TY - THES A1 - Liepertz, Sven Christian T1 - Zusammenhang zwischen dem Professionswissen von Physiklehrkräften, dem sachstrukturellen Angebot des Unterrichts und der Schülerleistung T2 - Studien zum Physik- und Chemielernen ; 224 Y1 - 2017 SN - 978-3-8325-4480-5 PB - Logos CY - Berlin ER - TY - JOUR A1 - Sanjurjo-Ferrrin, G. A1 - Torrejon, J. M. A1 - Postnov, K. A1 - Oskinova, Lida A1 - Rodes-Roca, J. J. A1 - Bernabeu, Guillermo T1 - XMM-Newton spectroscopy of the accreting magnetar candidate 4U0114+65 JF - Astronomy and astrophysics : an international weekly journal N2 - Methods. We analysed the energy-resolved light curve and the time-resolved X-ray spectra provided by the EPIC cameras on board XMM-Newton. We also analysed the first high-resolution spectrum of this source provided by the Reflection Grating Spectrometer. Results. An X-ray pulse of 9350 +/- 160 s was measured. Comparison with previous measurements confirms the secular spin up of this source. We successfully fit the pulse-phase-resolved spectra with Comptonisation models. These models imply a very small (r similar to 3 km) and hot (kT similar to 2-3 keV) emitting region and therefore point to a hot spot over the neutron star (NS) surface as the most reliable explanation for the X-ray pulse. The long NS spin period, the spin-up rate, and persistent X-ray emission can be explained within the theory of quasi-spherical settling accretion, which may indicate that the magnetic field is in the magnetar range. Thus, 4U0114+65 could be a wind-accreting magnetar. We also observed two episodes of low luminosity. The first was only observed in the low-energy light curve and can be explained as an absorption by a large over-dense structure in the wind of the B1 supergiant donor. The second episode, which was deeper and affected all energies, may be due to temporal cessation of accretion onto one magnetic pole caused by non-spherical matter capture from the structured stellar wind. The light curve displays two types of dips that are clearly seen during the high-flux intervals. The short dips, with durations of tens of seconds, are produced through absorption by wind clumps. The long dips, in turn, seem to be associated with the rarefied interclump medium. From the analysis of the X-ray spectra, we found evidence of emission lines in the X-ray photoionised wind of the B1Ia donor. The Fe K alpha line was found to be highly variable and much weaker than in other X-ray binaries with supergiant donors. The degree of wind clumping, measured through the covering fraction, was found to be much lower than in supergiant donor stars with earlier spectral types. Conclusions. The XMM-Newton spectroscopy provided further support for the magnetar nature of the neutron star in 4U0114+65. The light curve presents dips that can be associated with clumps and the interclump medium in the stellar wind of the mass donor. KW - X-rays: binaries KW - stars: winds, outflows KW - pulsars: individual: 4U0114+65 Y1 - 2017 U6 - https://doi.org/10.1051/0004-6361/201630119 SN - 1432-0746 VL - 606 SP - 4039 EP - 4042 PB - EDP Sciences CY - Les Ulis ER - TY - JOUR A1 - Miedema, P. S. A1 - Mitzner, Rolf A1 - Ganschow, S. A1 - Föhlisch, Alexander A1 - Beye, Martin T1 - X-ray spectroscopy on the active ion in laser crystals JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - The active ions in typical laser crystals were studied with Resonant Inelastic X-ray Scattering (RIXS) and Partial Fluorescence Yield X-ray Absorption (PFY-XAS) spectroscopies as solid state model systems for dilute active centers. We analyzed Ti3+ and Cr3+ in alpha-Al2O3:Ti3+ and LiCaAlF6:Cr3+, respectively. The comparison of experimental data with semi-empirical multiplet calculations provides insights into the electronic structure and shows how measured crystal field energies are related across different spectroscopies. Y1 - 2017 U6 - https://doi.org/10.1039/c7cp03026f SN - 1463-9076 SN - 1463-9084 VL - 19 SP - 21800 EP - 21806 PB - Royal Society of Chemistry