TY  - JOUR
A1  - Allan, Eric
A1  - Manning, Pete
A1  - Alt, Fabian
A1  - Binkenstein, Julia
A1  - Blaser, Stefan
A1  - Blüthgen, Nico
A1  - Böhm, Stefan
A1  - Grassein, Fabrice
A1  - Hölzel, Norbert
A1  - Klaus, Valentin H.
A1  - Kleinebecker, Till
A1  - Morris, E. Kathryn
A1  - Oelmann, Yvonne
A1  - Prati, Daniel
A1  - Renner, Swen C.
A1  - Rillig, Matthias C.
A1  - Schaefer, Martin
A1  - Schloter, Michael
A1  - Schmitt, Barbara
A1  - Schöning, Ingo
A1  - Schrumpf, Marion
A1  - Solly, Emily
A1  - Sorkau, Elisabeth
A1  - Steckel, Juliane
A1  - Steffen-Dewenter, Ingolf
A1  - Stempfhuber, Barbara
A1  - Tschapka, Marco
A1  - Weiner, Christiane N.
A1  - Weisser, Wolfgang W.
A1  - Werner, Michael
A1  - Westphal, Catrin
A1  - Wilcke, Wolfgang
A1  - Fischer, Markus
T1  - Land use intensification alters ecosystem multifunctionality via loss of biodiversity and changes to functional composition
JF  - Ecology letters
N2  - Global change, especially land-use intensification, affects human well-being by impacting the delivery of multiple ecosystem services (multifunctionality). However, whether biodiversity loss is a major component of global change effects on multifunctionality in real-world ecosystems, as in experimental ones, remains unclear. Therefore, we assessed biodiversity, functional composition and 14 ecosystem services on 150 agricultural grasslands differing in land-use intensity. We also introduce five multifunctionality measures in which ecosystem services were weighted according to realistic land-use objectives. We found that indirect land-use effects, i.e. those mediated by biodiversity loss and by changes to functional composition, were as strong as direct effects on average. Their strength varied with land-use objectives and regional context. Biodiversity loss explained indirect effects in a region of intermediate productivity and was most damaging when land-use objectives favoured supporting and cultural services. In contrast, functional composition shifts, towards fast-growing plant species, strongly increased provisioning services in more inherently unproductive grasslands.
KW  - Biodiversity-ecosystem functioning
KW  - ecosystem services
KW  - global change
KW  - land use
KW  - multifunctionality
Y1  - 2015
U6  - https://doi.org/10.1111/ele.12469
SN  - 1461-023X
SN  - 1461-0248
VL  - 18
IS  - 8
SP  - 834
EP  - 843
PB  - Wiley-Blackwell
CY  - Hoboken
ER  - 
TY  - JOUR
A1  - Soliveres, Santiago
A1  - van der Plas, Fons
A1  - Manning, Peter
A1  - Prati, Daniel
A1  - Gossner, Martin M.
A1  - Renner, Swen C.
A1  - Alt, Fabian
A1  - Arndt, Hartmut
A1  - Baumgartner, Vanessa
A1  - Binkenstein, Julia
A1  - Birkhofer, Klaus
A1  - Blaser, Stefan
A1  - Blüthgen, Nico
A1  - Boch, Steffen
A1  - Böhm, Stefan
A1  - Börschig, Carmen
A1  - Buscot, Francois
A1  - Diekötter, Tim
A1  - Heinze, Johannes
A1  - Hölzel, Norbert
A1  - Jung, Kirsten
A1  - Klaus, Valentin H.
A1  - Kleinebecker, Till
A1  - Klemmer, Sandra
A1  - Krauss, Jochen
A1  - Lange, Markus
A1  - Morris, E. Kathryn
A1  - Müller, Jörg
A1  - Oelmann, Yvonne
A1  - Overmann, Jörg
A1  - Pasalic, Esther
A1  - Rillig, Matthias C.
A1  - Schaefer, H. Martin
A1  - Schloter, Michael
A1  - Schmitt, Barbara
A1  - Schöning, Ingo
A1  - Schrumpf, Marion
A1  - Sikorski, Johannes
A1  - Socher, Stephanie A.
A1  - Solly, Emily F.
A1  - Sonnemann, Ilja
A1  - Sorkau, Elisabeth
A1  - Steckel, Juliane
A1  - Steffan-Dewenter, Ingolf
A1  - Stempfhuber, Barbara
A1  - Tschapka, Marco
A1  - Türke, Manfred
A1  - Venter, Paul C.
A1  - Weiner, Christiane N.
A1  - Weisser, Wolfgang W.
A1  - Werner, Michael
A1  - Westphal, Catrin
A1  - Wilcke, Wolfgang
A1  - Wolters, Volkmar
A1  - Wubet, Tesfaye
A1  - Wurst, Susanne
A1  - Fischer, Markus
A1  - Allan, Eric
T1  - Biodiversity at multiple trophic levels is needed for ecosystem multifunctionality
JF  - Nature : the international weekly journal of science
Y1  - 2016
U6  - https://doi.org/10.1038/nature19092
SN  - 0028-0836
SN  - 1476-4687
VL  - 536
SP  - 456
EP  - +
PB  - Nature Publ. Group
CY  - London
ER  - 
TY  - GEN
A1  - Sturzbecher, Dietmar
A1  - Schmitt, Michael
A1  - Rump-Räuber, Michael
T1  - Extrem rechts in Deutschland
T2  - Wochenschau für politische Erziehung, Sozial- und Gemeinschaftskunde : Ausg. Sek I + II
Y1  - 2002
SN  - 978-3-87929-809-8
VL  - 53, 2002
PB  - Wochenschau-Verl.
CY  - Schwalbach/Ts.
