TY - JOUR A1 - Schäfer, Thorsten A1 - Huber, Florian A1 - Seher, Holger A1 - Missana, Tiziana A1 - Alonso, Ursula A1 - Kumke, Michael Uwe A1 - Eidner, Sascha A1 - Claret, Francis A1 - Enzmann, Frieder T1 - Nanoparticles and their influence on radionuclide mobility in deep geological formations JF - Applied geochemistry : journal of the International Association of Geochemistry and Cosmochemistry N2 - This article gives an overview of the current status of knowledge concerning the role of nanoparticles (inorganic and organic) in deep geological host rocks and the potential influence of these nanoparticles on radionuclide migration in far-field systems. The manuscript is not intended to be a full review paper or overview paper concerning nanoparticles, here the intention is to refer to recent publications but to highlight the progress made in the 6th framework project IP FUNMIG (Fundamental processes of radionuclide migration) and the open literature over the past 5 a concerning the process understanding of nanoparticle related issues in the three host rock formations investigated, namely: claystones, crystalline rocks and salt rock overburden. The results show inter alia that the inorganic nanoparticle concentration in deep groundwaters of advection dominated systems rarely exceeds 1 mg L (1) and is expected to be in the ng L (1) range in diffusion controlled systems. For organic nanoparticles DOC concentrations up to tens of milligrams in diffusion-controlled indurated clays with molecular sizes mostly <500 Da have been found. Fulvic acid type organics have been identified in crystalline environments and plastic Clay formations (Boom Clay) with molecular sizes <= 300 kDa. Additional sources of inorganic nanoparticles from the repository near-field (compacted bentonite) were identified and the initial erosion rates were determined. The results indicate under stagnant conditions similar to 38 mg cm (2) a (1) for bi-distilled water, similar to 20 mg cm (2) a (1) for glacial melt water (Grimsel groundwater) and very low rates similar to 0.02 mg cm (2) a (1) for 5 mM CaCl2 contact water. The low critical coagulation concentration (CCC) indicative for purely diffusion controlled coagulation of 1 mM L (1) Ca2+ found in bentonite nanoparticle stability analysis matches the low nanoparticle mobilization from compacted bentonite found in these systems. Y1 - 2012 U6 - https://doi.org/10.1016/j.apgeochem.2011.09.009 SN - 0883-2927 VL - 27 IS - 2 SP - 390 EP - 403 PB - Elsevier CY - Oxford ER - TY - BOOK A1 - Schmidt, Thorsten Ingo A1 - Wagner, Dieter A1 - Schwerdtfeger, Roswitha A1 - Schäfer, Andrea A1 - Musil, Andreas A1 - Edeling, Thomas A1 - Bauer, Hartmut A1 - Kinyakin, Andrey A1 - Loladze, Besik A1 - Nehls, Danny A1 - Maaß, Christian A1 - Kuhlmann, Sabine A1 - Kuckei, Daniel A. A1 - Hein, Victoria A1 - Wille, Robert A1 - Franzke, Jochen A1 - Büchner, Christiane ED - Franzke, Jochen T1 - Festschrift für Dr. Christiane Büchner in Würdigung ihres Wirkens am Kommunalwissenschaftlichen Institut (1994–2022) T3 - KWI Schriften N2 - Diese eher ungewöhnliche, aber sehr persönlich gehaltene Festschrift ist dem lang­jährigen Wirken von Dr. Christiane Büchner als „Geschäftsführerin“ am Kommunal­wissenschaftlichen Institut (KWI) der Universität Potsdam gewidmet. Die von Prof. Jochen Franzke zusammengestellte und herausgegebene Publikation enthält im ersten Teil neben dem Grußwort des Geschäftsführenden Direktors des KWI Herrn Prof. Thorsten Ingo Schmidt eine Reihe persönlicher Würdigungen von Kolleginnen und Kollegen, Gastwissenschaftlern und Mitarbeitenden, die seit 1994 in verschiedenen Phasen der Entwicklung des KWIs mit Dr. Christiane Büchner eng zusammengearbeitet haben. Der abschließende Dokumentationsteil der Publikation enthält neben Auszügen aus dem Schriftenverzeichnis von Dr. Christiane Büchner auch zwei Nachdrucke aus deren Feder zum Thema der Kreisgebietsreform in Brandenburg (von 2001) sowie über den Landkreis Barnim (von 2019). T3 - KWI-Schriften - 13 KW - Festschrift KW - Kommunen KW - Landkreise KW - Kreisgebietsreform KW - Bibliografie Y1 - 2022 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-544987 SN - 978-3-86956-529-3 SN - 1867-951X SN - 1867-9528 IS - 13 PB - Universitätsverlag Potsdam CY - Potsdam ER -