TY  - JOUR
A1  - Vidadala, Srinivasa Rao
A1  - Pimpalpalle, Tukaram M.
A1  - Linker, Torsten
A1  - Hotha, Srinivas
T1  - Gold-Catalyzed reactions of 2-C-Branched carbohydrates mild glycosidations and selective anomerizations
JF  - European journal of organic chemistry
N2  - 2-C-branched methyl glycosides react with various alcohols under gold catalysis to transglycosylated products. The method is applicable for the convenient synthesis of disaccharides. Without nucleophile a selective anomerization occurs, giving first access to alpha-configured 2-C-nitromethyl glycosides. The results are interesting for the mechanism of gold-catalyzed glycosidations.
KW  - Anomerization
KW  - Carbohydrates
KW  - Glycosidation
KW  - Gold
KW  - Synthetic methods
Y1  - 2011
U6  - https://doi.org/10.1002/ejoc.201100134
SN  - 1434-193X
IS  - 13
SP  - 2426
EP  - 2430
PB  - Wiley-Blackwell
CY  - Malden
ER  - 
TY  - JOUR
A1  - Pimpalpalle, Tukaram M.
A1  - Vidadala, Srinivasa Rao
A1  - Hotha, Srinivas
A1  - Linker, Torsten
T1  - Lewis acid-catalyzed stereoselective lactonization and subsequent glycosidation of 2-C-malonyl carbohydrates
JF  - Chemical communications
N2  - Gold(III) bromide is a suitable catalyst for the stereoselective cyclization of 2-C-malonyl carbohydrates to the anomeric center under retention of one ester group. Reopening of the lactones with alcohols in the presence of TMSOTf affords allyl, propargyl and benzyl glycosides with high alpha-selectivity.
Y1  - 2011
U6  - https://doi.org/10.1039/c1cc13425f
SN  - 1359-7345
VL  - 47
IS  - 37
SP  - 10434
EP  - 10436
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  -