ER  - 
TY  - JOUR
A1  - Soliveres, Santiago
A1  - Manning, Peter
A1  - Prati, Daniel
A1  - Gossner, Martin M.
A1  - Alt, Fabian
A1  - Arndt, Hartmut
A1  - Baumgartner, Vanessa
A1  - Binkenstein, Julia
A1  - Birkhofer, Klaus
A1  - Blaser, Stefan
A1  - Bluethgen, Nico
A1  - Boch, Steffen
A1  - Boehm, Stefan
A1  - Boerschig, Carmen
A1  - Buscot, Francois
A1  - Diekoetter, Tim
A1  - Heinze, Johannes
A1  - Hoelzel, Norbert
A1  - Jung, Kirsten
A1  - Klaus, Valentin H.
A1  - Klein, Alexandra-Maria
A1  - Kleinebecker, Till
A1  - Klemmer, Sandra
A1  - Krauss, Jochen
A1  - Lange, Markus
A1  - Morris, E. Kathryn
A1  - Mueller, Joerg
A1  - Oelmann, Yvonne
A1  - Overmann, Jörg
A1  - Pasalic, Esther
A1  - Renner, Swen C.
A1  - Rillig, Matthias C.
A1  - Schaefer, H. Martin
A1  - Schloter, Michael
A1  - Schmitt, Barbara
A1  - Schoening, Ingo
A1  - Schrumpf, Marion
A1  - Sikorski, Johannes
A1  - Socher, Stephanie A.
A1  - Solly, Emily F.
A1  - Sonnemann, Ilja
A1  - Sorkau, Elisabeth
A1  - Steckel, Juliane
A1  - Steffan-Dewenter, Ingolf
A1  - Stempfhuber, Barbara
A1  - Tschapka, Marco
A1  - Tuerke, Manfred
A1  - Venter, Paul
A1  - Weiner, Christiane N.
A1  - Weisser, Wolfgang W.
A1  - Werner, Michael
A1  - Westphal, Catrin
A1  - Wilcke, Wolfgang
A1  - Wolters, Volkmar
A1  - Wubet, Tesfaye
A1  - Wurst, Susanne
A1  - Fischer, Markus
A1  - Allan, Eric
T1  - Locally rare species influence grassland ecosystem multifunctionality
JF  - Philosophical transactions of the Royal Society of London : B, Biological sciences
N2  - Species diversity promotes the delivery of multiple ecosystem functions (multifunctionality). However, the relative functional importance of rare and common species in driving the biodiversity multifunctionality relationship remains unknown. We studied the relationship between the diversity of rare and common species (according to their local abundances and across nine different trophic groups), and multifunctionality indices derived from 14 ecosystem functions on 150 grasslands across a land use intensity (LUI) gradient. The diversity of above- and below-ground rare species had opposite effects, with rare above-ground species being associated with high levels of multifunctionality, probably because their effects on different functions did not trade off against each other. Conversely, common species were only related to average, not high, levels of multifunctionality, and their functional effects declined with LUI. Apart from the community level effects of diversity, we found significant positive associations between the abundance of individual species and multifunctionality in 6% of the species tested. Species specific functional effects were best predicted by their response to LUI: species that declined in abundance with land use intensification were those associated with higher levels of multifunctionality. Our results highlight the importance of rare species for ecosystem multifunctionality and help guiding future conservation priorities.
KW  - biodiversity
KW  - common species
KW  - ecosystem function
KW  - identity hypothesis
KW  - land use
KW  - multitrophic
Y1  - 2016
U6  - https://doi.org/10.1098/rstb.2015.0269
SN  - 0962-8436
SN  - 1471-2970
VL  - 371
SP  - 3175
EP  - 3185
PB  - Royal Society
CY  - London
ER  - 
TY  - JOUR
A1  - Ehmann, Lisa
A1  - Zoller, Michael
A1  - Minichmayr, Iris K.
A1  - Scharf, Christina
A1  - Maier, Barbara
A1  - Schmitt, Maximilian V.
A1  - Hartung, Niklas
A1  - Huisinga, Wilhelm
A1  - Vogeser, Michael
A1  - Frey, Lorenz
A1  - Zander, Johannes
A1  - Kloft, Charlotte
T1  - Role of renal function in risk assessment of target non-attainment after standard dosing of meropenem in critically ill patients
BT  - a prospective observational study
JF  - Critical care
N2  - Background: Severe bacterial infections remain a major challenge in intensive care units because of their high prevalence and mortality. Adequate antibiotic exposure has been associated with clinical success in critically ill patients. The objective of this study was to investigate the target attainment of standard meropenem dosing in a heterogeneous critically ill population, to quantify the impact of the full renal function spectrum on meropenem exposure and target attainment, and ultimately to translate the findings into a tool for practical application. Methods: A prospective observational single-centre study was performed with critically ill patients with severe infections receiving standard dosing of meropenem. Serial blood samples were drawn over 4 study days to determine meropenem serum concentrations. Renal function was assessed by creatinine clearance according to the Cockcroft and Gault equation (CLCRCG). Variability in meropenem serum concentrations was quantified at the middle and end of each monitored dosing interval. The attainment of two pharmacokinetic/pharmacodynamic targets (100% T->MIC, 50% T->4xMIC) was evaluated for minimum inhibitory concentration (MIC) values of 2 mg/L and 8 mg/L and standard meropenem dosing (1000 mg, 30-minute infusion, every 8 h). Furthermore, we assessed the impact of CLCRCG on meropenem concentrations and target attainment and developed a tool for risk assessment of target non-attainment. Results: Large inter-and intra-patient variability in meropenem concentrations was observed in the critically ill population (n = 48). Attainment of the target 100% T->MIC was merely 48.4% and 20.6%, given MIC values of 2 mg/L and 8 mg/L, respectively, and similar for the target 50% T->4xMIC. A hyperbolic relationship between CLCRCG (25-255 ml/minute) and meropenem serum concentrations at the end of the dosing interval (C-8h) was derived. For infections with pathogens of MIC 2 mg/L, mild renal impairment up to augmented renal function was identified as a risk factor for target non-attainment (for MIC 8 mg/L, additionally, moderate renal impairment). Conclusions: The investigated standard meropenem dosing regimen appeared to result in insufficient meropenem exposure in a considerable fraction of critically ill patients. An easy-and free-to-use tool (the MeroRisk Calculator) for assessing the risk of target non-attainment for a given renal function and MIC value was developed.
