TY - JOUR A1 - Maiwald, Lisa Marie A1 - Junga, Yvonne Marie A1 - Lang, Thomas A1 - Montini, Romina A1 - Witthöft, Michael A1 - Heider, Jens A1 - Schröder, Annette A1 - Weck, Florian T1 - The role of therapist and patient in-session behavior for treatment outcome in exposure-based cognitive behavioral therapy for panic disorder with agoraphobia JF - Journal of clinical psychology N2 - Objective There is a very limited amount of research on the relationship between therapist and patient in‐session behavior and treatment outcome in cognitive behavioral therapy (CBT) for panic disorder with agoraphobia (PD/AG). Additionally, the findings tend to be inconclusive. This study investigates the association between therapist competence, adherence, patient interpersonal behavior, and therapeutic alliance and outcome in a low‐control CBT setting by using comprehensive measures. Methods Twenty‐six patients with PD/AG received 12 sessions of exposure‐based CBT. With regard to the outcome, treatments were classified either as problematic or nonproblematic by means of distinct criteria. Two raters evaluated the in‐session behavior. Results Patient interpersonal behavior was significantly associated with outcome at follow‐up (r = 0.49). At posttreatment, the correlation did not reach significance ( r = 0.34). Competence, adherence, and alliance were not outcome associated. Conclusion The findings emphasize the need for therapists to pay particular attention to patients’ interpersonal behavior during treatment. KW - interpersonal behavior KW - panic disorder with agoraphobia KW - therapeutic alliance KW - therapist competence KW - treatment outcome Y1 - 2018 U6 - https://doi.org/10.1002/jclp.22738 SN - 0021-9762 SN - 1097-4679 VL - 75 IS - 4 SP - 614 EP - 626 PB - Wiley CY - Hoboken ER - TY - JOUR A1 - Weber, Michael A1 - Scholz, Denis A1 - Schröder-Ritzrau, Andrea A1 - Deininger, Michael A1 - Spötl, Christoph A1 - Lugli, Federico A1 - Mertz-Kraus, Regina A1 - Jochum, Klaus Peter A1 - Fohlmeister, Jens Bernd A1 - Stumpf, Cintia F. A1 - Riechelmann, Dana F. C. T1 - Evidence of warm and humid interstadials in central Europe during early MISSUE 3 revealed by a multi-proxy speleothem record JF - Quaternary science reviews : the international multidisciplinary research and review journal N2 - Marine Isotope Stage 3 (MIS 3, 57-27 ka) was characterised by numerous rapid climate oscillations (i.e., Dansgaard-Oeschger (D/O-) events), which are reflected in various climate archives. So far, MIS 3 speleothem records from central Europe have mainly been restricted to caves located beneath temperate Alpine glaciers or close to the Atlantic Ocean. Thus, MIS 3 seemed to be too cold and dry to enable speleothem growth north of the Alps in central Europe. Here we present a new speleothem record from Bunker Cave, Germany, which shows two distinct growth phases from 52.0 (+0.8, -0.5) to 50.9 (+0.6, -1.3) ka and 473 (+1.0, -0.6) to 42.8 (+/- 0.9) ka, rejecting this hypothesis. These two growth phases potentially correspond to the two warmest and most humid phases in central Europe during MIS 3, which is confirmed by pollen data from the nearby Eifel. The hiatus separating the two phases is associated with Heinrich stadial 5 (HS 5), although the growth stop precedes the onset of HS 5. The first growth phase is characterised by a fast growth rate, and Mg concentrations and Sr isotope data suggest high infiltration and the presence of soil cover above the cave. The second growth phase was characterised by drier, but still favourable conditions for speleothem growth. During this phase, the delta C-13 values show a significant decrease associated with D/O-event 12. The timing of this shift is in agreement with other MIS 3 speleothem data from Europe and Greenland ice core data. (C) 2018 Elsevier Ltd. All rights reserved. KW - Speleothems KW - Pleistocene KW - Palaeoclimatology KW - Europe KW - Dansgaard-Oeschger event KW - Marine isotope stage 3 KW - Bunker cave KW - Multi-proxy approach KW - U-Th series Y1 - 