CY - Cambridge ER - TY - JOUR A1 - De Becker, M. A1 - del Valle, Maria Victoria A1 - Romero, G. E. A1 - Peri, C. S. A1 - Benaglia, P. T1 - X- ray study of bow shocks in runaway stars JF - Monthly notices of the Royal Astronomical Society N2 - Massive runaway stars produce bow shocks through the interaction of their winds with the interstellar medium, with the prospect for particle acceleration by the shocks. These objects are consequently candidates for non-thermal emission. Our aim is to investigate the X-ray emission from these sources. We observed with XMM-Newton a sample of five bow shock runaways, which constitutes a significant improvement of the sample of bow shock runaways studied in X-rays so far. A careful analysis of the data did not reveal any X-ray emission related to the bow shocks. However, X-ray emission from the stars is detected, in agreement with the expected thermal emission from stellar winds. On the basis of background measurements we derive conservative upper limits between 0.3 and 10 keV on the bow shocks emission. Using a simple radiation model, these limits together with radio upper limits allow us to constrain some of the main physical quantities involved in the non-thermal emission processes, such as the magnetic field strength and the amount of incident infrared photons. The reasons likely responsible for the non-detection of non-thermal radiation are discussed. Finally, using energy budget arguments, we investigate the detectability of inverse Compton X-rays in a more extended sample of catalogued runaway star bow shocks. From our analysis we conclude that a clear identification of non-thermal X-rays from massive runaway bow shocks requires one order of magnitude (or higher) sensitivity improvement with respect to present observatories. KW - acceleration of particles KW - radiation mechanisms: non-thermal KW - stars: earlytype KW - X-rays: stars Y1 - 2017 U6 - https://doi.org/10.1093/mnras/stx1826 SN - 0035-8711 SN - 1365-2966 VL - 471 SP - 4452 EP - 4464 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Munoz, Melissa A1 - Moffat, Anthony F. J. A1 - Hill, Grant M. A1 - Shenar, Tomer A1 - Richardson, Noel D. A1 - Pablo, Herbert A1 - St-Louis, Nicole A1 - Ramiaramanantsoa, Tahina T1 - WR 148: identifying the companion of an extreme runaway massive binary JF - Monthly notices of the Royal Astronomical Society N2 - WR 148 (HD 197406) is an extreme runaway system considered to be a potential candidate for a short-period (4.3173 d) rare WR + compact object binary. Provided with new high-resolution, high signal-to-noise spectra from the Keck observatory, we determine the orbital parameters for both the primary WR and the secondary, yielding respective projected orbital velocity amplitudes of 88.1 ± 3.8 km s−1 and 79.2 ± 3.1 km s−1 and implying a mass ratio of 1.1 ± 0.1. We then apply the shift-and-add technique to disentangle the spectra and obtain spectra compatible with a WN7ha and an O4-6 star. Considering an orbital inclination of ∼67°, derived from previous polarimetry observations, the system's total mass would be a mere 2–3M⊙⁠, an unprecedented result for a putative massive binary system. However, a system comprising a 37M⊙ secondary (typical mass of an O5V star) and a 33M⊙ primary (given the mass ratio) would infer an inclination of ∼18°. We therefore reconsider the previous methods of deriving the orbital inclination based on time-dependent polarimetry and photometry. While the polarimetric results are inconclusive requiring better data, the photometric results favour low inclinations. Finally, we compute WR 148’s space velocity and retrace the runaway's trajectory back to the Galactic plane (GP). With an ejection velocity of 198 ± 27 km s−1 and a travel time of 4.7 ± 0.8 Myr to reach its current location, WR 148 was most likely ejected via dynamical interactions in a young cluster. KW - binaries: spectroscopic KW - stars: individual: WR 148 KW - stars: kinematics and dynamics KW - stars: mass-loss KW - stars: winds, outflows KW - stars: Wolf-Rayet Y1 - 2017 U6 - https://doi.org/10.1093/mnras/stw2283 SN - 0035-8711 SN - 1365-2966 VL - 467 SP - 3105 EP - 3121 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Leussu, R. A1 - Usoskin, IIlya G. A1 - Valliappan, Senthamizh Pavai A1 - Diercke, Andrea A1 - Arlt, Rainer A1 - Denker, Carsten A1 - Mursula, K. T1 - Wings of the butterfly BT - sunspot groups for 1826-2015 JF - Astronomy and astrophysics : an international weekly journal N2 - The spatio-temporal evolution of sunspot activity, the so-called Maunder butterfly diagram, has been continously available since 1874 using data from the Royal Greenwich Observatory, extended by SOON network data after 1976. Here we present a new extended butterfly diagram of sunspot group occurrence since 1826, using the recently digitized data from Schwabe (1826-1867) and Sporer (1866-1880). The wings of the diagram are separated using a recently developed method based on an analysis of long gaps in sunspot group occurrence in different latitude bands. We define characteristic latitudes, corresponding to the start, end, and the largest extent of the wings (the F, L, and H latitudes). The H latitudes (30 degrees-45 degrees) are highly significantly correlated with the strength of the wings (quantified by the total sum of the monthly numbers of sunspot groups). The F latitudes (20 degrees-30 degrees) depict a weak tendency, especially in the southern hemisphere, to follow the wing strength. The L latitudes (2 degrees-10 degrees) show no clear relation to the wing strength. Overall, stronger cycle wings tend to start at higher latitudes and have a greater wing extent. A strong (5-6)-cycle periodic oscillation is found in the start and end times of the wings and in the overlap and gaps between successive wings of one hemisphere. While the average wing overlap is zero in the southern hemisphere, it is two to three months in the north. A marginally significant oscillation of about ten solar cycles is found in the asymmetry of the L latitudes. The new long database of butterfly wings provides new observational constraints to solar dynamo models that discuss the spatio-temporal distribution of sunspot occurrence over the solar cycle and longer. KW - Sun: activity KW - sunspots KW - history and philosophy of astronomy Y1 - 2017 U6 - https://doi.org/10.1051/0004-6361/201629533 SN - 1432-0746 VL - 599 PB - EDP Sciences CY - Les Ulis ER - TY - THES A1 - Kayser, Markus T1 - Wechselwirkung der atmosphärischen Grenzschicht mit synoptisch–skaligen Prozessen während der N-ICE2015 Kampagne N2 - Die Arktis erwärmt sich schneller als der Rest der Erde. Die Auswirkungen manifestieren sich unter Anderem in einer verstärkten Erwärmung der arktischen Grenzschicht. Diese Arbeit befasst sich mit Wechselwirkungen zwischen synoptischen Zyklonen und der arktischen Atmosphäre auf lokalen bis überregionalen Skalen. Ausgangspunkt dafür sind Messdaten und Modellsimulationen für den Zeitraum der N-ICE2015 Expedition, die von Anfang Januar bis Ende Juni 2015 im arktischen Nordatlantiksektor stattgefunden hat. Anhand von Radiosondenmessungen lassen sich Auswirkungen von synoptischen Zyklonen am deutlichsten im Winter erkennen, da sie durch die Advektion warmer und feuchter Luftmassen in die Arktis den Zustand der Atmosphäre von einem strahlungs-klaren in einen strahlungs-opaken ändern. Obwohl dieser scharfe Kontrast nur im Winter existiert, zeigt die Analyse, dass der integrierte Wasserdampf als Indikator für die Advektion von Luftmassen aus niedrigen Breiten in die Arktis auch im Frühjahr geeignet ist. Neben der Advektion von Luftmassen wird der Einfluss der Zyklonen auf die statische Stabilität charakterisiert. Beim Vergleich der N-ICE2015 Beobachtungen mit der SHEBA Kampagne (1997/1998), die über dickerem Eis stattfand, finden sich trotz der unterschiedlichen Meereisregime Ähnlichkeiten in der statischen Stabilität der Atmosphäre. Die beobachteten Differenzen in der Stabilität lassen sich auf Unterschiede in