TY - JOUR A1 - Thomas, Rainer A1 - Webster, J. D. A1 - Rhede, Dieter A1 - Seifert, W. A1 - Rickers, Karen A1 - Förster, Hans-Jürgen A1 - Heinrich, Wilhelm A1 - Davidson, P. T1 - The transition from peraluminous to peralkaline granitic melts: Evidence from melt inclusions and accessory minerals JF - Lithos : an international journal of mineralogy, petrology, and geochemistry N2 - Fractional crystallization of peraluminous F- and H(2)O-rich granite magmas progressively enriches the remaining melt with volatiles. We show that, at saturation, the melt may separate into two immiscible conjugate melt fractions, one of the fractions shows increasing peraluminosity and the other increasing peralkalinity. These melt fractions also fractionate the incompatible elements to significantly different degrees. Coexisting melt fractions have differing chemical and physical properties and, due to their high density and viscosity contrasts, they will tend to separate readily from each other. Once separated, each melt fraction evolves independently in response to changing T/P/X conditions and further immiscibility events may occur, each generating its own conjugate pair of melt fractions. The strongly peralkaline melt fractions in particular are very reactive and commonly react until equilibrium is attained. Consequently, the peralkaline melt fraction is commonly preserved only in the isolated melt and mineral inclusions. We demonstrate that the differences between melt fractions that can be seen most clearly in differing melt inclusion compositions are also visible in the composition of the resulting ore-forming and accessory minerals, and are visible on scales from a few micrometers to hundreds of meters. KW - granite melts KW - magma evolution KW - melt inclusions KW - melt-melt immiscibility KW - peraluminosity KW - peralkalinity KW - accessory minerals Y1 - 2006 U6 - https://doi.org/10.1016/j.lithos.2006.03.013 SN - 0024-4937 VL - 91 IS - 1-4 SP - 137 EP - 149 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Clahsen, Harald A1 - Siegmüller, Julia A1 - Penke, Martina A1 - Schröder, Astrid A1 - Hofmann, Janine A1 - Holzgrefe-Lang, Julia A1 - Skerra, Antje A1 - Adani, Flavia A1 - Gagarina, Natalʹja Vladimirovna A1 - Schröter, Carolin A1 - Frieg, Hendrike A1 - Belke, Eva A1 - Schwab, Susanne A1 - Seifert, Susanne A1 - Watko, Petra A1 - Obendrauf, Tanja A1 - Trauntschnig, Mike A1 - Gasteiger-Klicpera, Barbara A1 - Adelt, Anne A1 - Hanne, Sandra A1 - Burchert, Frank A1 - Swietza, Romy A1 - Doppelbauer, Lea A1 - Dralle, Jenny A1 - Purat, Patricia A1 - Webersinke, Dorothea A1 - Schwytay, Jeannine A1 - Stadie, Nicole A1 - Hoppe, Carina A1 - Heide, Judith A1 - Marusch, Tina A1 - von der Malsburg, Titus Raban A1 - Bastiaanse, Roelien A1 - Schultheiss, Corinna A1 - Nahrstaedt, Holger A1 - Schauer, Thomas A1 - Seidl, Rainer Ottis A1 - Rath, Elisa ED - Fritzsche, Tom ED - Meyer, Corinna B. ED - Adelt, Anne ED - Roß, Jennifer T1 - Spektrum Patholinguistik = Schwerpunktthema: Labyrinth Grammatik: Therapie von syntaktischen Störungen bei Kindern und Erwachsenen N2 - Das Herbsttreffen Patholinguistik wird seit 2007 jährlich vom Verband für Patholinguistik e.V. (vpl) durchgeführt. Das 6. Herbsttreffen mit dem Schwerpunktthema "Labyrinth Grammatik: Therapie von syntaktischen Störungen bei Kindern und Erwachsenen" fand am 17.11.2012 in Potsdam statt. Im vorliegenden Tagungsband finden sich alle Beiträge der Veranstaltung: die vier Hauptvorträge zum Schwerpunkthema, die Vorträge aus Praxis und Forschung von vier Patholinguistinnen in der Reihe Spektrum Patholinguistik sowie