2018 U6 - https://doi.org/10.1016/j.quascirev.2018.09.045 SN - 0277-3791 VL - 200 SP - 276 EP - 286 PB - Elsevier CY - Oxford ER - TY - JOUR A1 - Leitner, T. A1 - Josefsson, Ida A1 - Mazza, T. A1 - Miedema, Piter S. A1 - Schröder, H. A1 - Beye, Martin A1 - Kunnus, Kristjan A1 - Schreck, S. A1 - Düsterer, Stefan A1 - Föhlisch, Alexander A1 - Meyer, M. A1 - Odelius, Michael A1 - Wernet, Philippe T1 - Time-resolved electron spectroscopy for chemical analysis of photodissociation BT - Photoelectron spectra of Fe(CO)(5), Fe(CO)(4), and Fe(CO)(3) JF - The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr N2 - The prototypical photoinduced dissociation of Fe(CO)(5) in the gas phase is used to test time-resolved x-ray photoelectron spectroscopy for studying photochemical reactions. Upon one-photon excitation at 266 nm, Fe(CO)(5) successively dissociates to Fe(CO)(4) and Fe(CO)(3) along a pathway where both fragments retain the singlet multiplicity of Fe(CO)(5). The x-ray free-electron laser FLASH is used to probe the reaction intermediates Fe(CO)(4) and Fe(CO)(3) with time-resolved valence and core-level photoelectron spectroscopy, and experimental results are interpreted with ab initio quantum chemical calculations. Changes in the valence photoelectron spectra are shown to reflect changes in the valenceorbital interactions upon Fe-CO dissociation, thereby validating fundamental theoretical concepts in Fe-CO bonding. Chemical shifts of CO 3 sigma inner-valence and Fe 3 sigma core-level binding energies are shown to correlate with changes in the coordination number of the Fe center. We interpret this with coordination-dependent charge localization and core-hole screening based on calculated changes in electron densities upon core-hole creation in the final ionic states. This extends the established capabilities of steady-state electron spectroscopy for chemical analysis to time-resolved investigations. It could also serve as a benchmark for howcharge and spin density changes in molecular dissociation and excited-state dynamics are expressed in valence and core-level photoelectron spectroscopy. Published by AIP Publishing. Y1 - 2018 U6 - https://doi.org/10.1063/1.5035149 SN - 0021-9606 SN - 1089-7690 VL - 149 IS - 4 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Estendorfer, Jennifer A1 - Stempfhuber, Barbara A1 - Haury, Paula A1 - Vestergaard, Gisle A1 - Rillig, Matthias C. A1 - Joshi, Jasmin Radha A1 - Schröder, Peter A1 - Schloter, Michael T1 - The Influence of Land Use Intensity on the Plant-Associated Microbiome of Dactylis glomerata L. JF - Frontiers in plant science N2 - In this study, we investigated the impact of different land use intensities (LUI) on the root-associated microbiome of Dactylis glomerata (orchardgrass). For this purpose, eight sampling sites with different land use intensity levels but comparable soil properties were selected in the southwest of Germany. Experimental plots covered land use levels from natural grassland up to intensively managed meadows. We used 16S rRNA gene based barcoding to assess the plant-associated community structure in the endosphere, rhizosphere and bulk soil of D. glomerata. Samples were taken at the reproductive stage of the plant in early summer. Our data indicated that roots harbor a distinct bacterial community, which clearly differed from the microbiome of the rhizosphere and bulk soil. Our results revealed Pseudomonadaceae, Enterobacteriaceae and Comamonadaceae as the most abundant endophytes independently of land use intensity. Rhizosphere and bulk soil were dominated also by Proteobacteria, but the most abundant families differed from those obtained from root samples. In the soil, the effect of land use intensity was more pronounced compared to root endophytes leading to a clearly distinct pattern of bacterial communities under different LUI from rhizosphere and bulk soil vs. endophytes. Overall, a change of community structure on the plant-soil interface was observed, as the number of shared OTUs between all