der synoptischen Aktivität zurückführen. Dies lässt vermuten, dass die dünnere Eisdecke auf saisonalen Zeitskalen nur einen geringen Einfluss auf die thermodynamische Struktur der arktischen Troposphäre besitzt, solange eine dicke Schneeschicht sie bedeckt. Ein weiterer Vergleich mit den parallel zur N-ICE2015 Kampagne gestarteten Radiosonden der AWIPEV Station in Ny-Åesund, Spitzbergen, macht deutlich, dass die synoptischen Zyklonen oberhalb der Orographie auf saisonalen Zeitskalen das Wettergeschehen bestimmen. Des Weiteren werden für Februar 2015 die Auswirkungen von in der Vertikalen variiertem Nudging auf die Entwicklung der Zyklonen am Beispiel des hydrostatischen regionalen Klimamodells HIRHAM5 untersucht. Es zeigt sich, dass die Unterschiede zwischen den acht Modellsimulationen mit abnehmender Anzahl der genudgten Level zunehmen. Die größten Differenzen resultieren vornehmlich aus dem zeitlichen Versatz der Entwicklung synoptischer Zyklonen. Zur Korrektur des Zeitversatzes der Zykloneninitiierung genügt es bereits, Nudging in den unterstem 250 m der Troposphäre anzuwenden. Daneben findet sich zwischen den genudgten HIRHAM5-Simulation und den in situ Messungen der gleiche positive Temperaturbias, den auch ERA-Interim besitzt. Das freie HIRHAM hingegen reproduziert das positive Ende der N-ICE2015 Temperaturverteilung gut, besitzt aber einen starken negativen Bias, der sehr wahrscheinlich aus einer Unterschätzung des Feuchtegehalts resultiert. An Beispiel einer Zyklone wird gezeigt, dass Nudging Einfluss auf die Lage der Höhentiefs besitzt, die ihrerseits die Zyklonenentwicklung am Boden beeinflussen. Im Weiteren wird mittels eines für kleine Ensemblegrößen geeigneten Varianzmaßes eine statistische Einschätzung der Wirkung des Nudgings auf die Vertikale getroffen. Es wird festgestellt, dass die Ähnlichkeit der Modellsimulationen in der unteren Troposphäre generell höher ist als darüber und in 500 hPa ein lokales Minimum besitzt. Im letzten Teil der Analyse wird die Wechselwirkung der oberen und unteren Stratosphäre anhand zuvor betrachteter Zyklonen mit Daten der ERA-Interim Reanalyse untersucht. Lage und Ausrichtung des Polarwirbels erzeugten ab Anfang Februar 2015 eine ungewöhnlich große Meridionalkomponente des Tropopausenjets, die Zugbahnen in die zentrale Arktis begünstigte. Am Beispiel einer Zyklone wird die Übereinstimmung der synoptischen Entwicklung mit den theoretischen Annahmen über den abwärts gerichteten Einfluss der Stratosphäre auf die Troposphäre hervorgehoben. Dabei spielt die nicht-lineare Wechselwirkung zwischen der Orographie Grönlands, einer Intrusion stratosphärischer Luft in die Troposphäre sowie einer in Richtung Arktis propagierender Rossby-Welle eine tragende Rolle. Als Indikator dieser Wechselwirkung werden horizontale Signaturen aus abwechselnd aufsteigender und absinkender Luft innerhalb der Troposphäre identifiziert. N2 - The Arctic warms faster than the rest of the earth. The causes and effects of this arctic amplification are manifested in the arctic atmosphere, especially in the atmospheric boundary layer, which plays a key role in the exchange processes of the atmosphere, ocean and sea ice. This work highlights the importance of synoptic cyclones in the Arctic North Atlantic region. For this purpose, the influence of synoptic cyclones on the Arctic boundary layer as well as their interactions with different regions within the Arctic atmosphere on local to supraregional scales is investigated. The starting point for this are measurement data and model simulations for the period of the NICE2015 expedition, which took place in the Arctic North Atlantic region from early January to late June 2015. On the basis of radiosonde measurements, the effects of synoptic cyclones are most noticeable in the winter because, by the advection of warm and humid air masses into the Arctic, the condition of the atmosphere changes from a radiative clear to opaquely cloudy. Although this sharp contrast only exists in winter, the analysis