334 IS - 6059 SP - 1103 EP - 1107 PB - American Assoc. for the Advancement of Science CY - Washington ER - TY - JOUR A1 - Donges, Jonathan A1 - Donner, Reik Volker A1 - Trauth, Martin H. A1 - Marwan, Norbert A1 - Schellnhuber, Hans Joachim A1 - Kurths, Jürgen T1 - Nonlinear detection of paleoclimate-variability transitions possibly related to human evolution JF - Proceedings of the National Academy of Sciences of the United States of America N2 - Potential paleoclimatic driving mechanisms acting on human evolution present an open problem of cross-disciplinary scientific interest. The analysis of paleoclimate archives encoding the environmental variability in East Africa during the past 5 Ma has triggered an ongoing debate about possible candidate processes and evolutionary mechanisms. In this work, we apply a nonlinear statistical technique, recurrence network analysis, to three distinct marine records of terrigenous dust flux. Our method enables us to identify three epochs with transitions between qualitatively different types of environmental variability in North and East Africa during the (i) Middle Pliocene (3.35-3.15 Ma B. P.), (ii) Early Pleistocene (2.25-1.6 Ma B. P.), and (iii) Middle Pleistocene (1.1-0.7 Ma B. P.). A deeper examination of these transition periods reveals potential climatic drivers, including (i) large-scale changes in ocean currents due to a spatial shift of the Indonesian throughflow in combination with an intensification of Northern Hemisphere glaciation, (ii) a global reorganization of the atmospheric Walker circulation induced in the tropical Pacific and Indian Ocean, and (iii) shifts in the dominating temporal variability pattern of glacial activity during the Middle Pleistocene, respectively. A reexamination of the available fossil record demonstrates statistically significant coincidences between the detected transition periods and major steps in hominin evolution. This result suggests that the observed shifts between more regular and more erratic environmental variability may have acted as a trigger for rapid change in the development of humankind in Africa. KW - African climate KW - Plio-Pleistocene KW - climate-driven evolution KW - dynamical transitions KW - nonlinear time series analysis Y1 - 2011 U6 - https://doi.org/10.1073/pnas.1117052108 SN - 0027-8424 VL - 108 IS - 51 SP - 20422 EP - 20427 PB - National Acad. of Sciences CY - Washington ER - TY - JOUR A1 - Delahaye, T. A1 - Fiasson, A. A1 - Pohl, Martin A1 - Salati, P. T1 - The GeV-TeV Galactic gamma-ray diffuse emission I. Uncertainties in the predictions of the hadronic component JF - Astronomy and astrophysics : an international weekly journal N2 - Context. The Galactic gamma-ray diffuse emission is currently observed in the GeV-TeV energy range with unprecedented accuracy by the Fermi satellite. Understanding this component is crucial because it provides a background to many different signals, such as extragalactic sources or annihilating dark matter. It is timely to reinvestigate how it is calculated and to assess the various uncertainties that are likely to affect the accuracy of the predictions. Aims. The Galactic gamma-ray diffuse emission is mostly produced above a few GeV by the interactions of cosmic ray primaries impinging on the interstellar material. The theoretical error on that component is derived by exploring various potential sources of uncertainty. Particular attention is paid to cosmic ray propagation. Nuclear cross sections, the proton and helium fluxes at the Earth's position, the Galactic radial profile of supernova remnants, and the hydrogen distribution can also severely affect the signal. Methods. The propagation of cosmic ray species throughout the Galaxy is described in the framework of a semi-analytic two-zone diffusion/convection model. The gamma-ray flux is reliably and quickly determined. This allows conversion of the constraints set by the boron-to-carbon data