die Abstracts der Posterpräsentation. N2 - The 'Herbsttreffen Patholinguistik' is an annual conference organized by the Association for Patholinguistics (Verband für Patholinguistik e.V./vpl) since 2007. The 6th Herbsttreffen with its theme "Labyrinth Grammar: Therapy of Syntactic Disorders in Children and Adults" took place on November 17th, 2012 in Potsdam. These proceedings contain all contributions of the meeting: the four keynote talks, the talks on speech/language therapy and research in the section "Spektrum Patholinguistik" by four patholinguists as well as the abstracts of the poster session. T3 - Spektrum Patholinguistik - 6 KW - Patholinguistik KW - syntaktische Störungen KW - Aphasie KW - Agrammatismus KW - Dysgrammatismus KW - patholinguistics KW - speech/language therapy KW - syntactic disorders KW - aphasia KW - agrammatism Y1 - 2013 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-67659 SN - 978-3-86956-270-4 SN - 1869-3822 SN - 1866-9433 IS - 6 PB - Universitätsverlag Potsdam CY - Potsdam ER - TY - GEN A1 - Stoltnow, Malte A1 - Seifert, Thomas A1 - Jeske, Tilman J. A1 - Gilbricht, Sabine A1 - Krause, Joachim T1 - Contributions to the mineralogical and geochemical characterization of Fe-Sn-Zn-Cu-In skarn-type mineralization in the Schwarzenberg mining district, Germany T2 - Life with Ore Deposits on Earth – 15th SGA Biennial Meeting 2019 N2 - The Schwarzenberg mining district in the western Erzgebirge hosts numerous skarn-hosted tin-polymetallic deposits, such as Breitenbrunn. The St. Christoph mine is located in the Breitenbrunn deposit and is the locus typicus of christophite, an iron-rich sphalerite variety, which can be associated with indium enrichment. This study presents a revision of the paragenetic scheme, a contribution to the indium behavior and potential, and discussion on the origin of the sulfur. This was achieved through reflected light microscopy, SEM-based MLA, EPMA, and bulk mineral sulfur isotope analysis on 37 sulfide-rich skarn samples from a mineral collection. The paragenetic scheme includes: a pre-mineralization stage of anhydrous calc-silicates and hydrous minerals; an oxide stage, dominated by magnetite; a sulfide stage of predominantly sphalerite, minor pyrite, chalcopyrite, arsenopyrite, and galena. Some sphalerite samples present elevated indium contents of up to 0.44 wt%. Elevated iron contents (4-10 wt%) in sphalerite can be tentatively linked to increased indium incorporation, but further analyses are required. Analyzed sulfides exhibit homogeneous delta S-34 values (-1 to +2 parts per thousand VCDT), assumed to be post-magmatic. They correlate with other Fe-Sn-Zn-Cu-In skarn deposits in the western Erzgebirge, and Permian vein-hosted associations throughout the Erzgebirge region. Y1 - 2019 SP - 1089 EP - 1092 PB - SGA Soc Geology Applied mineral depositis CY - Geneva ER - TY - JOUR A1 - Seifert, Wolfgang A1 - Rhede, Dieter A1 - Förster, Hans-Jürgen A1 - Thomas, Rainer T1 - Accessory minerals as fingerprints for the thermal history and geochronology of the Caledonian Rumburk granite N2 - Accessory minerals of the Caledonian Rumburk granite are investigated to gain insight into its magmatic and post-magmatic evolution history. Recent geothermometers calibrated for trace elements in rutile (Zr), zircon (Ti), and quartz (Ti) were used to determine mineral-formation temperatures, which are compared with T data obtained from melt and fluid-inclusion Studies on quartz. Improved electron-microprobe analytical conditions allowed distinguishing several generations of rutile. Submicron-sized rutile