three compartments investigated increased with decreasing land use intensity. Thus, our findings suggest a stronger interaction of the plant with its surrounding soil under low land use intensity. Furthermore, the amount and quality of available nitrogen was identified as a major driver for shifts in the microbiome structure in all compartments. KW - Dactylis glomerata KW - land use change KW - endophytes KW - rhizosphere KW - soil microbiome KW - biodiversity Y1 - 2017 U6 - https://doi.org/10.3389/fpls.2017.00930 SN - 1664-462X VL - 8 PB - Frontiers Research Foundation CY - Lausanne ER - TY - JOUR A1 - Wernet, Philippe A1 - Leitner, T. A1 - Josefsson, Ida A1 - Mazza, T. A1 - Miedema, P. S. A1 - Schroder, H. A1 - Beye, Martin A1 - Kunnus, K. A1 - Schreck, S. A1 - Radcliffe, P. A1 - Dusterer, S. A1 - Meyer, M. A1 - Odelius, Michael A1 - Fohlisch, Alexander T1 - Communication: Direct evidence for sequential dissociation of gas-phase Fe(CO)(5) via a singlet pathway upon excitation at 266 nm JF - The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr N2 - We prove the hitherto hypothesized sequential dissociation of Fe(CO)(5) in the gas phase upon photoexcitation at 266 nm via a singlet pathway with time-resolved valence and core-level photoelectron spectroscopy with an x-ray free-electron laser. Valence photoelectron spectra are used to identify free CO molecules and to determine the time constants of stepwise dissociation to Fe(CO)(4) within the temporal resolution of the experiment and further to Fe(CO)(3) within 3 ps. Fe 3p core-level photoelectron spectra directly reflect the singlet spin state of the Fe center in Fe(CO)(5), Fe(CO)(4), and Fe(CO)(3) showing that the dissociation exclusively occurs along a singlet pathway without triplet-state contribution. Our results are important for assessing intra- and intermolecular relaxation processes in the photodissociation dynamics of the prototypical Fe(CO)(5) complex in the gas phase and in solution, and they establish time-resolved core-level photoelectron spectroscopy as a powerful tool for determining the multiplicity of transition metals in photochemical reactions of coordination complexes. Published by AIP Publishing. Y1 - 2017 U6 - https://doi.org/10.1063/1.4984774 SN - 0021-9606 SN - 1089-7690 VL - 146 PB - American Institute of Physics CY - Melville ER - TY - JOUR A1 - Kunnus, Kristjan A1 - Zhang, Wenkai A1 - Delcey, Mickael G. A1 - Pinjari, Rahul V. A1 - Miedema, Piter S. A1 - Schreck, Simon A1 - Quevedo, Wilson A1 - Schröder, Henning A1 - Föhlisch, Alexander A1 - Gaffney, Kelly J. A1 - Lundberg, Marcus A1 - Odelius, Michael A1 - Wernet, Philippe T1 - Viewing the Valence Electronic Structure of Ferric and Ferrous Hexacyanide in Solution from the Fe and Cyanide Perspectives JF - The journal of physical chemistry : B, Condensed matter, materials, surfaces, interfaces & biophysical chemistry N2 - The valence-excited states of ferric and ferrous hexacyanide ions in aqueous solution were mapped by resonant inelastic X-ray scattering (RIXS) at the Fe L-2,L-3 and N K edges. Probing of both the central Fe and the ligand N atoms enabled identification of the metal-and ligand-centered excited states, as well as ligand-to-metal and metal-to-ligand charge-transfer excited states. Ab initio calculations utilizing the RASPT2 method were used to simulate the Fe L-2,L-3-edge RIXS spectra and enabled quantification of the covalencies of both occupied and empty orbitals of pi and sigma symmetry. We found that pi back-donation in the ferric complex is smaller than that in the ferrous complex. This is evidenced by the relative amounts of Fe 3d character in the nominally 2 pi CN- molecular orbital of 7% and 9% in ferric and ferrous hexacyanide, respectively. Utilizing the direct sensitivity of Fe L-3-edge RIXS to the Fe 3d character in the occupied molecular orbitals, we also found that the donation interactions are dominated by sigma bonding. The latter was found to be stronger in the ferric complex, with an Fe 3d contribution to the