into a theoretical uncertainty on the diffuse emission. New deconvolutions of the HI and CO sky maps are also used to get the hydrogen distribution within the Galaxy. Results. The thickness of the cosmic ray diffusive halo is found to have a significant effect on the Galactic gamma-ray diffuse emission, while the interplay between diffusion and convection has little influence on the signal. The uncertainties related to nuclear cross sections and to the primary cosmic ray fluxes at the Earth are significant. The radial distribution of supernova remnants along the Galactic plane turns out to be a key ingredient. As expected, the predictions are extremely sensitive to the spatial distribution of hydrogen within the Milky Way. Conclusions. Most of the sources of uncertainty are likely to be reduced in the near future. The stress should be put (i) on better determination of the thickness of the cosmic ray diffusive halo; and (ii) on refined observations of the radial profile of supernova remnants. KW - gamma rays: diffuse background KW - cosmic rays KW - methods: analytical KW - gamma rays: ISM Y1 - 2011 U6 - https://doi.org/10.1051/0004-6361/201116647 SN - 0004-6361 VL - 531 IS - 4 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Blakesley, James C. A1 - Schubert, Marcel A1 - Steyrleuthner, Robert A1 - Chen, Zhihua A1 - Facchetti, Antonio A1 - Neher, Dieter T1 - Time-of-flight measurements and vertical transport in a high electron-mobility polymer JF - Applied physics letters N2 - We investigate charge transport in a high-electron mobility polymer, poly(N, N-bis 2-octyldodecyl-naphthalene-1,4,5,8-bis dicarboximide-2,6-diyl-alt-5,5-2,2-bithiophene) [P(NDI2OD-T2), Polyera ActivInk (TM) N2200]. Time-of-flight measurements reveal electron mobilities approaching those measured in field-effect transistors, the highest ever recorded in a conjugated polymer using this technique. The modest temperature dependence and weak dispersion of the transients indicate low energetic disorder in this material. Steady-state electron-only current measurements reveal a barrier to injection of about 300 meV. We propose that this barrier is located within the P(NDI2OD-T2) film and arises from molecular orientation effects. Y1 - 2011 U6 - https://doi.org/10.1063/1.3657827 SN - 0003-6951 VL - 99 IS - 18 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Turner, Sarah T. A1 - Pingel, Patrick A1 - Steyrleuthner, Robert A1 - Crossland, Edward J. W. A1 - Ludwigs, Sabine A1 - Neher, Dieter T1 - Quantitative analysis of bulk heterojunction films using linear absorption spectroscopy and solar cell performance JF - Advanced functional materials N2 - A fundamental understanding of the relationship between the bulk morphology and device performance is required for the further development of bulk heterojunction organic solar cells. Here, non-optimized (chloroform cast) and nearly optimized (solvent-annealed o-dichlorobenzene cast) P3HT:PCBM blend films treated over a range of annealing temperatures are studied via optical and photovoltaic device measurements. Parameters related to the P3HT aggregate morphology in the blend are obtained through a recently established analytical model developed by F. C. Spano for the absorption of weakly interacting H-aggregates. Thermally induced changes are related to the glass transition range of the blend. In the chloroform prepared devices, the improvement in device efficiency upon annealing within the glass transition range can be attributed to the growth of P3HT aggregates, an overall increase in the percentage of chain crystallinity, and a concurrent increase in the hole mobilities. Films treated above the glass transition range show an increase in efficiency and fill factor not only associated with the change in chain crystallinity, but also with a decrease in the energetic disorder. On the other hand, the properties of the P3HT phase in the solvent-annealed o-dichlorobenzene cast