TY  - JOUR
A1  - Harms, Stephan
A1  - Raetzke, Klaus
A1  - Faupel, Franz
A1  - Egger, Werner
A1  - Ravello, Lori Boyd de
A1  - Laschewsky, André
A1  - Wang, Weinan
A1  - Müller-Buschbaum, Peter
T1  - Free volume and swelling in thin films of poly(n-isopropylacrylamide) end-capped with n-butyltrithiocarbonate
N2  - The free volume in thin films of poly(N-isopropylacrylamid) end-capped with n-butyltrio-carbonate (nbc-PNIPAM) is probed with positron annihilation lifetime spectroscopy (PALS). The PALS measurements are performed as function of energy to obtain depth profiles of the free volume of nbc-PNIPAM films. The range of nbc-PNIPAM films with thicknesses from 40 to 200 nm is focused. With decreasing film thickness the free volume increases in good agreement with an increase in the maximum swelling capability of the nbc-PNIPAM films. Thus in thin hydrogel films the sorption and swelling behavior is governed by free volume.
Y1  - 2010
UR  - http://www3.interscience.wiley.com/cgi-bin/jhome/10003270
U6  - https://doi.org/10.1002/marc.201000067
SN  - 1022-1336
ER  - 
TY  - JOUR
A1  - Adelsberger, Joseph
A1  - Kulkarni, Amit
A1  - Jain, Abhinav
A1  - Wang, Weinan
A1  - Bivigou Koumba, Achille Mayelle
A1  - Busch, Peter
A1  - Pipich, Vitaliy
A1  - Holderer, Olaf
A1  - Hellweg, Thomas
A1  - Laschewsky, André
A1  - Müller-Buschbaum, Peter
A1  - Papadakis, Christine M.
T1  - Thermoresponsive PS-b-PNIPAM-b-PS micelles : aggregation behavior, segmental dynamics, and thermal response
N2  - We have studied I lie thermal behavior of amphiphilic, symmetric triblock copolymers having short, deuterated polystyrene (PS) end blocks and a large poly(N-isopropylacrylarnicle) (PNIPAM) middle block exhibiting a lower critical solution temperature (LCST) in aqueous solution. A wide range of concentrations (0.1-300 mg/mL) is investigated using it number of analytical methods such as fluorescence correlation spectroscopy (FCS), turbidimetry, dynamic light scattering (DLS), small-angle neutron scattering (SANS), and neutron spin-echo spectroscopy (NSE). The critical micelle concentration is determined using FCS to be 1 mu M or less. The collapse of the micelles at the LCST is investigated using turbidimetry and DLS and shows a weak dependence on the degree of polymerization of the PNIPAM block. SANS with contrast matching allows its to reveal the core-shell Structure of the micelles as well as their correlation as a function of temperature. The segmental dynamics of the PNIPAM shell are studied as a function of temperature and arc found to be faster in the collapsed state than in the swollen state. The mode detected has a linear dispersion in q(2) and is found to be faster in the collapsed state as compared to the swollen state. We attribute this result to the averaging over mobile and immobilized segments.
Y1  - 2010
UR  - http://pubs.acs.org/journal/mamobx
U6  - https://doi.org/10.1021/Ma902714p
SN  - 0024-9297
ER  - 
TY  - JOUR
A1  - Zhong, Qi
A1  - Wang, Weinan
A1  - Adelsberger, Joseph
A1  - Golosova, Anastasia
A1  - Koumba, Achille M. Bivigou
A1  - Laschewsky, André
A1  - Funari, Sergio S.
A1  - Perlich, Jan
A1  - Roth, Stephan V.
A1  - Papadakis, Christine M.
A1  - Müller-Buschbaum, Peter
T1  - Collapse transition in thin films of poly(methoxydiethylenglycol acrylate)
JF  - Colloid and polymer science : official journal of the Kolloid-Gesellschaft
N2  - The thermal behavior of poly(methoxydiethylenglycol acrylate) (PMDEGA) is studied in thin hydrogel films on solid supports and is compared with the behavior in aqueous solution. The PMDEGA hydrogel film thickness is varied from 2 to 422 nm. Initially, these films are homogenous, as measured with optical microscopy, atomic force microscopy, X-ray reflectivity, and grazing-incidence small-angle X-ray scattering (GISAXS). However, they tend to de-wet when stored under ambient conditions. Along the surface normal, no long-ranged correlations between substrate and film surface are detected with GISAXS, due to the high mobility of the polymer at room temperature. The swelling of the hydrogel films as a function of the water vapor pressure and the temperature are probed for saturated water vapor pressures between 2,380 and 3,170 Pa. While the swelling capability is found to increase with water vapor pressure, swelling in dependence on the temperature revealed a collapse phase transition of a lower critical solution temperature type. The transition temperature decreases from 40.6 A degrees C to 36.6 A degrees C with increasing film thickness, but is independent of the thickness for very thin films below a thickness of 40 nm. The observed transition temperature range compares well with the cloud points observed in dilute (0.1 wt.%) and semi-dilute (5 wt.%) solution which decrease from 45 A degrees C to 39 A degrees C with increasing concentration.
KW  - Hydrogel
KW  - Thin film
KW  - Thermoresponsive
KW  - LCST behavior
KW  - GISAXS
KW  - AFM
Y1  - 2011
U6  - https://doi.org/10.1007/s00396-011-2384-1
SN  - 0303-402X
VL  - 289
IS  - 5-6
SP  - 569
EP  - 581
PB  - Springer
CY  - New York
ER  -