nominally 5 sigma CN- molecular orbitals of 29% compared to 20% in the ferrous complex. These results are consistent with the notion that a higher charge at the central metal atom increases donation and decreases back-donation. Y1 - 2016 U6 - https://doi.org/10.1021/acs.jpcb.6b04751 SN - 1520-6106 VL - 120 SP - 7182 EP - 7194 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Vorpahl, Peter A1 - Dislich, Claudia A1 - Elsenbeer, Helmut A1 - Märker, Michael A1 - Schröder-Esselbach, Boris T1 - Biotic controls on shallow translational landslides JF - Earth surface processes and landforms : the journal of the British Geomorphological Research Group N2 - In undisturbed tropical montane rainforests massive organic layers accommodate the majority of roots and only a small fraction of roots penetrate the mineral soil. We investigated the contribution of vegetation to slope stability in such environments by modifying a standard model for slope stability to include an organic layer with distinct mechanical properties. The importance of individual model parameters was evaluated using detailed measurements of soil and vegetation properties to reproduce the observed depth of 11 shallow landslides in the Andes of southern Ecuador. By distinguishing mineral soil, organic layer and above-ground biomass, it is shown that in this environment vegetation provides a destabilizing effect mainly due to its contribution to the mass of the organic layer (up to 973 t ha-1 under wet conditions). Sensitivity analysis shows that the destabilizing effect of the mass of soil and vegetation can only be effective on slopes steeper than 37.9 degrees. This situation applies to 36% of the study area. Thus, on the steep slopes of this megadiverse ecosystem, the mass of the growing forest promotes landsliding, which in turn promotes a new cycle of succession. This feedback mechanism is worth consideration in further investigations of the impact of landslides on plant diversity in similar environments. KW - shallow translational landslides KW - tropical montane forest KW - biomass KW - organic layer Y1 - 2013 U6 - https://doi.org/10.1002/esp.3320 SN - 0197-9337 VL - 38 IS - 2 SP - 198 EP - 212 PB - Wiley-Blackwell CY - Hoboken ER - TY - JOUR A1 - Mitzner, Rolf A1 - Rehanek, Jens A1 - Kern, Jan A1 - Gul, Sheraz A1 - Hattne, Johan A1 - Taguchi, Taketo A1 - Alonso-Mori, Roberto A1 - Tran, Rosalie A1 - Weniger, Christian A1 - Schröder, Henning A1 - Quevedo, Wilson A1 - Laksmono, Hartawan A1 - Sierra, Raymond G. A1 - Han, Guangye A1 - Lassalle-Kaiser, Benedikt A1 - Koroidov, Sergey A1 - Kubicek, Katharina A1 - Schreck, Simon A1 - Kunnus, Kristjan A1 - Brzhezinskaya, Maria A1 - Firsov, Alexander A1 - Minitti, Michael P. A1 - Turner, Joshua J. A1 - Möller, Stefan A1 - Sauter, Nicholas K. A1 - Bogan, Michael J. A1 - Nordlund, Dennis A1 - Schlotter, William F. A1 - Messinger, Johannes A1 - Borovik, Andrew S. A1 - Techert, Simone A1 - de Groot, Frank M. F. A1 - Föhlisch, Alexander A1 - Erko, Alexei A1 - Bergmann, Uwe A1 - Yachandra, Vittal K. A1 - Wernet, Philippe A1 - Yano, Junko T1 - L-edge x-ray absorption spectroscopy of dilute systems relevant to metalloproteins using an X-ray free-electron laser JF - The journal of physical chemistry letters N2 - L-edge spectroscopy of 3d transition metals provides important electronic structure information and has been used in many fields. However, the use of this method for studying dilute aqueous systems, such as metalloenzymes, has not been prevalent because of severe radiation damage and the lack of suitable detection systems. Here we present spectra from a dilute Mn aqueous solution using a high-transmission zone-plate spectrometer at the Linac Coherent Light Source (LCLS). The spectrometer has been optimized for discriminating the Mn L-edge signal from the overwhelming 0 K-edge background that arises from water and protein itself, and the ultrashort LCLS X-ray pulses can outrun X-ray induced damage. We show that the deviations of the partial-fluorescence yield-detected