blends are almost indistinguishable from those of the corresponding pristine P3HT layer and are only weakly affected by thermal annealing. Apparently, slow drying of the blend allows the P3HT chains to crystallize into large domains with low degrees of intra- and interchain disorder. This morphology appears to be most favorable for the efficient generation and extraction of charges. KW - Organic electronics KW - morphology KW - solar cells KW - mobility KW - absorption spectroscopy Y1 - 2011 U6 - https://doi.org/10.1002/adfm.201101583 SN - 1616-301X VL - 21 IS - 24 SP - 4640 EP - 4652 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Rivnay, Jonathan A1 - Steyrleuthner, Robert A1 - Jimison, Leslie H. A1 - Casadei, Alberto A1 - Chen, Zhihua A1 - Toney, Michael F. A1 - Facchetti, Antonio A1 - Neher, Dieter A1 - Salleo, Alberto T1 - Drastic control of texture in a high performance n-Type polymeric semiconductor and implications for charge transport JF - Macromolecules : a publication of the American Chemical Society N2 - Control of crystallographic texture from mostly face-on to edge-on is observed for the film morphology of the n-type semicrystalline polymer [N,N-9-bis(2-octyldodecyl)naphthalene-1,4,5,8-bis(dicarboximide)-2,6-diy1]alt-5,59-(2,29-bithiophene)}, P(NDI2OD-T2), when annealing the film to the polymer melting point followed by slow cooling to ambient temperature. A variety of X-ray diffraction analyses, including pole figure construction and Fourier transform peak shape deconvolution, are employed to quantify the texture change, relative degree of crystallinity and lattice order. We find that annealing the polymer film to the melt leads to a shift from 77.5% face-on to 94.6% edge-on lamellar texture as well as to a 2-fold increase in crystallinity and a 40% decrease in intracrystallite cumulative disorder. The texture change results in a significant drop in the electron-only diode current density through the film thickness upon melt annealing while little change is observed in the in-plane transport of bottom gated thin film transistors. This suggests that the texture change is prevalent in the film interior and that either the (bottom) surface structure is different from the interior structure or the intracrystalline order and texture play a secondary role in transistor transport for this material. Y1 - 2011 U6 - https://doi.org/10.1021/ma200864s SN - 0024-9297 VL - 44 IS - 13 SP - 5246 EP - 5255 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Ilnytskyi, Jaroslav M. A1 - Neher, Dieter A1 - Saphiannikova, Marina T1 - Opposite photo-induced deformations in azobenzene-containing polymers with different molecular architecture molecular dynamics study JF - The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr N2 - Photo-induced deformations in azobenzene-containing polymers (azo-polymers) are central to a number of applications, such as optical storage and fabrication of diffractive elements. The microscopic nature of the underlying opto-mechanical coupling is yet not clear. In this study, we address the experimental finding that the scenario of the effects depends on molecular architecture of the used azo-polymer. Typically, opposite deformations in respect to the direction of light polarization are observed for liquid crystalline and amorphous azo-polymers. In this study, we undertake molecular dynamics simulations of two different models that mimic these two types of azo-polymers. We employ hybrid force field modeling and consider only trans-isomers of azobenzene, represented as Gay-Berne sites. The effect of illumination on the orientation of the chromophores is considered on the level of orientational hole burning and emphasis is given to the resulting deformation of the polymer matrix. We reproduce deformations of opposite sign for the two models being considered here and discuss the relevant microscopic mechanisms in both cases. KW - amorphous state KW - light