KW  - beta-Lactam
KW  - Intensive care
KW  - Pharmacokinetics/Pharmacodynamics
KW  - Target attainment
KW  - Renal function
KW  - Risk assessment tool
KW  - Continuous renal replacement therapy
Y1  - 2017
U6  - https://doi.org/10.1186/s13054-017-1829-4
SN  - 1466-609X
SN  - 1364-8535
VL  - 21
PB  - BioMed Central
CY  - London
ER  - 
TY  - BOOK
A1  - Schmitt, Hanno
A1  - Dogerloh, Annette
A1  - Niedermeier, Michael
A1  - Siebrecht, Silke
T1  - Leben, Lust und Tod in Gärten um 1800 : [Begleitbuch zur Ausstellung im Rochow-Museum Reckahn vom 29. August bis 28 November 2004]
Y1  - 2004
SN  - 3-9809752-0-7
PB  - Rochow-Museum und Akad. für Bildungsgeschichtliche Forschung
CY  - Berlin
ER  - 
TY  - JOUR
A1  - Pröve, Ralf
A1  - Kroll, Stefan
A1  - Asche, Matthias
A1  - Heinecke, Anne
A1  - Huhtamies, Mikko
A1  - Marschke, Benjamin
A1  - Gräf, Holger Th.
A1  - Reimer, Torsten F.
A1  - Schmitt, Bernhard
A1  - Muth, Jörg
A1  - Reiff, Michael
A1  - Gebuhr, Ralf
A1  - Martin, Alexander M.
A1  - Krebs, Daniel
T1  - Militär und Gesellschaft in der Frühen Neuzeit
N2  - Aus dem Inhalt dieser Ausgabe: BEITRAG: Ralf Pröve: Vom Schmuddelkind zur anerkannten Subdisziplin?1Die „neue Militärgeschichte“ der Frühen Neuzeitund der AMG PROJEKTE: Stefan Kroll: Kursächsische Soldaten im 18. Jahrhundert (1728-1789) Matthias Asche: Neusiedler im verheerten Land –Kriegsfolgenbewältigung, Landeswiederaufbau undMigration in der Mark Brandenburg und in Badennach den Kriegen des 17. Jahrhunderts Anne Heinecke: Wahrnehmung und Darstellungvon Plünderung im 17. Jahrhundertim Spiegel von Selbstzeugnissen Militärangehöriger Mikko Huhtamies: Ersatzsoldaten in Europa in der Frühen Neuzeit Benjamin MarschkeThe Development of the Army Chaplaincy inEarly Eighteenth-Century Prussia Holger Th. Gräf: Valentin Wagner – Zeichnungen aus der Zeit desDreißigjährigen Krieges Torsten F. Reimer: magi-e – integriertes Publizierenin der Geschichtswissenschaft Bernhard Schmitt: Militär und Integration im 19. Jahrhundert –Zur Bedeutung und Funktion der Armeebei der Eingliederung neuer Bevölkerungsgruppenin Preußen und der Habsburgermonarchie 1815-1867 Jörg Muth: Flucht aus dem militärischen AlltagUrsachen und individuelle Ausprägung der Desertionin der Armee Friedrichs des Großen Michael Reiff: Strandgut des Krieges: Die soziale Lage Kriegsversehrterin den deutschen Armeen des Absolutismusund der napoleonischen Zeit ( 1648 – 1815 ) Ralf Gebuhr: Nickel von Minckwitzund der frühneuzeitliche Schlossbauin der Niederlausitz Alexander M. Martin: Die Napoleonische Okkupation Moskaus 1812 Daniel Krebs: Deutsche Kriegsgefangeneim Amerikanischen Unabhängigkeitskrieg BERICHTE: REZENSIONEN:
T3  - Militär und Gesellschaft in der frühen Neuzeit - 5, Heft 1 
KW  - Militär / Geschichte
Y1  - 2001
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-28135
SN  - 1617-9722
SN  - 1861-910X
VL  - 5
IS  - 1
ER  - 
TY  - JOUR
A1  - Sun, Y. -P.
A1  - Hennies, Franz
A1  - Pietzsch, Annette
A1  - Kennedy, B.
A1  - Schmitt, Thorsten
A1  - Strocov, Vladimir N.
A1  - Andersson, Joakim
A1  - Berglund, Martin
A1  - Rubensson, Jan-Erik
A1  - Aidas, K.
A1  - Gel'mukhanov, F.
A1  - Odelius, Michael
A1  - Föhlisch, Alexander
T1  - Intramolecular soft modes and intermolecular interactions in liquid acetone
JF  - Physical review : B, Condensed matter and materials physics
N2  - Resonant inelastic x-ray scattering spectra excited at the O1s(-1)pi* resonance of liquid acetone are presented. Scattering to the electronic ground state shows a resolved vibrational progression where the dominant contribution is due to the C-O stretching mode, thus demonstrating a unique sensitivity of the method to the local potential energy surface in complex molecular systems. For scattering to electronically excited states, soft vibrational modes and, to a smaller extent, intermolecular interactions give a broadening, which blurs the vibrational fine structure. It is predicted that environmental broadening is dominant in aqueous acetone.