needles included in quartz crystallized at around 739 +/- 13 degrees C and, thus, are evidently magmatic. Simultaneous crystallization of the high-T rutile and quartz is the favoured concept compared with an exsolution model for the needles. Th-U-total Pb dating of xenotime-(Y) by electron microprobe yielded a bimodal age distribution of 494 +/- 8 Ma (2 sigma; n = 44) and 311 +/- 8 Ma (2 sigma; n = 48), which is missing in monazite-(Ce). The older age correlates with the early Ordovician granite emplacement age Suggested by earlier isotopic Studies. The younger Carboniferous age also may be geologically reasonable, because the granite experienced a minor tectonothermal overprint during the Variscan orogenesis. However, whether this event has caused the resetting of the isotopic system in the xenotime is uncertain. This also holds for the age of the partial breakdown of monazite and xenotime into reaction coronas composed of fluorapatite, allanite-(Ce), epidote +/- clinozoisite. This alteration assemblage was likely produced already during autometasomatic reworking of the solidifying magma in Ordovician time, but it cannot be excluded that it relates to a Carboniferous fluid imprint connected with late-Variscan processes. Y1 - 2009 UR - http://www.ingentaconnect.com/content/schweiz/njma U6 - https://doi.org/10.1127/0077-7757/2009/0147 SN - 0077-7757 ER - TY - JOUR A1 - Debatin, Franziska A1 - Behrens, Karsten A1 - Weber, Jens A1 - Baburin, Igor A. A1 - Thomas, Arne A1 - Schmidt, Johannes A1 - Senkovska, Irena A1 - Kaskel, Stefan A1 - Kelling, Alexandra A1 - Hedin, Niklas A1 - Bacsik, Zoltan A1 - Leoni, Stefano A1 - Seifert, Gotthard A1 - Jäger, Christian A1 - Günter, Christina A1 - Schilde, Uwe A1 - Friedrich, Alwin A1 - Holdt, Hans-Jürgen T1 - An isoreticular family of microporous metal-organic frameworks based on zinc and 2-substituted imidazolate-4-amide-5-imidate Syntheses, structures and properties JF - Chemistry - a European journal N2 - We report on a new series of isoreticular frameworks based on zinc and 2-substituted imidazolate-4-amide-5-imidate (IFP-14, IFP=imidazolate framework Potsdam) that form one-dimensional, microporous hexagonal channels. Varying R in the 2-substitued linker (R=Me (IFP-1), Cl (IFP-2), Br (IFP-3), Et (IFP-4)) allowed the channel diameter (4.01.7 angstrom), the polarisability and functionality of the channel walls to be tuned. Frameworks IFP-2, IFP-3 and IFP-4 are isostructural to previously reported IFP-1. The structures of IFP-2 and IFP-3 were solved by X-ray crystallographic analyses. The structure of IFP-4 was determined by a combination of PXRD and structure modelling and was confirmed by IR spectroscopy and 1H MAS and 13C CP-MAS NMR spectroscopy. All IFPs showed high thermal stability (345400?degrees C); IFP-1 and IFP-4 were stable in boiling water for 7 d. A detailed porosity analysis was performed on the basis of adsorption measurements by using various gases. The potential of the materials to undergo specific interactions with CO2 was investigated by measuring the isosteric heats of adsorption. The capacity to adsorb CH4 (at 298 K), CO2 (at 298 K) and H2 (at 77 K) at high pressure were also investigated. In situ IR spectroscopy showed that CO2 is physisorbed on IFP-14 under dry conditions and that both CO2 and H2O are physisorbed on IFP-1 under moist conditions. KW - adsorption KW - metal- organic frameworks KW - microporous materials KW - N KW - O ligands KW - zinc Y1 - 2012 U6 - https://doi.org/10.1002/chem.201200889 SN - 0947-6539 VL - 18 IS - 37 SP - 11630 EP - 11640 PB - Wiley-VCH CY - Weinheim ER -