polarisation KW - liquid crystal polymers KW - molecular dynamics method KW - optical hole burning KW - photochemistry Y1 - 2011 U6 - https://doi.org/10.1063/1.3614499 SN - 0021-9606 VL - 135 IS - 4 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Kniepert, Juliane A1 - Schubert, Marcel A1 - Blakesley, James C. A1 - Neher, Dieter T1 - Photogeneration and recombination in P3HT/PCBM solar cells probed by time-delayed collection field experiments JF - The journal of physical chemistry letters N2 - Time-delayed collection field (TDCF) experiments are performed on bulk heterojunction solar cells comprised of a blend of poly(3-hexylthiophene) and [6,6]-phenyl C-71 butyric acid methyl ester. TDCF is analogous to a pump-probe experiment using optical excitation and an electrical probe with a resolution of < 100 ns. The number of free charge carriers extracted after a short delay is found to be independent of the electric field during illumination. Also, experiments performed with a variable delay between the optical excitation and the electrical probe do not reveal any evidence for the generation of charge via field-assisted dissociation of bound long-lived polaron pairs. Photocurrent transients are well fitted by computational drift diffusion simulations with only direct generation of free charge carriers. With increasing delay times between pump and probe, two loss mechanisms are identified; first, charge-carriers are swept out of the device by the internal electric field, and second, bimolecular recombination of the remaining carriers takes place with a reduced recombination coefficient. Y1 - 2011 U6 - https://doi.org/10.1021/jz200155b SN - 1948-7185 VL - 2 IS - 7 SP - 700 EP - 705 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Kuehn, Sergei A1 - Pingel, Patrick A1 - Breusing, Markus A1 - Fischer, Thomas A1 - Stumpe, Joachim A1 - Neher, Dieter A1 - Elsaesser, Thomas T1 - High-Resolution Near-Field Optical Investigation of Crystalline Domains in Oligomeric PQT-12 Thin Films JF - Advanced functional materials N2 - The structure and morphology on different length scales dictate both the electrical and optical properties of organic semiconductor thin films. Using a combination of spectroscopic methods, including scanning near-field optical microscopy, we study the domain structure and packing quality of highly crystalline thin films of oligomeric PQT-12 with 100 nanometer spatial resolution. The pronounced optical anisotropy of these layers measured by polarized light microscopy facilitates the identification of regions with uniform molecular orientation. We find that a hierarchical order on three different length scales exists in these layers, made up of distinct well-ordered dichroic areas at the ten-micrometer-scale, which are sub-divided into domains with different molecular in-plane orientation. These serve as a template for the formation of smaller needle-like crystallites at the layer surface. A high degree of crystalline order is believed to be the cause of the rather high field-effect mobility of these layers of 10(-3) cm 2 V(-1) s(-1), whereas it is limited by the presence of domain boundaries at macroscopic distances. Y1 - 2011 U6 - https://doi.org/10.1002/adfm.201001978 SN - 1616-301X VL - 21 IS - 5 SP - 860 EP - 868 PB - Wiley-Blackwell CY - Malden ER - TY - JOUR A1 - Blakesley, James C. A1 - Neher, Dieter T1 - Relationship between energetic disorder and open-circuit voltage in bulk heterojunction organic solar cells JF - Physical review : B, Condensed matter and materials physics N2 - We simulate organic bulk heterojunction solar cells. The effects of energetic disorder are incorporated through a Gaussian or exponential model of density of states. Analytical models of open-circuit voltage (V(OC)) are derived from the splitting of quasi-Fermi potentials. Their predictions are backed up by more complex numerical device simulations including effects such as carrier-density-dependent