Y1  - 2011
U6  - https://doi.org/10.1103/PhysRevB.84.132202
SN  - 1098-0121
VL  - 84
IS  - 13
PB  - American Physical Society
CY  - College Park
ER  - 
TY  - JOUR
A1  - Toy, Virginia Gail
A1  - Sutherland, Rupert
A1  - Townend, John
A1  - Allen, Michael J.
A1  - Becroft, Leeza
A1  - Boles, Austin
A1  - Boulton, Carolyn
A1  - Carpenter, Brett
A1  - Cooper, Alan
A1  - Cox, Simon C.
A1  - Daube, Christopher
A1  - Faulkner, D. R.
A1  - Halfpenny, Angela
A1  - Kato, Naoki
A1  - Keys, Stephen
A1  - Kirilova, Martina
A1  - Kometani, Yusuke
A1  - Little, Timothy
A1  - Mariani, Elisabetta
A1  - Melosh, Benjamin
A1  - Menzies, Catriona D.
A1  - Morales, Luiz
A1  - Morgan, Chance
A1  - Mori, Hiroshi
A1  - Niemeijer, Andre
A1  - Norris, Richard
A1  - Prior, David
A1  - Sauer, Katrina
A1  - Schleicher, Anja Maria
A1  - Shigematsu, Norio
A1  - Teagle, Damon A. H.
A1  - Tobin, Harold
A1  - Valdez, Robert
A1  - Williams, Jack
A1  - Yeo, Samantha
A1  - Baratin, Laura-May
A1  - Barth, Nicolas
A1  - Benson, Adrian
A1  - Boese, Carolin
A1  - Célérier, Bernard
A1  - Chamberlain, Calum J.
A1  - Conze, Ronald
A1  - Coussens, Jamie
A1  - Craw, Lisa
A1  - Doan, Mai-Linh
A1  - Eccles, Jennifer
A1  - Grieve, Jason
A1  - Grochowski, Julia
A1  - Gulley, Anton
A1  - Howarth, Jamie
A1  - Jacobs, Katrina
A1  - Janku-Capova, Lucie
A1  - Jeppson, Tamara
A1  - Langridge, Robert
A1  - Mallyon, Deirdre
A1  - Marx, Ray
A1  - Massiot, Cécile
A1  - Mathewson, Loren
A1  - Moore, Josephine
A1  - Nishikawa, Osamu
A1  - Pooley, Brent
A1  - Pyne, Alex
A1  - Savage, Martha K.
A1  - Schmitt, Doug
A1  - Taylor-Offord, Sam
A1  - Upton, Phaedra
A1  - Weaver, Konrad C.
A1  - Wiersberg, Thomas
A1  - Zimmer, Martin
T1  - Bedrock geology of DFDP-2B, central Alpine Fault, New Zealand
JF  - New Zealand journal of geology and geophysics : an international journal of the geoscience of New Zealand, the Pacific Rim, and Antarctica ; NZJG
N2  - During the second phase of the Alpine Fault, Deep Fault Drilling Project (DFDP) in the Whataroa River, South Westland, New Zealand, bedrock was encountered in the DFDP-2B borehole from 238.5–893.2 m Measured Depth (MD). Continuous sampling and meso- to microscale characterisation of whole rock cuttings established that, in sequence, the borehole sampled amphibolite facies, Torlesse Composite Terrane-derived schists, protomylonites and mylonites, terminating 200–400 m above an Alpine Fault Principal Slip Zone (PSZ) with a maximum dip of 62°. The most diagnostic structural features of increasing PSZ proximity were the occurrence of shear bands and reduction in mean quartz grain sizes. A change in composition to greater mica:quartz + feldspar, most markedly below c. 700 m MD, is inferred to result from either heterogeneous sampling or a change in lithology related to alteration. Major oxide variations suggest the fault-proximal Alpine Fault alteration zone, as previously defined in DFDP-1 core, was not sampled.
KW  - Alpine Fault
KW  - New Zealand
KW  - scientific drilling
KW  - mylonite
KW  - cataclasite
Y1  - 2017
U6  - https://doi.org/10.1080/00288306.2017.1375533
SN  - 0028-8306
SN  - 1175-8791
VL  - 60
IS  - 4
SP  - 497
EP  - 518
PB  - Taylor & Francis
CY  - Abingdon
ER  - 
TY  - JOUR
A1  - Dlugaiczyk, Martina
A1  - Blastenbrei, Peter
A1  - Haas, Hagen
A1  - Schmitt, Bernhard
A1  - Pühringer, Andrea
A1  - Reimer, Torsten
A1  - Schreiter, René
A1  - Podruczny, Grzegorz
A1  - Huntebrinker, Jan Willem
A1  - Mehrkens, Heidi
A1  - Körber, Esther-Beate
A1  - Göse, Frank
A1  - Feistauer, Daniela
A1  - Muth, Jörg
A1  - Busch, Michael
A1  - Krebs, Daniel
A1  - Luh, Jürgen
A1  - Ludwig, Ulrike
T1  - Militär und Gesellschaft in der Frühen Neuzeit
N2  - Aus dem Inhalt dieser Ausgabe: BEITRÄGE: Martina Dlugaiczyk: Der Waffenstillstand (1609-1621) als Medienereignis Peter Blastenbrei: Literaten und Soldaten (Teil 2) Hagen Haas: "Denn die Bombe, wann sie fällt ..." PROJEKTE: Bernhard Schmitt: "... eine ausgedehnte Gelegenheit zu einer ordentlichen Versorgung und besseren Fortkommen in dem Militärdienste" Andrea Pühringer: Die Darstellung von -Gewalt- im Krieg Torsten Reimer: Armada und Seeschlacht René Schreiter: Das Große Militärwaisenhaus zu Potsdam Grzegorz Podruczny: Preußische Militärarchitektur in Schlesien Jan Willem Huntebrinker: "Von der landsknecht lumphosen" BERICHTE: Heidi Mehrkens: Besatzung, Funktion und Gestalt militärischer Fremdherrschaft Esther-Beate Körber: Bericht über die Tagung der Arbeitsgemeinschaft zur preußischen Geschichte REZENSIONEN: Frank Göse: Dreißigjähriger Krieg und Westfälischer Friede. Forschungen aus westfälischen Adelsarchiven. Vorträge auf dem Kolloquium der Vereinigten Westfälischen Adelsarchive e. V. vom 3.