spectra from the true absorption can be well modeled using the state-dependence of the fluorescence yield, and discuss implications for the application of our concept to biological samples. Y1 - 2013 U6 - https://doi.org/10.1021/jz401837f SN - 1948-7185 VL - 4 IS - 21 SP - 3641 EP - 3647 PB - American Chemical Society CY - Washington ER - TY - JOUR A1 - Vorpahl, Peter A1 - Elsenbeer, Helmut A1 - Märker, Michael A1 - Schröder-Esselbach, Boris T1 - How can statistical models help to determine driving factors of landslides? JF - Ecological modelling : international journal on ecological modelling and engineering and systems ecolog N2 - Landslides are a hazard for humans and artificial structures. From an ecological point of view, they represent an important ecosystem disturbance, especially in tropical montane forests. Here, shallow translational landslides are a frequent natural phenomenon and one local determinant of high levels of biodiversity. In this paper, we apply weighted ensembles of advanced phenomenological models from statistics and machine learning to analyze the driving factors of natural landslides in a tropical montane forest in South Ecuador. We exclusively interpret terrain attributes, derived from a digital elevation model, as proxies to several driving factors of landslides and use them as predictors in our models which are trained on a set of five historical landslide inventories. We check the model generality by transferring them in time and use three common performance criteria (i.e. AUC, explained deviance and slope of model calibration curve) to, on the one hand, compare several state-of-the-art model approaches and on the other hand, to create weighted model ensembles. Our results suggest that it is important to consider more than one single performance criterion. Approaching our main question, we compare responses of weighted model ensembles that were trained on distinct functional units of landslides (i.e. initiation, transport and deposition zones). This way, we are able to show that it is quite possible to deduce driving factors of landslides, if the consistency between the training data and the processes is maintained. Opening the 'black box' of statistical models by interpreting univariate model response curves and relative importance of single predictors regarding their plausibility, we provide a means to verify this consistency. With the exception of classification tree analysis, all techniques performed comparably well in our case study while being outperformed by weighted model ensembles. Univariate response curves of models trained on distinct functional units of landslides exposed different shapes following our expectations. Our results indicate the occurrence of landslides to be mainly controlled by factors related to the general position along a slope (i.e. ridge, open slope or valley) while landslide initiation seems to be favored by small scale convexities on otherwise plain open slopes. KW - Landslides KW - Tropical montane forests KW - Statistical modeling KW - Model comparison KW - Artificial neuronal network KW - Classification trees KW - Random forests KW - Boosted regression trees KW - Generalized linear models KW - Multivariate adaptive regression splines KW - Maximum entropy method KW - Weighted model ensembles Y1 - 2012 U6 - https://doi.org/10.1016/j.ecolmodel.2011.12.007 SN - 0304-3800 SN - 1872-7026 VL - 239 IS - 7 SP - 27 EP - 39 PB - Elsevier CY - Amsterdam ER - TY - JOUR A1 - Böhme, Romy A1 - Burmester, Juliane A1 - Krajewski, Melanie A1 - Nager, Wido A1 - Jungehülsing, Gerhard Jan A1 - Schröder, Astrid A1 - Wartenburger, Isabell A1 - Jöbges, Michael T1 - Transkranielle Gleichstromstimulation (tDCS) BT - zur Entwicklung einer Therapiestudie in der Behandlung von aphasischen Störungen des mündlichen Bildbenennens JF - Spektrum Patholinguistik Y1 - 2010 U6 - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-47045 SN - 1866-9085 SN - 1866-9433 VL - 3 SP - 167 EP - 174 PB - Universitätsverlag Potsdam CY - Potsdam ER -