charge-carrier mobilities. It is predicted that the V(OC) depends on: (1) the donor-acceptor energy gap; (2) charge-carrier recombination rates; (3) illumination intensity; (4) the contact work functions (if not in the pinning regime); and (5) the amount of energetic disorder. A large degree of energetic disorder, or a high density of traps, is found to cause significant reductions in V(OC). This can explain why V(OC) is often less than expected in real devices. Energetic disorder also explains the nonideal temperature and intensity dependence of V(OC) and the superbimolecular recombination rates observed in many real bulk heterojunction solar cells. Y1 - 2011 U6 - https://doi.org/10.1103/PhysRevB.84.075210 SN - 1098-0121 VL - 84 IS - 7 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Lange, Ilja A1 - Blakesley, James C. A1 - Frisch, Johannes A1 - Vollmer, Antje A1 - Koch, Norbert A1 - Neher, Dieter T1 - Band bending in conjugated polymer layers JF - Physical review letters N2 - We use the Kelvin probe method to study the energy-level alignment of four conjugated polymers deposited on various electrodes. Band bending is observed in all polymers when the substrate work function exceeds critical values. Through modeling, we show that the band bending is explained by charge transfer from the electrodes into a small density of states that extends several hundred meV into the band gap. The energetic spread of these states is correlated with charge-carrier mobilities, suggesting that the same states also govern charge transport in the bulk of these polymers. Y1 - 2011 U6 - https://doi.org/10.1103/PhysRevLett.106.216402 SN - 0031-9007 VL - 106 IS - 21 PB - American Physical Society CY - College Park ER - TY - JOUR A1 - Hundertmark, Michaela A1 - Dimova, Rumiana A1 - Lengefeld, Jan A1 - Seckler, Robert A1 - Hincha, Dirk K. T1 - The intrinsically disordered late embryogenesis abundant protein LEA18 from Arabidopsis thaliana modulates membrane stability through binding and folding JF - Biochimica et biophysica acta : Biomembranes N2 - Intrinsically disordered proteins (IDPs) constitute a substantial part of cellular proteomes. late embryogenesis abundant (LEA) proteins are mostly predicted to be IDPs associated with dehydration tolerance in many plant, animal and bacterial species. Their functions, however, are largely unexplored and also their structure and interactions with potential target molecules have only recently been experimentally investigated in a small number of proteins. Here, we report on the structure and interactions with membranes of the Pfam LEA_1 protein LEA18 from the higher plant Arabidopsis thaliana. This functionally uncharacterized positively charged protein specifically aggregated and destabilized negatively charged liposomes. Isothermal titration calorimetry showed binding of the protein to both charged and uncharged membranes. LEA18 alone was largely unstructured in solution. While uncharged membranes had no influence on the secondary structure of LEA18, the protein partially folded into beta-sheet structure in the presence of negatively charged liposomes. These data suggest that LEA18 does not function as a membrane stabilizing protein, as suggested for other LEA proteins. Instead, a possible function of LEA18 could be the composition-dependent modulation of membrane stability, e.g., during signaling or vesicle-mediated transport. KW - Intrinsically disordered protein KW - Late embryogenesis abundant protein KW - Membrane stability KW - Protein-membrane interaction KW - Protein folding Y1 - 2011 U6 - https://doi.org/10.1016/j.bbamem.2010.09.010 SN - 0005-2736 VL - 1808 IS - 1 SP - 446 EP - 453 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Eichler, David A1 - Pohl, Martin T1 - Can ultrahigh-energy cosmic rays come from Gamma-ray bursts? - cosmic rays below the ankle and galactic gamma-ray bursts JF - The astrophysical journal : an international