-4. Dezember 1998 in Münster, Selbstverlag der Vereinigten Westfälischen Adelsarchive e. V. 2000 Daniela Feistauer: Karen Hagemann, "Mannlicher Muth und Teutsche Ehre". Nation, Militär und Geschlecht zur Zeit der Antinapo-leonischen Kriege Preußens, Paderborn, München, Wien, Zürich: Ferdinand Schöningh 2002 Jörg Muth: Das Heerwesen in Brandenburg und Preußen von 1640 bis 1806. Bd. 1: Olaf Groehler, Das Heerwesen, 2. Aufl., Berlin: Brandenburgisches Verlaghaus 2001 Michael Busch: Annette Hempel, "Eigentlicher Bericht / So wol auch Abkontra-feytung." Eine Untersuchung der nicht-allegorischen Nach-richtenblätter zu den Schlachten und Belagerungen der schwedischen Armee unter Gustav II Adolf (1628/30-1632), Frankfurt a. M.: Peter Lang Verlag 2000 Daniel Krebs: Michael Zimmer’s Diary. Ein deutsches Tagebuch aus dem Amerikanischen Bürgerkrieg, hrsg. von Jürgen Macha und Andrea Wolf, Frankfurt am Main, Berlin u. a.: Peter Lang Verlag 2001 Jürgen Luh: Michael Hochedlinger, Krise und Wiederherstellung. Öster-reichische Großmachtpolitik zwischen Türkenkrieg und "Zweiter Diplomatischer Revolution" 1787-1791, Berlin Duncker & Humblot 2000 Ulrike Ludwig: Sine ira et studio. Militärhistorische Studien zur Erinnerung an Hans Schmidt, hrsg. von Uta Lindgren, Karl Schnith und Jakob Seibert, Kallmünz/OPF.: Verlag Michael Lassleben 2001
T3  - Militär und Gesellschaft in der frühen Neuzeit - 7, Heft 1 
KW  - Militär / Geschichte
Y1  - 2003
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus-28093
SN  - 1617-9722
SN  - 1861-910X
VL  - 7
IS  - 1
ER  - 
TY  - JOUR
A1  - Vaz da Cruz, Vinicius
A1  - Ertan, Emelie
A1  - Couto, Rafael C.
A1  - Eckert, Sebastian
A1  - Fondell, Mattis
A1  - Dantz, Marcus
A1  - Kennedy, Brian
A1  - Schmitt, Thorsten
A1  - Pietzsch, Annette
A1  - Guimaraes, Freddy F.
A1  - Ågren, Hans
A1  - Odelius, Michael
A1  - Föhlisch, Alexander
A1  - Kimberg, Victor
T1  - A study of the water molecule using frequency control over nuclear dynamics in resonant X-ray scattering
JF  - Physical chemistry, chemical physics : a journal of European Chemical Societies
N2  - In this combined theoretical and experimental study we report a full analysis of the resonant inelastic X-ray scattering (RIXS) spectra of H2O, D2O and HDO. We demonstrate that electronically-elastic RIXS has an inherent capability to map the potential energy surface and to perform vibrational analysis of the electronic ground state in multimode systems. We show that the control and selection of vibrational excitation can be performed by tuning the X-ray frequency across core-excited molecular bands and that this is clearly reflected in the RIXS spectra. Using high level ab initio electronic structure and quantum nuclear wave packet calculations together with high resolution RIXS measurements, we discuss in detail the mode coupling, mode localization and anharmonicity in the studied systems.
Y1  - 2017
U6  - https://doi.org/10.1039/c7cp01215b
SN  - 1463-9076
SN  - 1463-9084
VL  - 19
SP  - 19573
EP  - 19589
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  - 
TY  - JOUR
A1  - Vaz da Cruz, Vinicius
A1  - Eckert, Sebastian
A1  - Iannuzzi, Marcella
A1  - Ertan, Emelie
A1  - Pietzsch, Annette
A1  - Couto, Rafael C.
A1  - Niskanen, Johannes
A1  - Fondell, Mattis
A1  - Dantz, Marcus
A1  - Schmitt, Thorsten
A1  - Lu, Xingye
A1  - McNally, Daniel
A1  - Jay, Raphael Martin
A1  - Kimberg, Victor
A1  - Föhlisch, Alexander
A1  - Odelius, Michael
T1  - Probing hydrogen bond strength in liquid water by resonant inelastic X-ray scattering
JF  - Nature Communications
N2  - Local probes of the electronic ground state are essential for understanding hydrogen bonding in aqueous environments. When tuned to the dissociative core-excited state at the O1s pre-edge of water, resonant inelastic X-ray scattering back to the electronic ground state exhibits a long vibrational progression due to ultrafast nuclear dynamics. We show how the coherent evolution of the OH bonds around the core-excited oxygen provides access to high vibrational levels in liquid water. The OH bonds stretch into the long-range part of the potential energy curve, which makes the X-ray probe more sensitive than infra-red spectroscopy to the local environment. We exploit this property to effectively probe hydrogen bond strength via the distribution of intramolecular OH potentials derived from measurements. In contrast, the dynamical splitting in the spectral feature of the lowest valence-excited state arises from the short-range part of the OH potential curve and is rather insensitive to hydrogen bonding.
