TY  - JOUR
A1  - Mei, Shilin
A1  - Jafta, Charl J.
A1  - Lauermann, Iver
A1  - Ran, Qidi
A1  - Kaergell, Martin
A1  - Ballauff, Matthias
A1  - Lu, Yan
T1  - Porous Ti4O7 Particles with Interconnected-Pore Structure as a High-Efficiency Polysulfide Mediator for Lithium-Sulfur Batteries
JF  - Advanced functional materials
N2  - Multifunctional Ti4O7 particles with interconnected-pore structure are designed and synthesized using porous poly(styrene-b-2-vinylpyridine) particles as a template. The particles can work efficiently as a sulfur-host material for lithium-sulfur batteries. Specifically, the well-defined porous Ti4O7 particles exhibit interconnected pores in the interior and have a high-surface area of 592 m(2) g(-1); this shows the advantage of mesopores for encapsulating of sulfur and provides a polar surface for chemical binding with polysulfides to suppress their dissolution. Moreover, in order to improve the conductivity of the electrode, a thin layer of carbon is coated on the Ti4O7 surface without destroying its porous structure. The porous Ti4O7 and carbon-coated Ti4O7 particles show significantly improved electrochemical performances as cathode materials for Li-S batteries as compared with those of TiO2 particles.
KW  - lithium-sulfur batteries
KW  - porous particles
KW  - poly(styrene-b-2-vinylpyridine) (PS-P2VP)
KW  - Ti4O7
Y1  - 2017
U6  - https://doi.org/10.1002/adfm.201701176
SN  - 1616-301X
SN  - 1616-3028
VL  - 27
PB  - Wiley-VCH
CY  - Weinheim
ER  - 
TY  - JOUR
A1  - Jia, He
A1  - Gao, Haitao
A1  - Mei, Shilin
A1  - Kneer, Janosch
A1  - Lin, Xianzhong
A1  - Ran, Qidi
A1  - Wang, Fuxian
A1  - Palzer, Stefan
A1  - Lu, Yan
T1  - Cu2O@PNIPAM core-shell microgels as novel inkjet materials for the preparation of CuO hollow porous nanocubes gas sensing layers
JF  - Journal of materials chemistry : C, Materials for optical and electronic devices
N2  - There has been long-standing interest in developing metal oxide-based sensors with high sensitivity, selectivity, fast response and low material consumption. Here we report for the first time the utilization of Cu2O@PNIPAM core-shell microgels with a nanocube-shaped core structure for construction of novel CuO gas sensing layers. The hybrid microgels show significant improvement in colloidal stability as compared to native Cu2O nanocubes. Consequently, a homogeneous thin film of Cu2O@PNIPAM nanoparticles can be engineered in a quite low solid content (1.5 wt%) by inkjet printing of the dispersion at an optimized viscosity and surface tension. Most importantly, thermal treatment of the Cu2O@PNIPAM microgels forms porous CuO nanocubes, which show much faster response to relevant trace NO2 gases than sensors produced from bare Cu2O nanocubes. This outcome is due to the fact that the PNIPAM shell can successfully hinder the aggregation of CuO nanoparticles during pyrolysis, which enables full utilization of the sensor layers and better access of the gas to active sites. These results point out great potential of such an innovative system as gas sensors with low cost, fast response and high sensitivity.
Y1  - 2018
U6  - https://doi.org/10.1039/c8tc01995a
SN  - 2050-7526
SN  - 2050-7534
VL  - 6
IS  - 27
SP  - 7249
EP  - 7256
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  -