review of spectroscopy and astronomical physics ; Part 2, Letters N2 - The maximum cosmic-ray energy achievable by acceleration by a relativistic blast wave is derived. It is shown that forward shocks from long gamma-ray bursts (GRBs) in the interstellar medium accelerate protons to large enough energies, and have a sufficient energy budget, to produce the Galactic cosmic-ray component just below the ankle at 4 x 10(18) eV, as per an earlier suggestion. It is further argued that, were extragalactic long GRBs responsible for the component above the ankle as well, the occasional Galactic GRB within the solar circle would contribute more than the observational limits on the outward flux from the solar circle, unless an avoidance scenario, such as intermittency and/or beaming, allows the present-day local flux to be less than 10(-3) of the average. Difficulties with these avoidance scenarios are noted. KW - cosmic rays KW - galaxies: general KW - gamma-ray burst: general Y1 - 2011 U6 - https://doi.org/10.1088/2041-8205/738/2/L21 SN - 2041-8205 VL - 738 IS - 2 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Mizuno, Yosuke A1 - Pohl, Martin A1 - Niemiec, Jacek A1 - Zhang, Bing A1 - Nishikawa, Ken-Ichi A1 - Hardee, Philip E. T1 - Magnetic-field amplification by turbulence in a relativistic shockpropagating through an inhomogeneous medium JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - We perform two-dimensional relativistic magnetohydrodynamic simulations of a mildly relativistic shock propagating through an inhomogeneous medium. We show that the postshock region becomes turbulent owing to preshock density inhomogeneity, and the magnetic field is strongly amplified due to the stretching and folding of field lines in the turbulent velocity field. The amplified magnetic field evolves into a filamentary structure in two-dimensional simulations. The magnetic energy spectrum is flatter than the Kolmogorov spectrum and indicates that a so-called small-scale dynamo is occurring in the postshock region. We also find that the amount of magnetic-field amplification depends on the direction of the mean preshock magnetic field, and the timescale of magnetic-field growth depends on the shock strength. KW - gamma-ray burst: general KW - magnetohydrodynamics (MHD) KW - methods: numerical KW - relativistic processes KW - shock waves KW - turbulence Y1 - 2011 U6 - https://doi.org/10.1088/0004-637X/726/2/62 SN - 0004-637X VL - 726 IS - 2 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Pohl, Martin A1 - Eichler, David T1 - Origin of ultra-high-energy galactic cosmic rays the isotropy problem JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - We study the propagation of ultra-high-energy cosmic rays (UHECRs) in the Galaxy, concentrating on the energy range below the ankle in the spectrum at 4 EeV. A Monte Carlo method, based on analytical solutions to the time-dependent diffusion problem, is used to account for intermittency by placing sources at random locations. Assuming a source population that scales with baryon mass density or star formation (e.g., long GRB), we derive constraints arising from intermittency and the observational limits on the composition and anisotropy. It is shown that the composition and anisotropy at 10(18) eV are difficult to reproduce and require that either (1) the particle mean free path is much smaller than a gyroradius, implying the escape time is very long, (2) the composition is heavier than suggested by recent Auger data, (3) the ultra-high-energy sub-ankle component is mostly extragalactic, or (4) we are living in a rare lull in the UHECR production, and the current UHECR intensity is far below the Galactic time average. We therefore recommend a strong observational focus on determining the UHECR composition around 10(18) eV. KW - cosmic rays KW - gamma-ray burst: general Y1 - 2011 U6 - https://doi.org/10.1088/0004-637X/742/2/114 SN - 0004-637X VL - 742 IS - 2 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Abdo, A. A. A1 - Ackermann, Margit A1 - Ajello, M. A1 - Allafort, A. J. A1 - Baldini, L. A1 - Ballet, J. A1 - Barbiellini, G. A1 - Baring, M. G. A1 - Bastieri, D. A1 - Bellazzini, R. A1 - Berenji, B. A1 - Blandford, R. D. A1 - Bloom, E. D. A1 - Bonamente, E. A1 - Borgland, A. W. A1 - Bouvier, A. A1 - Brandt, T. J. A1 - Bregeon, Johan A1 - Brigida, M. A1 - Bruel, P. A1 - Buehler, R. A1 - Buson, S. A1 - Caliandro, G. A. A1 - Cameron, R. A. A1 - Caraveo, P. A. A1 - Casandjian, J. M. A1 - Cecchi, C. A1 - Chaty, S. A1 - Chekhtman, A. A1 - Cheung, C. C. A1 - Chiang, J. A1 - Cillis, A. N. A1 - Ciprini, S. A1 - Claus, R. A1 - Cohen-Tanugi, J. A1 - Conrad, Jan A1 - Corbel, S. A1 - Cutini, S. A1 - de Angelis, A. A1 - de Palma, F. A1 - Dermer, C. D. A1 - Digel, S. W. A1 - do Couto e Silva, E. A1 - Drell, P. S. A1 - Drlica-Wagner, A. A1 - Dubois, R. A1 - Dumora, D. A1 - Favuzzi, C. A1 - Ferrara, E. C. A1 - Fortin, P. A1 - Frailis, M. A1 - Fukazawa, Y. A1 - Fukui, Y. A1 - Funk, S. A1 - Fusco, P. A1 - Gargano, F. A1 - Gasparrini, D. A1 - Gehrels, N. A1 - Germani, S. A1 - Giglietto, N. A1 - Giordano, F. A1 - Giroletti, M. A1 - Glanzman, T. A1 - Godfrey, G. A1 - Grenier, I. A. A1 - Grondin, M. -H. A1 - Guiriec, S. A1 - Hadasch, D. A1 - Hanabata, Y. A1 - Harding, A. K. A1 - Hayashida, M. A1 - Hayashi, K. A1 - Hays, E. A1 - Horan, D. A1 - Jackson, M. S. A1 - Johannesson, G. A1 - Johnson, A. S. A1 - Kamae, T. A1 - Katagiri, H. A1 - Kataoka, J. A1 - Kerr, M. A1 - Knoedlseder, J. A1 - Kuss, M. A1 - Lande, J. A1 - Latronico, L. A1 - Lee, S. -H. A1 - Lemoine-Goumard, M. A1 - Longo, F. A1 - Loparco, F. A1 - Lovellette, M. N. A1 - Lubrano, P. A1 - Madejski, G. M. A1 - Makeev, A. A1 - Mazziotta, Mario Nicola A1 - McEnery, J. E. A1 - Michelson, P. F. A1 - Mignani, R. P. A1 - Mitthumsiri, W. A1 - Mizuno, T. A1 - Moiseev, A. A. A1 - Monte, C. A1 - Monzani, M. E. A1 - Morselli, A. A1 - Moskalenko, I. V. A1 - Murgia, S. A1 - Naumann-Godo, M. A1 - Nolan, P. L. A1 - Norris, J. P. A1 - Nuss, E. A1 - Ohsugi, T. A1 - Okumura, A. A1 - Orlando, E. A1 - Ormes, J. F. A1 - Paneque, D. A1 - Parent, D. A1 - Pelassa, V. A1 - Pesce-Rollins, M. A1 - Pierbattista, M. A1 - Piron, F. A1 - Pohl, Martin A1 - Porter, T. A. A1 - Raino, S. A1 - Rando, R. A1 - Razzano, M. A1 - Reimer, O. A1 - Reposeur, T. A1 - Ritz, S. A1 - Romani, R. W. A1 - Roth, M. A1 - Sadrozinski, H. F. -W. A1 - Parkinson, P. M. Saz A1 - Sgro, C. A1 - Smith, D. A. A1 - Smith, P. D. A1 - Spandre, G. A1 - Spinelli, P. A1 - Strickman, M. S. A1 - Tajima, H. A1 - Takahashi, H. A1 - Takahashi, T. A1 - Tanaka, T. A1 - Thayer, J. G. A1 - Thayer, J. B. A1 - Thompson, D. J. A1 - Tibaldo, L. A1 - Tibolla, O. A1 - Torres, D. F. A1 - Tosti, G. A1 - Tramacere, A. A1 - Troja, E. A1 - Uchiyama, Y. A1 - Vandenbroucke, J. A1 - Vasileiou, V. A1 - Vianello, G. A1 - Vilchez, N. A1 - Vitale, V. A1 - Waite, A. P. A1 - Wang, P. A1 - Winer, B. L. A1 - Wood, K. S. A1 - Yamamoto, H. A1 - Yamazaki, R. A1 - Yang, Z. A1 - Ziegler, M. T1 - Observations of the young supernova remnant RX J1713.7-3946 with the fermi large area telescope JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - We present observations of the young supernova remnant (SNR) RX J1713.7-3946 with the Fermi Large Area Telescope (LAT). We clearly detect a source positionally coincident with the SNR. The source is extended with a best-fit extension of 0 degrees.55 +/- 0 degrees.04 matching the size of the non-thermal X-ray and TeV gamma-ray emission from the remnant. The positional coincidence and the matching extended emission allow us to identify the LAT source with SNR RX J1713.7-3946. The spectrum of the source can be described by a very hard power law with a photon index of Gamma = 1.5 +/- 0.1 that coincides in normalization with the steeper H. E. S. S.