Y1  - 2019
U6  - https://doi.org/10.1038/s41467-019-08979-4
SN  - 2041-1723
VL  - 10
PB  - Nature Publ. Group
CY  - London
ER  - 
TY  - JOUR
A1  - Eckert, Sebastian
A1  - Vaz da Cruz, Vinicius
A1  - Ertan, Emelie
A1  - Ignatova, Nina
A1  - Polyutov, Sergey
A1  - Couto, Rafael C.
A1  - Fondell, Mattis
A1  - Dantz, Marcus
A1  - Kennedy, Brian
A1  - Schmitt, Thorsten
A1  - Pietzsch, Annette
A1  - Odelius, Michael
A1  - Föhlisch, Alexander
T1  - One-dimensional cuts through multidimensional potential-energy surfaces by tunable x rays
JF  - Physical review : A, Atomic, molecular, and optical physics
N2  - The concept of the potential-energy surface (PES) and directional reaction coordinates is the backbone of our description of chemical reaction mechanisms. Although the eigenenergies of the nuclear Hamiltonian uniquely link a PES to its spectrum, this information is in general experimentally inaccessible in large polyatomic systems. This is due to (near) degenerate rovibrational levels across the parameter space of all degrees of freedom, which effectively forms a pseudospectrum given by the centers of gravity of groups of close-lying vibrational levels. We show here that resonant inelastic x-ray scattering (RIXS) constitutes an ideal probe for revealing one-dimensional cuts through the ground-state PES of molecular systems, even far away from the equilibrium geometry, where the independent-mode picture is broken. We strictly link the center of gravity of close-lying vibrational peaks in RIXS to a pseudospectrum which is shown to coincide with the eigenvalues of an effective one-dimensional Hamiltonian along the propagation coordinate of the core-excited wave packet. This concept, combined with directional and site selectivity of the core-excited states, allows us to experimentally extract cuts through the ground-state PES along three complementary directions for the showcase H2O molecule.
Y1  - 2018
U6  - https://doi.org/10.1103/PhysRevA.97.053410
SN  - 2469-9926
SN  - 2469-9934
VL  - 97
IS  - 5
PB  - American Physical Society
CY  - College Park
ER  - 
TY  - JOUR
A1  - Ertan, Emelie
A1  - Savchenko, Viktoriia
A1  - Ignatova, Nina
A1  - Vaz da Cruz, Vinicius
A1  - Couto, Rafael C.
A1  - Eckert, Sebastian
A1  - Fondell, Mattis
A1  - Dantz, Marcus
A1  - Kennedy, Brian
A1  - Schmitt, Thorsten
A1  - Pietzsch, Annette
A1  - Föhlisch, Alexander
A1  - Odelius, Michael
A1  - Kimberg, Victor
T1  - Ultrafast dissociation features in RIXS spectra of the water molecule
JF  - Physical chemistry, chemical physics : a journal of European Chemical Societies
N2  - In this combined theoretical and experimental study we report on an analysis of the resonant inelastic X-ray scattering (RIXS) spectra of gas phase water via the lowest dissociative core-excited state |1s−1O4a11〉. We focus on the spectral feature near the dissociation limit of the electronic ground state. We show that the narrow atomic-like peak consists of the overlapping contribution from the RIXS channels back to the ground state and to the first valence excited state |1b−114a11〉 of the molecule. The spectral feature has signatures of ultrafast dissociation (UFD) in the core-excited state, as we show by means of ab initio calculations and time-dependent nuclear wave packet simulations. We show that the electronically elastic RIXS channel gives substantial contribution to the atomic-like resonance due to the strong bond length dependence of the magnitude and orientation of the transition dipole moment. By studying the RIXS for an excitation energy scan over the core-excited state resonance, we can understand and single out the molecular and atomic-like contributions in the decay to the lowest valence-excited state. Our study is complemented by a theoretical discussion of RIXS in the case of isotopically substituted water (HDO and D2O) where the nuclear dynamics is significantly affected by the heavier fragments' mass.
Y1  - 2018
U6  - https://doi.org/10.1039/c8cp01807c
SN  - 1463-9076
SN  - 1463-9084
VL  - 20
IS  - 21
SP  - 14384
EP  - 14397
PB  - Royal Society of Chemistry
CY  - Cambridge
ER  - 
TY  - JOUR
A1  - Couto, Rafael C.
A1  - Cruz, Vinicius V.
A1  - Ertan, Emelie
A1  - Eckert, Sebastian
A1  - Fondell, Mattis
A1  - Dantz, Marcus
A1  - Kennedy, Brian
A1  - Schmitt, Thorsten
A1  - Pietzsch, Annette
A1  - Guimaraes, Freddy F.
A1  - Agren, Hans
A1  - Odelius, Michael
A1  - Kimberg, Victor
A1  - Föhlisch, Alexander
T1  - Selective gating to vibrational modes through resonant X-ray scattering
JF  - Nature Communications
N2  - The dynamics of fragmentation and vibration of molecular systems with a large number of coupled degrees of freedom are key aspects for understanding chemical reactivity and properties. Here we present a resonant inelastic X-ray scattering (RIXS) study to show how it is possible to break down such a complex multidimensional problem into elementary components. Local multimode nuclear wave packets created by X-ray excitation to different core-excited potential energy surfaces (PESs) will act as spatial gates to selectively probe the particular ground-state vibrational modes and, hence, the PES along these modes. We demonstrate this principle by combining ultra-high resolution RIXS measurements for gas-phase water with state-of-the-art simulations.