shows that integrated water vapor is an indicator for the advection of air masses from low latitudes into the Arctic even in the spring. In addition to the advection of air masses, the influence of cyclones on static stability is characterized. Comparing the N-ICE2015 observations with the SHEBA campaign (1997/1998), which took place over thicker ice, similarities are found in the static stability of the atmosphere despite the different sea ice regimes. The observed differences in stability can be attributed to differences in synoptic activity. A further comparison with the radiosondes of the AWIPEV station in Ny-Åesund, Spitzbergen, which were launched parallel to the N-ICE2015 campaign, shows that synoptic cyclones determine the course of the winter months. In addition, the effects of vertically-varying nudging on the development of cyclones is examined for February 2015 using the hydrostatic regional climate model HIRHAM5. It is shown that the differences between the eight model simulations are increasing with decreasing number of nudged levels. The greatest differences are mainly due to the temporal offset of the development of synoptic cyclones. To correct the time offset of the cyclone initiation, it is sufficient to use nudging in the lowest troposphere. The free HIRHAM reproduces the positive end of the N-ICE2015 temperature distribution well, but has a strong negative bias which most likely results from an under-estimation of the moisture content. An example of a cyclone shows that nudging has an influence on the position of the high altitude lows, which in turn influences cyclone development on the ground. Furthermore, a statistical estimate of the effect of nudging on the vertical is made by means of a variance measure suitable for small ensemble sizes. It is found that the similarity of model simulations in the lower troposphere is generally higher than above and has a local minimum in 500 hPa. In the last part of the analysis, the interaction of the upper troposphere and the lower stratosphere is investigated with data from the ERA interim reanalysis using previously examined cyclones. The position and orientation of the polar vortex produced an unusually large meridional component of the tropopause jets, which favored passage of low pressure systems into the central Arctic from the beginning of February 2015 onwards. Using a cyclone as an example, the synoptic development is compared with the theoretical assumptions about the downward impact of the stratosphere on the troposphere. The non-linear interaction between Greenland’s orography, an intrusion of stratospheric air into the troposphere, and a Rossby wave propagating in the direction of the Arctic play a key role in the selected time frame. As an indicator of this interaction, horizontal signatures are identified from alternately ascending and descending air within the troposphere. KW - arktische Grenzschicht KW - Arctic boundary layer KW - synoptische Zyklone KW - synoptic cyclones KW - thermodynamische Struktur KW - thermodynamic structure KW - regional climate simulations KW - regionale Klimasimulationen KW - nudging Y1 - 2017 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-411124 ER - TY - JOUR A1 - Allen, C. A1 - Archambault, S. A1 - Archer, A. A1 - Benbow, W. A1 - Bird, R. A1 - Bourbeau, E. A1 - Brose, Robert A1 - Buchovecky, M. A1 - Buckley, J. H. A1 - Bugaev, V. A1 - Cardenzana, J. V. A1 - Cerruti, M. A1 - Chen, Xuhui A1 - Christiansen, J. L. A1 - Connolly, M. P. A1 - Cui, W. A1 - Daniel, M. K. A1 - Eisch, J. D. A1 - Falcone, Abe A1 - Feng, Q. A1 - Fernandez-Alonso, M. A1 - Finley, J. P. A1 - Fleischhack, H. A1 - Flinders, A. A1 - Fortson, L. A1 - Furniss, A. A1 - Gillanders, G. H. A1 - Griffin, S. A1 - Grube, J. A1 - Huetten, M. A1 - Hakansson, N. A1 - Hanna, D. A1 - Hervet, O. A1 - Holder, J. A1 - Hughes, G. A1 - Humensky, T. B. A1 - Johnson, C. A. A1 - Kaaret, P. A1 - Kar, P. A1 - Kelley-Hoskins, N. A1 - Kertzman, M. A1 - Kieda, D. A1 - Krause, M. A1 - Krennrich, F. A1 - Kumar, S. A1 - Lang, M. J. A1 - Maier, G. A1 - McArthur, S. A1 - McCann, A. A1 - Meagher, K. A1 - Moriarty, P. A1 - Mukherjee, R. A1 - Nguyen, T. A1 - Nieto, D. A1 - Ong, R. A. A1 - Otte, A. N. A1 - Park, N. A1 - Petrashyk, A. A1 - Pichel, A. A1 - Pohl, Martin A1 - Popkow, A. A1 - Pueschel, Elisa A1 - Quinn, J. A1 - Ragan, K. A1 - Reynolds, P. T. A1 - Richards, G. T. A1 - Roache, E. A1 - Rovero, A. C. A1 - Rulten, C. A1 - Sadeh, I. A1 - Santander, Marcos A1 - Sembroski, G. H. A1 - Shahinyan, K. A1 - Telezhinsky, Igor O. A1 - Tucci, J. V. A1 - Tyler, J. A1 - Wakely, S. P. A1 - Weinstein, A. A1 - Wilhelm, Alina A1 - Williams, D. A. T1 - Very-High-Energy gamma-Ray Observations of the Blazar 1ES 2344+514 with VERITAS JF - Monthly notices of the Royal Astronomical Society N2 - We present very-high-energy gamma-ray observations of the BL Lac object 1ES 2344+514 taken by the Very Energetic Radiation Imaging Telescope Array System between 2007 and 2015. 1ES 2344+514 is detected with a statistical significance above the background of 20.8 sigma in 47.2 h (livetime) of observations, making this the most comprehensive very-high-energy study of 1ES 2344+514 to date. Using these observations, the temporal properties of 1ES 2344+514 are studied on short and long times-scales. We fit a constant-flux model to nightly and seasonally binned light curves and apply a fractional variability test to determine the stability of the source on different time-scales. We reject the constant-flux model for the 2007-2008 and 2014-2015 nightly binned light curves and for the long-term seasonally binned light curve at the > 3 sigma level. The spectra of the time-averaged emission before and after correction for attenuation by the extragalactic background light are obtained. The observed time-averaged spectrum above 200 GeV is satisfactorily fitted (x(2)/NDF = 7.89/6) by a power-law function with an index Gamma = 2.46 +/- 0.06(stat) +/- 0.20(sys) and extends to at least 8 TeV. The extragalactic-backgroundlight-deabsorbed spectrum is adequately fit (x(2)/NDF = 6.73/6) by a power-law function with an index Gamma = 2.15 +/- 0.06(stat) +/- 0.20(sys) while an F-test indicates that the power law with an exponential cut-off function provides a marginally better fit (x(2)/NDF = 2.56/5) at the 2.1 sigma level. The source location is found to be consistent with the published radio location and its spatial extent is consistent with a point source. KW - astroparticle physics KW - BL Lacertae objects: individual: 1ES 2344+514=VERJ2347+517 KW - gamma-rays: galaxies Y1 - 2017 U6 - https://doi.org/10.1093/mnras/stx1756 SN - 0035-8711 SN - 1365-2966 VL - 471 SP - 2117 EP - 2123 PB - Oxford Univ. Press CY - Oxford ER - TY - JOUR A1 - Kayser, Markus A1 - Maturilli, Marion A1 - Graham, Robert M. A1 - Hudson, Stephen R. A1 - Rinke, Annette A1 - Cohen, Lana A1 - Kim, Joo-Hong A1 - Park, Sang-Jong A1 - Moon, Woosok A1 - Granskog, Mats A. T1 - Vertical thermodynamic structure of the troposphere during the Norwegian young sea ICE expedition (N-ICE2015) JF - Journal of geophysical research-atmosheres N2 - The Norwegian young sea ICE (N-ICE2015) expedition was designed to investigate the atmosphere-snow-ice-ocean interactions in the young and thin sea ice regime north of Svalbard. Radiosondes were launched twice daily during the expedition from January to June 2015. Here we use these upper air measurements to study the multiple cyclonic events observed during N-ICE2015 with respect to changes in the vertical thermodynamic structure, moisture content, and boundary layer characteristics. We provide statistics of temperature inversion characteristics, static stability, and boundary layer extent. During winter, when radiative cooling is most effective, we find the strongest impact of synoptic cyclones. Changes to thermodynamic characteristics of the boundary layer are associated with transitions between the radiatively "clear" and "opaque" atmospheric states. In spring, radiative fluxes warm the surface