TY - JOUR A1 - Bauer-Gogonea, Simona A1 - Bauer, Siegfried A1 - Wirges, Werner A1 - Gerhard, Reimund T1 - Dielectric investigation of photo-induced chromophore degradation in nonlinear optical side-chain polymer electrets N2 - Organic materials with non-centrosymmetric chromophores are known to be susceptible to a number of photochemical processes, including reversible isomerization reactions as well as irreversible photo-oxidation or photo- reduction reactions. Reversible isomerization is the basis for a variety of applications, such as photo-induced poling, optical data storage and optical grating formation. The irreversible processes that involve the destruction of the chromophores have been found useful for the fabrication of optical waveguides, but they also limit the life times of polymeric photonic devices. In this paper, it is demonstrated that dielectric measurements allow for an in-depth investigation of non-reversible chromophore degradation processes in a typical side-chain polymer. The time- and temperature-dependent dielectric function of the polymer at 1 kHz enables us to follow the chromophore-degradation kinetics and to monitor the bleaching depth as a function of time at room and elevated temperatures Y1 - 2004 ER - TY - JOUR A1 - Stracke, A. A1 - Bayer, A. A1 - Zimmermann, S. A1 - Wendorff, Joachim Heinz A1 - Wirges, Werner A1 - Bauer-Gogonea, Simona A1 - Bauer, Siegfried A1 - Gerhard, Reimund T1 - Relaxation behaviour of electrically induced polar orientation and of optically induced non-polar orientation in an azo-chromophore side group polymer Y1 - 1999 SN - 0022-3727 ER - TY - JOUR A1 - Bauer-Gogonea, Simona A1 - Cheng, Z. Y. A1 - Wirges, Werner A1 - Bauer, Siegfried A1 - Gerhard, Reimund A1 - Das-Gupta, D. K. T1 - Dielectric investigation of thermally-induced chromophore degradation in nonlinear optical polymer electrets Y1 - 1998 ER - TY - JOUR A1 - Donval, Ariela A1 - Berkovic, Garry A1 - Yilmaz, Sükrü A1 - Bauer-Gogonea, Simona A1 - Brinker, Walter A1 - Wirges, Werner A1 - Bauer, Siegfried A1 - Gerhard, Reimund T1 - Spatial and thermal analysis of nonlinearity created by asymmetric charge injection Y1 - 1996 ER - TY - JOUR A1 - Bauer-Gogonea, Simona A1 - Wirges, Werner A1 - Bauer, Siegfried A1 - Gerhard, Reimund A1 - Liang, J. A1 - Zyss, Joseph T1 - Electrical determination of the degree of cross-linking in a poled nonlinear optical polymer Y1 - 1996 ER - TY - JOUR A1 - Bauer-Gogonea, Simona A1 - Bauer, Siegfried A1 - Wirges, Werner A1 - Gerhard, Reimund T1 - Preparation and pyroelectrical investigation of bimorph polymer layers Y1 - 1995 ER - TY - JOUR A1 - Gerhard, Reimund A1 - Bauer, Siegfried A1 - Bauer-Gogonea, Simona A1 - Brinker, Walter A1 - Dinger, Claudia A1 - Molzow, Wolf-Dietrich A1 - Wirges, Werner A1 - Yilmaz, Sükrü T1 - Electro-optical investigation of the dipole orientation in poled polymers Y1 - 1995 ER - TY - JOUR A1 - Bauer, Siegfried A1 - Bauer-Gogonea, Simona A1 - Yilmaz, Sükrü A1 - Dinger, Claudia A1 - Wirges, Werner A1 - Gerhard, Reimund A1 - Michelotti, F. A1 - Toussaere, E. A1 - Levenson, R. A1 - Liang, J. A1 - Zyss, Joseph T1 - Pyroelectric, dielectric and electro-optical investigation of crosslinking in Red Acid Magly Y1 - 1995 ER - TY - JOUR A1 - Bauer-Gogonea, Simona A1 - Bauer, Siegfried A1 - Wirges, Werner A1 - Gerhard, Reimund A1 - Wintler, H. J. T1 - Physical aging after photo-induced or thermally assisted poling for enhancing the stability of polymeric dipole glasses Y1 - 1995 ER - TY - JOUR A1 - Donval, Ariela A1 - Berkovic, Garry A1 - Bauer-Gogonea, Simona A1 - Wirges, Werner A1 - Bauer, Siegfried A1 - Gerhard, Reimund T1 - Pyroelectric depth profiling of the optical nonlinearity caused by charge injection Y1 - 1995 ER -