Y1  - 2017
U6  - https://doi.org/10.1038/ncomms14165
SN  - 2041-1723
VL  - 8
PB  - Nature Publ. Group
CY  - London
ER  - 
TY  - JOUR
A1  - Vaz da Cruz, Vinícius
A1  - Ignatova, Nina
A1  - Couto, Rafael
A1  - Fedotov, Daniil
A1  - Rehn, Dirk R.
A1  - Savchenko, Viktoriia
A1  - Norman, Patrick
A1  - Ågren, Hans
A1  - Polyutov, Sergey
A1  - Niskanen, Johannes
A1  - Eckert, Sebastian
A1  - Jay, Raphael Martin
A1  - Fondell, Mattis
A1  - Schmitt, Thorsten
A1  - Pietzsch, Annette
A1  - Föhlisch, Alexander
A1  - Odelius, Michael
A1  - Kimberg, Victor
A1  - Gel’mukhanov, Faris
T1  - Nuclear dynamics in resonant inelastic X-ray scattering and X-ray absorption of methanol
JF  - The journal of chemical physics : bridges a gap between journals of physics and journals of chemistr
N2  - We report on a combined theoretical and experimental study of core-excitation spectra of gas and liquid phase methanol as obtained with the use of X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS). The electronic transitions are studied with computational methods that include strict and extended second-order algebraic diagrammatic construction [ADC(2) and ADC(2)-x], restricted active space second-order perturbation theory, and time-dependent density functional theory-providing a complete assignment of the near oxygen K-edge XAS. We show that multimode nuclear dynamics is of crucial importance for explaining the available experimental XAS and RIXS spectra. The multimode nuclear motion was considered in a recently developed "mixed representation" where dissociative states and highly excited vibrational modes are accurately treated with a time-dependent wave packet technique, while the remaining active vibrational modes are described using Franck-Condon amplitudes. Particular attention is paid to the polarization dependence of RIXS and the effects of the isotopic substitution on the RIXS profile in the case of dissociative core-excited states. Our approach predicts the splitting of the 2a RIXS peak to be due to an interplay between molecular and pseudo-atomic features arising in the course of transitions between dissociative core- and valence-excited states. The dynamical nature of the splitting of the 2a peak in RIXS of liquid methanol near pre-edge core excitation is shown. The theoretical results are in good agreement with our liquid phase measurements and gas phase experimental data available from the literature. (C) 2019 Author(s).
Y1  - 2019
U6  - https://doi.org/10.1063/1.5092174
SN  - 0021-9606
SN  - 1089-7690
VL  - 150
IS  - 23
PB  - American Institute of Physics
CY  - Melville
ER  - 
TY  - GEN
A1  - Couto, Rafael C.
A1  - Cruz, Vinicius V.
A1  - Ertan, Emelie
A1  - Eckert, Sebastian
A1  - Fondell, Mattis
A1  - Dantz, Marcus
A1  - Kennedy, Brian
A1  - Schmitt, Thorsten
A1  - Pietzsch, Annette
A1  - Guimarães, Freddy F.
A1  - Ågren, Hans
A1  - Gel’mukhanov, Faris
A1  - Odelius, Michael
A1  - Kimberg, Victor
A1  - Föhlisch, Alexander
T1  - Selective gating to vibrational modes through resonant X-ray scattering
T2  - Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe
N2  - The dynamics of fragmentation and vibration of molecular systems with a large number of coupled degrees of freedom are key aspects for understanding chemical reactivity and properties. Here we present a resonant inelastic X-ray scattering (RIXS) study to show how it is possible to break down such a complex multidimensional problem into elementary components. Local multimode nuclear wave packets created by X-ray excitation to different core-excited potential energy surfaces (PESs) will act as spatial gates to selectively probe the particular ground-state vibrational modes and, hence, the PES along these modes. We demonstrate this principle by combining ultra-high resolution RIXS measurements for gas-phase water with state-of-the-art simulations.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 1124 
KW  - potential-energy surface
KW  - raman-scattering
KW  - water-vapor
KW  - spectroscopy
KW  - chemistry
KW  - molecule
KW  - spectrum
KW  - CM(-1)
KW  - states
KW  - NM
Y1  - 2021
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-436926
SN  - 1866-8372
IS  - 1124
ER  - 
TY  - GEN
A1  - Vaz da Cruz, Vinicius
A1  - Ertan, Emelie
A1  - Couto, Rafael C.
A1  - Eckert, Sebastian
A1  - Fondell, Mattis
A1  - Dantz, Marcus
A1  - Kennedy, Brian
A1  - Schmitt, Thorsten
A1  - Pietzsch, Annette
A1  - Guimarães, Freddy  F.
A1  - Ågren, Hans
A1  - Gel'mukhanov, Faris
A1  - Odelius, Michael
A1  - Föhlisch, Alexander
A1  - Kimberg, Victor
T1  - A study of the water molecule using frequency control over nuclear dynamics in resonant X-ray scattering
T2  - Postprints der Universität Potsdam Mathematisch-Naturwissenschaftliche Reihe
N2  - In this combined theoretical and experimental study we report a full analysis of the resonant inelastic X-ray scattering (RIXS) spectra of H2O, D2O and HDO. We demonstrate that electronically-elastic RIXS has an inherent capability to map the potential energy surface and to perform vibrational analysis of the electronic ground state in multimode systems. We show that the control and selection of vibrational excitation can be performed by tuning the X-ray frequency across core-excited molecular bands and that this is clearly reflected in the RIXS spectra. Using high level ab initio electronic structure and quantum nuclear wave packet calculations together with high resolution RIXS measurements, we discuss in detail the mode coupling, mode localization and anharmonicity in the studied systems.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 781 
KW  - raman-scattering
KW  - vibrational structure
KW  - fast dissociation
KW  - auger spectrum
KW  - liquid water
KW  - spectroscopy
KW  - emission
KW  - collapse
KW  - states
KW  - vapor
Y1  - 2019
U6  - http://nbn-resolving.de/urn/resolver.pl?urn:nbn:de:kobv:517-opus4-436901
SN  - 1866-8372
IS  - 781
SP  - 19573
EP  - 19589
ER  - 
TY  - JOUR
A1  - Insel, N.
