TY - JOUR A1 - Delorme, Nicolas A1 - Dubois, Monique A1 - Garnier, Sebastien A1 - Laschewsky, André A1 - Weinkamer, Richard A1 - Zemb, Thomas A1 - Fery, Andreas T1 - Surface immobilization and mechanical properties of catanionic hollow faceted polyhedrons N2 - We report here for the first time on surface immobilization of hollow faceted polyhedrons formed from catanionic surfactant mixtures. We find that electrostatic interaction with the substrate dominates their adhesion behavior. Using polyelectrolyte coated surfaces with tailored charge densities, polyhedrons can thus be immobilized without complete spreading, which allows for further study of their mechanical properties using AFM force measurements. The elastic response of individual polyhedrons can be locally resolved, showing pronounced differences in stiffness between faces and vertexes of the structure, which makes these systems interesting as models for structurally similar colloidal scale objects such as viruses, where such effects are predicted but cannot be directly observed due to the smaller dimensions. Elastic constants of the wall material are estimated using shell and plate deformation models and are found to be a factor of 5 larger than those for neutral lipidic bilayers in the gel state. We discuss the molecular origins of this high stiffness Y1 - 2006 UR - http://pubs.acs.org/journal/jpcbfk U6 - https://doi.org/10.1021/Jp054473+ SN - 1520-1758 ER - TY - JOUR A1 - Rusconi, Marco A1 - Valleriani, Angelo A1 - Dunlop, John William Chapman A1 - Kurths, Jürgen A1 - Weinkamer, Richard T1 - Insights into the control of trabecular bone remodelling obtained by a Markov model Y1 - 2009 UR - http://www.sciencedirect.com/science/journal/87563282 U6 - https://doi.org/10.1016/j.bone.2009.03.467 SN - 8756-3282 ER - TY - JOUR A1 - Rusconi, Marco A1 - Valleriani, Angelo A1 - Dunlop, John William Chapman A1 - Kurths, Jürgen A1 - Weinkamer, Richard T1 - Quantitative approach to the stochastics of bone remodeling JF - epl : a letters journal exploring the frontiers of physics N2 - During life bones constantly adapt their structure to their mechanical environment via a mechanically controlled process called bone remodeling. For trabecular bone, this process modifies the thickness of each trabecula leading occasionally to full resorption. We describe the irreversible dynamics of the trabecular thickness distribution (TTD) by means of a Markov chain discrete in space and time. By using thickness data from adult patients, we derive the transition probabilities in the chain. This allows a quantification, in terms of geometrical quantities, of the control of bone remodeling and thus to determine the evolution of the TTD with age. Y1 - 2012 U6 - https://doi.org/10.1209/0295-5075/97/28009 SN - 0295-5075 VL - 97 IS - 2 PB - EDP Sciences CY - Mulhouse ER -