leading to lifted temperature inversions and a statically unstable boundary layer. Further, we compare the N-ICE2015 static stability distributions to corresponding profiles from ERA-Interim reanalysis, from the closest land station in the Arctic North Atlantic sector, Ny-Alesund, and to soundings from the SHEBA expedition (1997/1998). We find similar stability characteristics for N-ICE2015 and SHEBA throughout the troposphere, despite differences in location, sea ice thickness, and snow cover. For Ny-Alesund, we observe similar characteristics above 1000 m, while the topography and ice-free fjord surrounding Ny-Alesund generate great differences below. The long-term radiosonde record (1993-2014) from Ny-Alesund indicates that during the N-ICE2015 spring period, temperatures were close to the climatological mean, while the lowest 3000 m were 1-3 degrees C warmer than the climatology during winter. Plain Language Summary The Norwegian young sea ICE (N-ICE2015) expedition was designed to investigate the atmosphere-snow-ice-ocean interactions in the young and thin sea ice regime north of Svalbard. Radiosondes were launched twice daily during the expedition from January to June 2015. Here we use these upper air measurements to study the multiple cyclonic events observed during N-ICE2015 with respect to changes in the vertical thermodynamic structure, moisture content, and the atmospheric boundary layer characteristics. During winter, we find the strongest impact of synoptic cyclones, which transport warm and moist air into the cold and dry Arctic atmosphere. In spring, incoming solar radiation warms the surface. This leads to very different thermodynamic conditions and higher moisture content, which reduces the contrast between stormy and calm periods. Further, we compare the N-ICE2015 measurements to corresponding profiles from ERA-Interim reanalysis, from the closest land station in the Arctic North Atlantic sector, Ny-Alesund, and to soundings from the SHEBA expedition (1997/1998). We find similar stability characteristics for N-ICE2015 and SHEBA throughout the troposphere, despite differences in location, sea ice thickness, and snow cover. The comparisons highlight the value of the N-ICE2015 observation and show the importance of winter time observations in the Arctic North Atlantic sector. Y1 - 2017 U6 - https://doi.org/10.1002/2016JD026089 SN - 2169-897X SN - 2169-8996 VL - 122 IS - 20 SP - 10855 EP - 10872 PB - American Geophysical Union CY - Washington ER - TY - JOUR A1 - Eckert, Sebastian A1 - Niskanen, Johannes A1 - Jay, Raphael Martin A1 - Miedema, Piter S. A1 - Fondell, Mattis A1 - Kennedy, Brian A1 - Quevedo, Wilson A1 - Iannuzzi, Marcella A1 - Föhlisch, Alexander T1 - Valence orbitals and local bond dynamics around N atoms of histidine under X-ray irradiation JF - Physical chemistry, chemical physics : a journal of European Chemical Societies N2 - The valence orbitals of aqueous histidine under basic, neutral and acidic conditions and their X-ray induced transformations have been monitored through N 1s resonant inelastic X-ray scattering. Using density functional ab initio molecular dynamics simulations in the core-hole state within the Z + 1 approximation, core-excitation-induced molecular transformations are quantified. Spectroscopic evidence for a highly directional X-ray-induced local N-H dissociation within the scattering duration is presented for acidic histidine. Our report demonstrates a protonation-state and chemical-environment dependent propensity for a molecular dissociation, which is induced by the absorption of high energy photons. This case study indicates that structural deformations in biomolecules under exposure to ionizing radiation, yielding possible alteration or loss of function, is highly dependent on the physiological state of the molecule upon irradiation. Y1 - 2017 U6 - https://doi.org/10.1039/c7cp05713j SN - 1463-9076 SN - 1463-9084 VL - 19 SP - 32091 EP - 32098 PB - Royal Society of Chemistry CY - Cambridge ER -