A1  - Grove, M.
A1  - Haschke, Michael
A1  - Barnes, J. B.
A1  - Schmitt, Axel K.
A1  - Strecker, Manfred
T1  - Paleozoic to early Cenozoic cooling and exhumation of the basement underlying the eastern Puna plateau margin prior to plateau growth
JF  - Tectonics
N2  - Constraining the pre-Neogene history of the Puna plateau is crucial for establishing the initial conditions that attended the early stage evolution of the southern extent of the Andean plateau. We apply high-to low-temperature thermochronology data from plutonic rocks in northwestern Argentina to quantify the Paleozoic, Mesozoic and early Tertiary cooling history of the Andean crust. U-Pb crystallization ages of zircons indicate that pluton intrusion occurred during the early mid-Ordovician (490-470 Ma) and the late Jurassic (160-150 Ma). Lower-temperature cooling histories from Ar-40/Ar-39 analyses of K-feldspar vary substantially. Basement rocks underlying the western Puna resided at temperatures below 200 degrees C (<6 km depth) since the Devonian (similar to 400 Ma). In contrast, basement rocks underlying the southeastern Puna were hotter (similar to 200-300 degrees C) throughout the Paleozoic and Jurassic and cooled to temperatures of <200 degrees C by similar to 120 Ma. The southeastern Puna basement records a rapid cooling phase coeval with active extension of the Cretaceous Salta rift at similar to 160-100 Ma that we associate with tectonic faulting and lithospheric thinning. The northeastern Puna experienced protracted cooling until the late Cretaceous with temperatures <200 degrees C during the Paleocene. Higher cooling rates between 78 and 55 Ma are associated with thermal subsidence during the postrift stage of the Salta rift and/or shortening-related flexural subsidence. Accelerated cooling and deformation during the Eocene was focused within a narrow zone along the eastern Puna/Eastern Cordillera transition that coincides with Paleozoic/Mesozoic structural and thermal boundaries. Our results constrain regional erosion-induced cooling throughout the Cenozoic to have been less than similar to 150 degrees C, which implies total Cenozoic denudation of <6-4 km.
Y1  - 2012
U6  - https://doi.org/10.1029/2012TC003168
SN  - 0278-7407
VL  - 31
IS  - 23
PB  - American Geophysical Union
CY  - Washington
ER  - 
TY  - GEN
A1  - Ehmann, Lisa
A1  - Zoller, Michael
A1  - Minichmayr, Iris K.
A1  - Schmitt, Maximilian V.
A1  - Hartung, Niklas
A1  - Huisinga, Wilhelm
A1  - Zander, Johannes
A1  - Kloft, Charlotte
T1  - Development of a tool to identify intensive care patients at risk of meropenem therapy failure
T2  - International Journal of Clinical Pharmacy
Y1  - 2018
SN  - 2210-7703
SN  - 2210-7711
VL  - 40
IS  - 1
SP  - 317
EP  - 317
PB  - Springer
CY  - Dordrecht
ER  - 
TY  - JOUR
A1  - Schulze-Makuch, Dirk
A1  - Wagner, Dirk
A1  - Kounaves, Samuel P.
A1  - Mangelsdorf, Kai
A1  - Devine, Kevin G.
A1  - de Vera, Jean-Pierre
A1  - Schmitt-Kopplin, Philippe
A1  - Grossart, Hans-Peter
A1  - Parro, Victor
A1  - Kaupenjohann, Martin
A1  - Galy, Albert
A1  - Schneider, Beate
A1  - Airo, Alessandro
A1  - Froesler, Jan
A1  - Davila, Alfonso F.
A1  - Arens, Felix L.
A1  - Caceres, Luis
A1  - Cornejo, Francisco Solis
A1  - Carrizo, Daniel
A1  - Dartnell, Lewis
A1  - DiRuggiero, Jocelyne
A1  - Flury, Markus
A1  - Ganzert, Lars
A1  - Gessner, Mark O.
A1  - Grathwohl, Peter
A1  - Guan, Lisa
A1  - Heinz, Jacob
A1  - Hess, Matthias
A1  - Keppler, Frank
A1  - Maus, Deborah
A1  - McKay, Christopher P.
A1  - Meckenstock, Rainer U.
A1  - Montgomery, Wren
A1  - Oberlin, Elizabeth A.
A1  - Probst, Alexander J.
A1  - Saenz, Johan S.
A1  - Sattler, Tobias
A1  - Schirmack, Janosch
A1  - Sephton, Mark A.
A1  - Schloter, Michael
A1  - Uhl, Jenny
A1  - Valenzuela, Bernardita
A1  - Vestergaard, Gisle
A1  - Woermer, Lars
A1  - Zamorano, Pedro
T1  - Transitory microbial habitat in the hyperarid Atacama Desert
JF  - Proceedings of the National Academy of Sciences of the United States of America
KW  - habitat
KW  - aridity
KW  - microbial activity
KW  - biomarker
KW  - Mars
Y1  - 2018
U6  - https://doi.org/10.1073/pnas.1714341115
SN  - 0027-8424
VL  - 115
IS  - 11
SP  - 2670
EP  - 2675
PB  - National Acad. of Sciences
CY  - Washington
ER  -