-detected gamma-ray spectrum at higher energies. The broadband gamma-ray emission is consistent with a leptonic origin as the dominant mechanism for the gamma-ray emission. KW - acceleration of particles KW - gamma rays: general KW - gamma rays: ISM KW - ISM: individual objects (RX J1713.7-3946) KW - ISM: supernova remnants KW - radiation mechanisms: non-thermal Y1 - 2011 U6 - https://doi.org/10.1088/0004-637X/734/1/28 SN - 0004-637X VL - 734 IS - 1 PB - IOP Publ. Ltd. CY - Bristol ER - TY - JOUR A1 - Acciari, V. A. A1 - Aliu, E. A1 - Arlen, T. A1 - Aune, T. A1 - Beilicke, M. A1 - Benbow, W. A1 - Bradbury, S. M. A1 - Buckley, J. H. A1 - Bugaev, V. A1 - Byrum, K. A1 - Cannon, A. A1 - Cesarini, A. A1 - Ciupik, L. A1 - Collins-Hughes, E. A1 - Connolly, M. P. A1 - Cui, W. A1 - Dickherber, R. A1 - Duke, C. A1 - Errando, M. A1 - Falcone, A. A1 - Finley, J. P. A1 - Finnegan, G. A1 - Fortson, L. A1 - Furniss, A. A1 - Galante, N. A1 - Gall, D. A1 - Gillanders, G. H. A1 - Godambe, S. A1 - Griffin, S. A1 - Grube, J. A1 - Guenette, R. A1 - Gyuk, G. A1 - Hanna, D. A1 - Holder, J. A1 - Hughes, G. A1 - Hui, C. M. A1 - Humensky, T. B. A1 - Kaaret, P. A1 - Karlsson, N. A1 - Kertzman, M. A1 - Kieda, D. A1 - Krawczynski, H. A1 - Krennrich, F. A1 - Lang, M. J. A1 - LeBohec, S. A1 - Maier, G. A1 - Majumdar, P. A1 - McArthur, S. A1 - McCann, A. A1 - Moriarty, P. A1 - Mukherjee, R. A1 - Ong, R. A. A1 - Orr, M. A1 - Otte, A. N. A1 - Park, N. A1 - Perkins, J. S. A1 - Pohl, Martin A1 - Prokoph, H. A1 - Quinn, J. A1 - Ragan, K. A1 - Reyes, L. C. A1 - Reynolds, P. T. A1 - Roache, E. A1 - Rose, H. J. A1 - Ruppel, J. A1 - Saxon, D. B. A1 - Schroedter, M. A1 - Sembroski, G. H. A1 - Senturk, G. D. A1 - Smith, A. W. A1 - Staszak, D. A1 - Tesic, G. A1 - Theiling, M. A1 - Thibadeau, S. A1 - Tsurusaki, K. A1 - Varlotta, A. A1 - Vassiliev, V. V. A1 - Vincent, S. A1 - Vivier, M. A1 - Wakely, S. P. A1 - Ward, J. E. A1 - Weekes, T. C. A1 - Weinstein, A. A1 - Weisgarber, T. A1 - Williams, D. A. A1 - Zitzer, B. T1 - VERITAS OBSERVATIONS OF THE TeV BINARY LS I+61 degrees 303 DURING 2008-2010 JF - The astrophysical journal : an international review of spectroscopy and astronomical physics N2 - We present the results of observations of the TeV binary LS I + 61 degrees 303 with the VERITAS telescope array between 2008 and 2010, at energies above 300 GeV. In the past, both ground-based gamma-ray telescopes VERITAS and MAGIC have reported detections of TeV emission near the apastron phases of the binary orbit. The observations presented here show no strong evidence for TeV emission during these orbital phases; however, during observations taken in late 2010, significant emission was detected from the source close to the phase of superior conjunction (much closer to periastron passage) at a 5.6 standard deviation (5.6 sigma) post-trials significance. In total, between 2008 October and 2010 December a total exposure of 64.5 hr was accumulated with VERITAS on LS I + 61 degrees 303, resulting in an excess at the 3.3 sigma significance level for constant emission over the entire integrated data set. The flux upper limits derived for emission during the previously reliably active TeV phases (i.e., close to apastron) are less than 5% of the Crab Nebula flux in the same energy range. This result stands in apparent contrast to previous observations by both MAGIC and VERITAS which detected the source during these phases at 10% of the Crab Nebula flux. During the two year span of observations, a large amount of X-ray data were also accrued on LS I + 61 degrees 303 by the Swift X-ray Telescope and the Rossi X-ray Timing Explorer Proportional Counter Array. We find no evidence for a correlation between emission in the X-ray and TeV regimes during 20 directly overlapping observations. We also comment on data obtained contemporaneously by the Fermi Large Area Telescope. KW - binaries: general KW - gamma rays: general KW - X-rays: binaries Y1 - 2011 U6 - https://doi.org/10.1088/0004-637X/738/1/3 SN - 0004-637X VL - 738 IS - 1 PB - IOP Publ. Ltd. CY - Bristol ER -