TY - JOUR A1 - Ast, Sandra A1 - Schwarze, Thomas A1 - Müller, Holger A1 - Sukhanov, Aleksey A1 - Michaelis, Stefanie A1 - Wegener, Joachim A1 - Wolfbeis, Otto S. A1 - Körzdörfer, Thomas A1 - Dürkop, Axel A1 - Holdt, Hans-Jürgen T1 - A highly K+-Selective Phenylaza-[18]crown-6-Lariat-Ether-Based Fluoroionophore and its application in the sensing of K+ Ions with an optical sensor film and in cells JF - Chemistry - a European journal N2 - Herein, we report the synthesis of two phenylaza-[18]crown-6 lariat ethers with a coumarin fluorophore (1 and 2) and we reveal that compound 1 is an excellent probe for K+ ions under simulated physiological conditions. The presence of a 2-methoxyethoxy lariat group at the ortho position of the anilino moiety is crucial to the substantially increased stability of compounds 1 and 2 over their lariat-free phenylaza-[18] crown-6 ether analogues. Probe 1 shows a high K+/Na+ selectivity and a 2.5-fold fluorescence enhancement was observed in the presence of 100 mm K+ ions. A fluorescent membrane sensor, which was prepared by incorporating probe 1 into a hydrogel, showed a fully reversible response, a response time of 150 s, and a signal change of 7.8% per 1 mm K+ within the range 1-10 mm K+. The membrane was easily fabricated (only a single sensing layer on a solid polyester support), yet no leaching was observed. Moreover, compound 1 rapidly permeated into cells, was cytocompatible, and was suitable for the fluorescent imaging of K+ ions on both the extracellular and intracellular levels. KW - crown compounds KW - fluorescence KW - gels KW - potassium KW - sensors Y1 - 2013 U6 - https://doi.org/10.1002/chem.201302350 SN - 0947-6539 SN - 1521-3765 VL - 19 IS - 44 SP - 14911 EP - 14917 PB - Wiley-VCH CY - Weinheim ER - TY - JOUR A1 - Harth, Helene A1 - Haßler, Gerda A1 - Kosta, Peter A1 - Krüger, Hans-Peter A1 - Tristram, Hildegard L. C. A1 - Wegener, Heide A1 - Stehl, Thomas T1 - Laudation zur Verleihung des Doktogrades ehrenhalber an Herrn Prof. em. Dr. phil. Helmut Lüdke Y1 - 2008 SN - 978-3- 8233-6362-0 ER - TY - JOUR A1 - Weinhold, Till A1 - Wegener, Michael A1 - Künstler, Wolfgang A1 - Seiß, Martin A1 - Görne, Thomas A1 - Gerhard, Reimund T1 - Porous polytetrafluoroethylene (PTFE) single-film space-charge electrets with high piezoelectric coefficients Y1 - 2000 SN - 0537-9989 ER - TY - JOUR A1 - Bergweiler, Steffen A1 - Bergner, André A1 - Görne, Thomas A1 - Wegener, Michael A1 - Gerhard, Reimund T1 - Breathing modes and sound radiation of metallic organ pipes Y1 - 2003 ER - TY - THES A1 - Wegener, Thomas T1 - Das Image der Päpste BT - Pius XII., Johannes XXIII. und Paul VI. in bundesdeutschen Printmedien N2 - Wie jede öffentlichkeitssuchende Institution oder Person legen auch die katholische Kirche und ihre Päpste großen Wert auf das eigene Image. Dabei weicht die intendierte Selbstdarstellung oftmals von der medialen Wahrnehmung ab oder steht ihr sogar diametral entgegen. Ganz gleich ob Pius XII. als „Hitlers Papst“, Johannes XXIII. als „Revoluzzer“ oder Paul VI. als „Antipillenpapst“ – es existieren eine Fülle von außen zugetragener printmedialer Papst-Images, deren Entstehung, Verlauf und Brüche es in diesem Buch mithilfe einer mediensemiotischen, textbasierten Methodik auszumachen und nachzuzeichnen gilt. Y1 - 2022 SN - 978-3-658-37275-0 SN - 978-3-658-37276-7 U6 - https://doi.org/https://doi.org/10.1007/978-3-658-37276-7_1 PB - Springer VS CY - Wiesbaden ER - TY - JOUR A1 - Gerhard, Reimund A1 - Wegener, Michael A1 - Künstler, Wolfgang A1 - Wirges, Werner A1 - Görne, Thomas A1 - Urayama, D. A1 - Neher, Dieter T1 - Inverse piezoelectricity of porous PTFE films with bipolar space charge Y1 - 2000 ER -